Studies on the electronic transport properties of some organic semiconductors in thin films

The investigated compounds are some derivatives of orthotolidin-N,N-bis (4-aminobenzene-2-sulphonic) acid. The temperature dependences of the electrical conductivity and Seebeck coefficient are studied on the thin films deposited from dimethylformamide solution onto glass substrates. It is known that the investigated compounds have typical semiconducting properties. The values of some important parameters of the films (thermal activation energy of electrical conduction, concentrations and mobilities of charge carriers) have been determined. The correlations between some of these parameters and molecular structure of the respective compounds are discussed.     

A new route to graphene starting from heavily ozonized fullerenes: Part 3 – an electron spin resonance study

It is shown that graphite oxide (GO) and both heavily ozonized C₆₀ and C₇₀ fullerenes, known as “fullerene ozopolymers,” are paramagnetic materials with a very strong electron spin resonance (ESR) signal at room temperature. When thermally annealed, the paramagnetic centers are gradually lost in large part. This occurs at 350°C in the case of GO, while for fullerene ozopolymers, a higher temperature is required, reaching the same results in the end. The half-width of ESR signal is linked to the distribution of paramagnetic centers. Once again, striking analogies were found in the half-width of the ESR signal measured on GO and fullerene ozopolymers, at least in the temperature range of 25–450°C. Similarly, the same g-factor values, which are diagnostic for understanding the chemical nature of paramagnetic centers, were found on both GO and fullerene ozopolymers in all ranges of temperature considered.     

Concepts and fuzzy logic

Weights are used to measure relative importance of multiple attributes or objectives, which influence evaluation or decision results to a great degree. Thus, analyzing weight sensitivity is an important work for a multi-attribute evaluation or decision. A measuring method based on the inclined angle of two vectors is proposed in this paper in order to solve the weight sensitivity of a multi-attribute evaluation with isotonicity characteristic. This method uses the cosine of the inclined angle to measure the weight sensitivity based on preferences or preference combinations. Concepts of sensitivity space, degree, and angle are given, and the relevant measurement method is discussed and proved. Also, this method is used for the choice of the water environment protection projects in Heyuan City.     

Benefits of Residual Aluminum in Ductile Iron

Two main chemistry systems of micro-inclusions can be identified in ductile iron: Ca-S-X and Mg-Si-O-X with the majority of the inclusions regardless of treatment type and location being of the second type, silicates. Laboratory investigations have shown that simple silicates were present in the matrix, while more complex silicates were present in conjunction with graphite, probably acting as graphite nucleation sites. In these more complex silicates, elevated levels of Al, Ca, Ce and La were typical. Comparing micro-particles embedded in iron matrix and graphite nodules of iron treated with pure Mg-metal and iron treated with MgFeSi alloy showed a higher amount of complex silicates with elevated Al-levels in the iron treated with MgFeSi. Further laboratory investigation was undertaken to explore which source of Al and which range of residual Al would have a favorable impact on the graphite nucleation in ductile iron. The work showed that a residual aluminum of 0.005 to 0.020 wt.% appears to be beneficial for improving ductile iron solidification characteristics without the incidence of pinholes. Greatest benefits were achieved when introducing the Al into the iron via an inoculant late during processing or via a pre-conditioner to the base iron. Al added via the MgFeSi provided less benefit. Some case studies illustrating the effect of Al in ductile iron are also presented, as Al-containing pre-conditioner or/and Al-bearing, FeSi inoculant application.     

Cancer Stem Cells: Biological Functions and Therapeutically Targeting

Almost all tumors are composed of a heterogeneous cell population, making them difficult to treat. A small cancer stem cell population with a low proliferation rate and a high tumorigenic potential is thought to be responsible for cancer development, metastasis and resistance to therapy. Stem cells were reported to be involved in both normal development and carcinogenesis, some molecular mechanisms being common in both processes. No less controversial, stem cells are considered to be important in treatment of malignant diseases both as targets and drug carriers. The efforts to understand the role of different signalling in cancer stem cells requires in depth knowledge about the mechanisms that control their self-renewal, differentiation and malignant potential. The aim of this paper is to discuss insights into cancer stem cells historical background and to provide a brief review of the new therapeutic strategies for targeting cancer stem cells.     

Agent-Oriented Supply-Chain Management

The supply chain is a worldwide network of suppliers, factories, warehouses, distribution centers, and retailers through which raw materials are acquired, transformed, and delivered to customers. In recent years, a new software architecture for managing the supply chain at the tactical and operational levels has emerged. It views the supply chain as composed of a set of intelligent software agents, each responsible for one or more activities in the supply chain and each interacting with other agents in the planning and execution of their responsibilities. This paper investigates issues and presents solutions for the construction of such an agent-oriented software architecture. The approach relies on the use of an agent building shell, providing generic, reusable, and guaranteed components and services for communicative-act-based communication, conversational coordination, role-based organization modeling, and others. Using these components, we show two nontrivial agent-based supply-chain architectures able to support complex cooperative work and the management of perturbation caused by stochastic events in the supply chain.     

GBT formulation to analyse the behaviour of thin-walled members with variable cross-section

The generalised beam theory (GBT) provides a general solution for the linear/non-linear analysis of prismatic thin-walled structures, using bar elements capable of describing the cross-section rigid-body motions and distortions. Nowadays GBT is fully developed for thin-walled members having a large variety of constant cross-sections. This paper provides the extension of GBT for the special case of thin-walled members with variable open cross-section and the limits of its applicability.     

Error estimation in the approximation of the solution of nonlinear fuzzy Fredholm integral equations

Using a fixed point technique, the sequence of successive approximations and a recent quadrature formula for fuzzy-number-valued functions, it is constructed a numerical method for the solution of nonlinear fuzzy Fredholm integral equations. Moreover, the error estimate of the method and a criterion to stop the corresponding algorithm are given.     

Bistable hybrids in sol–gel technology for switching devices

Development of memories based on organic soft materials is a current industrial niche aimed at the upper contacts flash memories. The electrical bistability of such materials makes them ideal candidates for cost-effective, fast-programming switching devices. Hybrid thin films of SiO₂ with Rose Bengal (bis-triethylammonium) dopant are here reported for the first time, together with their characterisations. Technology-wise the main advantage of the films is the possibility to cast photolithographically, which is also cost-effective. The physical and chemical stability of the films yields reproducible devices, from both the microtechnological and electrical point of view.     

Co-pyrolysis of pine cone with synthetic polymers

Biomass from pine cone (Pinus pinea L.) was co-pyrolyzed with synthetic polymers (PE, PP and PS) in order to investigate the effect of biomass and plastic nature on the product yields and quality of pyrolysis oils and chars. The pyrolysis temperature was of 500 °C and it was selected based on results from thermogravimetric analysis of the studied samples. Co-pyrolysis products namely gases, aqueous and tar fraction coming from biomass, oils from synthetic polymers and residual char were collected and analyzed. Due to the synergistic effect in the pyrolysis of the biomass/polymer mixtures, higher amounts of liquid products were obtained compared to theoretical ones. To investigate the effect of biomass content on the co-pyrolysis, the co-pyrolysis of pure cellulose as model natural polymer for biomass with polymer mixture was also carried out. In the presence of cellulose, degradation reaction leading to more gas formation and less char yield was more advanced than in the case of co-pyrolysis with pine cone. Co-pyrolysis gave polar oxygenated compounds distributed between tar and aqueous phase and hydrocarbon oils with composition depending on the type of synthetic polyolefin. Co-pyrolysis chars had higher calorific values compared to pyrolysis of biomass alone.