Mechanochemical tuning of molecular weight distribution of styrene homopolymers as postpolymerization modification in solvent-free solid-state

Mechanochemical degradation by planetary ball milling (PM) is used for postpolymerization modification of styrene homopolymers (PS). A complete factorial design was chosen to study the effect of radical scavengers, milling time, initial molecular weight, and revolution radius (R_p), on the shape of molecular weight distributions (MWDs) of PS. Size-exclusion chromatography analysis shows the feasibility of fine-tuning MWD of PS at up to 40% conversion. Distributions ranged from unimodal to bimodal in a PM with R_p = 150 mm at different stage of milling, whereas in a PM with R_p of 60.8 mm the adjustment of unimodal distributions is achieved. Initial polydispersity is more important to develop bimodal distributions when compared with initial molecular weight. Fourier transform infrared and X-ray electron spectrometry analysis show some suppression of PS degradation and complete oxidation inhibition of macromolecular radicals with the incorporation of radical scavengers, which we considered as additional aids when adjusting the MWDs.     

Post-embryonic development of the antennal sensilla in Melipona quadrifasciata anthidioides (Hymenoptera: Meliponini)

The sensilla are sensory organs formed by cuticular and cellular structures specialized in reception of chemical and physical stimuli from the environment and transmission to the insect's central nervous system. In function of the great concentration of sensilla, the antennae are the main organs for interaction between bees and with the environment. This work studied the presence of antennal sensilla in the different phases of pupal development of the stingless bee Melipona quadrifasciata anthidioides by means of scanning electron microscopy and light microscopy. The results showed that antennal sensilla begin their development in the transition of the prepupae to the white-eyed pupae and finish it in the pigmented-body pupae phase. The antennal sensilla were exposed to the environment in the black-eyed pupae when the old cuticle is completely digested, suggesting that only in the final pupal phases can these bees perceive the environmental stimuli.     

Path integral study of the 4He wetting transition

The ⁴ He wetting transition on a Cs surface is for the first time studied by Path Integral Monte Carlo simulation. Numerical results for a system of 64 ⁴ He atoms are qualitatively consistent with a wetting transition at a temperature T 2 K.     

LCMine: An efficient algorithm for mining discriminative regularities and its application in supervised classification

In this paper, we introduce an efficient algorithm for mining discriminative regularities on databases with mixed and incomplete data. Unlike previous methods, our algorithm does not apply an a priori discretization on numerical features; it extracts regularities from a set of diverse decision trees, induced with a special procedure. Experimental results show that a classifier based on the regularities obtained by our algorithm attains higher classification accuracy, using fewer discriminative regularities than those obtained by previous pattern-based classifiers. Additionally, we show that our classifier is competitive with traditional and state-of-the-art classifiers.     

Coherency Hub Design for Multisocket Sun Servers with CoolThreads Technology

CoHub, a coherency hub ASIC, provides a cost-effective way to extend a glueless two-node chip-multithreading system to a four-node system without changes to the processor. The four-node, 256-thread system achieves near-linear scaling of performance with thread count on transaction-processing workloads. Time-to-market pressure, 800-MHz operation, and a six-stage pipeline were among the constraints that shaped CoHub's design.     

Thermal conductivity measurements and molecular association in a series of alcohol vapors: Methanol,ethanol, isopropanol,and t-butanol

Thermal conductivity measurements on the vapors of methanol, ethanol, isopropanol, and t-butanol are reported as a function of temperature (330–420 K) and pressure (11–240 kPa). The thermal conductivity versus pressure isotherms for all four alcohols exhibit upward curvatures at the lower temperatures and nearly linear increases at higher temperatures. This behavior is indicative of a dimeric species and one or more polymeric clusters in the vapor in addition to the monomer. Quantum mechanical calculations have indicated that tetramers are the most likely polymeric species. Detailed analyses of the data provide thermodynamic data (H,S) for the dimerization and tetramerization reactions and show interesting correlations with the size of the monomer unit.