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21.
Electroactive polymers are a new generation of "green" cathode materials for rechargeable lithium batteries. We have developed nanocomposites combining graphene with two promising polymer cathode materials, poly(anthraquinonyl sulfide) and polyimide, to improve their high-rate performance. The polymer-graphene nanocomposites were synthesized through a simple in situ polymerization in the presence of graphene sheets. The highly dispersed graphene sheets in the nanocomposite drastically enhanced the electronic conductivity and allowed the electrochemical activity of the polymer cathode to be efficiently utilized. This allows for ultrafast charging and discharging; the composite can deliver more than 100 mAh/g within just a few seconds. 相似文献
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Influence of Temperature on the Colloidal Stability of Polymer‐Coated Gold Nanoparticles in Cell Culture Media 下载免费PDF全文
Mikhail V. Zyuzin Tobias Honold Susana Carregal‐Romero Karsten Kantner Matthias Karg Wolfgang J. Parak 《Small (Weinheim an der Bergstrasse, Germany)》2016,12(13):1723-1731
The temperature‐dependence of the hydrodynamic diameter and colloidal stability of gold‐polymer core‐shell particles with temperature‐sensitive (poly(N‐isopropylacrylamide)) and temperature‐insensitive shells (polyallylaminine hydrochloride/polystyrensulfonate, poly(isobutylene‐alt‐maleic anhydride)‐graft‐dodecyl) are investigated in various aqueous media. The data demonstrate that for all nanoparticle agglomeration, i.e., increase in effective nanoparticle size, the presence of salts or proteins in the dispersion media has to be taken into account. Poly(N‐isopropylacrylamide) coated nanoparticles show a reversible temperature‐dependent increase in size above the volume phase transition of the polymer shell when they are dispersed in phosphate buffered saline or in media containing protein. In contrast, the nanoparticles coated with temperature‐insensitive polymers show a time‐dependent increase in size in phosphate buffered saline or in medium containing protein. This is due to time‐dependent agglomeration, which is particularly strong in phosphate buffered saline, and induces a time‐dependent, irreversible increase in the hydrodynamic diameter of the nanoparticles. This demonstrates that one has to distinguish between temperature‐ and time‐induced agglomerations. Since the size of nanoparticles regulates their uptake by cells, temperature‐dependent uptake of thermosensitive and non‐thermosensitive nanoparticles by cells lines is compared. No temperature‐specific difference between both types of nanoparticles could be observed. 相似文献
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A photoelectric autocollimator with high accuracy and extended measurement range based on the quadrangular pyramid is proposed, and the corresponding algorithms are also deduced. A new image processing algorithm has been proposed to improve the accuracy, and the corresponding errors are also estimated, the error does not exceed half a pixel when the distance between the marks more than two radii. The experimental results have verified that the measurement range of the proposed two-dimensional (2D) quadrangular pyramid photoelectric autocollimator can be increased times than that of the flat mirror photoelectric autocollimator from 10′ to 15′. The accuracy is better than 1″ when the deflection is less than 15′. 相似文献
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Devis Tuia Jordi Muñoz-Marí Mikhail Kanevski Gustavo Camps-Valls 《Journal of Signal Processing Systems》2011,65(3):301-310
Traditional kernel classifiers assume independence among the classification outputs. As a consequence, each misclassification receives the same weight in the loss function. Moreover, the kernel function only takes into account the similarity between input values and ignores possible relationships between the classes to be predicted. These assumptions are not consistent for most of real-life problems. In the particular case of remote sensing data, this is not a good assumption either. Segmentation of images acquired by airborne or satellite sensors is a very active field of research in which one tries to classify a pixel into a predefined set of classes of interest (e.g. water, grass, trees, etc.). In this situation, the classes share strong relationships, e.g. a tree is naturally (and spectrally) more similar to grass than to water. In this paper, we propose a first approach to remote sensing image classification using structured output learning. In our approach, the output space structure is encoded using a hierarchical tree, and these relations are added to the model in both the kernel and the loss function. The methodology gives rise to a set of new tools for structured classification, and generalizes the traditional non-structured classification methods. Comparison to standard SVM is done numerically, statistically and by visual inspection of the obtained classification maps. Good results are obtained in the challenging case of a multispectral image of very high spatial resolution acquired with QuickBird over a urban area. 相似文献
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Vladimir Ivanovich Lysenko Sergey Bardakhanov Alexey Korchagin Nikolay Kuksanov Alexander Lavrukhin Rustam Salimov Sergey Fadeev Vladislav Cherepkov Mikhail Veis Andrey Nomoev 《Bulletin of Materials Science》2011,34(4):677-681
Electron-beam evaporation of various natural and industrial materials in the atmosphere of different gases at atmospheric pressure can be used for the synthesis of nanosize powders. These powders are characterized by high purity and may exhibit unusual properties. In particular, nanopowders of silicon dioxide and oxide (SiO2, SiO), magnesia (MgO), alumina (Al2O3), titania (TiO2), gadolinium oxide (Gd2O3), various metals (tantalum, molybdenum, nickel, aluminium, copper, silver), semiconductor (Si), nitrides (AlN, TiN), and some other substances had been produced. The process of nanopowder synthesis is highly effective; in particular, the yield of oxides can exceed ten kilograms per hour. 相似文献
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Marina A. Katkova Tatyana V. Balashova Alexander A. Maleev Vasilii A. Ilichev Alexey N. Konev Georgy K. Fukin Alexander S. Mitin Sergey Yu. Ketkov Mikhail N. Bochkarev 《Synthetic Metals》2010,160(23-24):2476-2480
Efficient yellow–green electroluminescence emission at λmax = 530 nm with CIE coordinates x = 0.3913, y = 0.4947 was obtained with organic light-emitting devices based on tris(2-methyl-8-quinolinolate) scandium (1). The device with the configuration of indium tin oxide/N,N′-bis(3-methylphenyl)-N,N′-diphenylbenzidine/1/Yb exhibits current efficiency of 3.1 cd/A and power efficiency of 1.8 lm/W at a luminance of 100 cd/m2. The DFT calculations demonstrate that structural changes of the scandium complex 1 influence the electroluminescence spectrum, the better agreement with experimental data being achieved when monodentate ligands are taken into consideration. 相似文献
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Studying of cellular interaction of hairpin‐like peptide EcAMP1 from barnyard grass (Echinochloa crusgalli L.) seeds with plant pathogenic fungus Fusarium solani using microscopy techniques 下载免费PDF全文