CpTi(dbm)Cl_2催化烯烃聚合及其聚合物性质

开发了一种新型非茂聚烯烃催化剂———CpTi(dbm)Cl2,考察了催化剂在均相及负载条件下对乙烯及乙烯-1-己烯共聚的催化行为。催化剂在均相条件下对乙烯聚合的催化活性较低,但用MgCl2和MgCl2/SiO2复合双载体对催化剂进行负载后,催化乙烯聚合具有非常好的催化活性。催化剂还具有良好的共聚能力及良好的氢调敏感性。     

焦化DCS控制系统的设计与实现

以某公司焦化厂焦化DCS控制系统为例，从DCS系统的选型、设计、实施等几方面。阐述焦化DCS控制系统的设计与实现。     

蜘蛛丝力学性能的多变性

为进一步探索蜘蛛丝的成丝机理，研究了不同个体大小，不同生存方式，不同环境湿度的大腹圆蛛牵引丝的拉伸性能。结果表明，蜘蛛对其丝纤维的结构和性能具有自我调控能力，随着环境，自身条件，生存方式等成丝条件的变化，蜘蛛牵引丝的力学性能也会发生相应的变化。     

Porosity distribution in highly compressible cake: Experimental and theoretical verification of the dense skin

The rate of filtration and the water content of cake are influenced by the existence of a dense skin in a highly compressible cake. The phenomenon of the dense skin has been rarely studied, and its existence has not been verified experimentally. In this study, the porosity variation in a very compressible cake is measured by using a new experimental apparatus, and with this the existence of dense skin has been established experimentally. ‘Unified theory on solid-liquid separation’, a recently developed theory, is utilized for calculating the porosity variation in a very compressible cake.     

地面驱动螺杆泵恒液面控制方法

恒液面控制有利于提高泵效,降低抽油杆柱和泵等设备的失效率。为此结合地面控制装置,研究了一种控制方法和软件。该软件根据控制装置实时测量的转速、扭矩等参数并结合地层开采能力、杆泵型号等参数,分析计算出液面高度和控制范围,并计算出转速改变量,由控制装置实行闭环控制。经大庆油田5口井试验表明,液面高度误差均在50 m内,实现了螺杆泵恒液面控制目的。     

静载荷和疲劳载荷作用下 C/Al 正交层压板的力学响应

本文讨论静载荷及疲劳载荷作用下 C/Al 正交层压板的力学响应,并考虑损伤过程中的临界现象,以此作为结构设计准则的基础。对静载荷作用的情况:(1)90°铺层的门槛应变ε_(FPF)随着约束程度增加而增加,而且开裂后的行为也受约束程度的影响。(2)经历加载-卸载再重新加载至断裂的过程后,初始试样存在一个剩余永久变形,其损伤状态可以用刚度的变化来表征;而疲劳试样在加载-卸载过程中刚度变化很小,反映其损伤达到一个稳定的状态。对疲劳载荷作用的情况:(1)对于给定的应力比 R,试样会趋于与它所承受的 S_(max)最大值相应的 SDS 状态。循环应力范围的不断增大,会引起基体损伤的增加,从而重新建立新的饱和损伤状态。(2)对于每一损伤状态均有一对应的循环应变范围 Δε。在 SDS 状态下,Δε保持不变。(3)以刚度下降为损伤参数对 C/Al 层压板进行了降级应力分析,并由此来预计在ΔS_(sh)以下,层压板不会发生疲劳损伤累积。     

激光角膜矫正术中所用激光波长的选择

用分光光度计测定了12例兔角膜和1例人角膜的吸收光谱,结果表明波长小于300nm的准分子激光和波长在1.88μm～2.64μm,2.36μm～40μm的激光,均可对角膜进行切割并可望用于激光角膜矫正术。     

Nested polymerase chain reaction (PCR) and multiple cloned antibody capture PCR for the examination of serum hepatitis B virus DNA in negative hepatitis B surface antigen patients suffering from liver diseases

In order to find out rapidly the causes of the liver diseases suffered by patients with negative hepatitis B surface antigen (HBsAg), nested polymerase chain reaction (PCR) and multiple cloned antibody capture PCR techniques were established to examine serum hepatitis B virus (HBV) DNA. By using both techniques along with the examination of hepatitis C virus (HCV) infection, the causes of chronic liver diseases with negative HBsAg were studied. It is found that nested-PCR can increase the sensitivity of single PCR more than 1,000 fold and multiple cloned antibody capture-PCR can detect concentration of HBV DNA as low as 0.1-0.01 pg/L. HBV DNA positive patients were found in 45.5%, 30.8%, 13.3% and 100% respectively of the patients suffering from liver cirhosis with negative HBsAg (group A, 22 cases), chronic hepatitis with negative HBsAg (group B, 13 cases), normal subjects with negative HBsAg and positive hepatitis B core antibody (HBcAb, group C, 30 cases) and liver cirhosis with positive HBsAg and negative HBeAg (group D, 12 cases). HBV DNA can be also found in the serum of HBsAb positive patients and subjects supposed to be healthy, 81.8% and 53.8% of the patients were infected with HBV and/or HCV in group A and group B respectively. All these results suggest that nested-PCR and multiple cloned antibody capture-PCR are rapid and highly sensitive methods for detection of serum HBV DNA. HBV infection is an important cause of chronic liver diseases in patients with negative HBsAg. The causes of most of the HBsAg-negative chronic liver diseases are related with infection of viruses. The clinical significance of serum HBsAb in naturally infected patients should be reconsidered.     

利用射线路径反演层状介质速度的方法

本文根据欧拉方程对于连续层状介质进行了方程推导，得出一个波传播的射线路径公式，利用中 公式导出了ＶＳＰ资料处理中的速度反演公式。     

一种按时间切换的最速控制方法

基于初始状态空间下的子空间概念，提出了一种按时间进行切换的最速控制方法，不需要求取开关线或开关面。数字仿真结果表明，采用这一方法是完全可行的。