500 MPa级门架型钢的奥氏体晶粒长大行为

为探究加热温度和保温时间对500 MPa级门架型钢奥氏体晶粒尺寸的影响,以两种不同成分试验钢为研究对象,采用了SK型管式加热炉分别将试验钢加热到1000~1200 ℃下保温15、30 min,快速冷却后对组织进行观察。结果表明,奥氏体晶粒尺寸随着加热温度的升高和保温时间的延长而长大,Cr元素的添加对奥氏体晶粒的长大具有一定的抑制作用,研究结果对制定大生产加热具有实际指导作用。     

提高轻苯回收率途径的探讨

安阳钢铁集团有限责任公司焦炉煤气回收苯有两个系统,均采用洗油洗苯和堂式炉加热脱苯工艺,两系统洗苯塔均采用填料塔,但二系统洗苯塔后煤气含苯明显高于一系统洗苯塔后含苯即二系统洗苯塔吸收效率不佳,进行原因分析,验证,对策实施,提高苯的回收率。     

Hypercrosslinked polystyrene microspheres with bimodal pore size distribution and controllable macroporosity

A combination of suspension polymerization and postcrosslinking was used to prepare hypercrosslinked polystyrene (H‐PS) microspheres with controllably bimodal pore size distribution in the presence of toluene and polypropylene (PP) as a coporogen. The proportion of PP in the coporogen was changed to investigate the influence of the coporogen composition on the pore structure of the H‐PS microspheres. The addition of a small amount of PP achieved the aim of a clearly bimodal pore size distribution and the control of the macroporosity of the H‐PS microspheres, which have potential application in the preparation of catalyst supports. The specific surface area of the H‐PS microspheres could be adjusted in the range 380–790 m²/g by changes in the concentration of PP in the coporogen. Moreover, the H‐PS microspheres displayed all the characteristics of Davankov‐type resins by their ability to be swollen in both thermodynamically poor solvents such as water and good solvents such as toluene. Finally, the possible mechanism of porosity formation during polymerization and postcrosslinking was also examined by a combination of pore structure data and the appearance of the microspheres before and after postcrosslinking. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Experimental Investigation of the Isothermal Section in Fe-Gd-Pd Ternary System at 873 K

Isothermal section of Fe-Gd-Pd ternary system at 873 K has been established by means of x-ray diffraction (XRD), differential scanning calorimetry (DSC), and scanning electron microscope (SEM) with energy disperse x-ray spectroscopy (EDS) in backscattered electron imaging modes. The isothermal section consists of 14 single-phase regions, 25 two-phase regions, and 12 three-phase regions. At 873 K, no ternary compound was found and the binary inermetallic compounds Gd₃Pd and Fe₂₃Gd₆ are not stable, whereas the compound Fe₂₃Gd₆ decomposes into compounds Fe₁₇Gd₂ and Fe₃Gd. The XRD and the SEM/EDS analysis show that there is almost no solubility of Gd in the FePd and FePd₃ phases, and the solubilities of Pd in Fe₁₇Gd₂, Fe₃Gd and Fe₂Gd and Fe in GdPd₂, α-Gd₃Pd₄ and Gd₃Pd₂ are all less than 1 at.%. Meanwhile, the solubilities of Fe in GdPd₃, α-GdPd and Gd₇Pd₃ are determined to be as high as 1.37, 5.31, and 4.18 at.% Fe, respectively.     

我国改性聚氨酯的研究现状

综述了我国改性聚氨酯的主要分类,重点介绍了环氧树脂改性聚氨酯、聚丙烯酸酯改性聚氨酯、无机碳纳米管改性聚氨酯、有机硅改性聚氨酯等的研究进展,最后指出了我国改性聚氨酯今后发展方向。     

改性SiO_2粒子制备超疏水表面的研究

通过改性SiO2粒子和其他几种物质共混配制涂料,在PVC膜材上进行涂层烘干并焙烘,获得超疏水涂层表面。讨论了几种物质的用量对表面性能及形态的影响;初步探索了表面微结构对接触角的影响。利用改性SiO2粒子成功制备出了超疏水表面;获得了最佳涂层工艺条件;结构的粗糙度对接触角有着直接的影响。     

Chemical looping gasification of sewage sludge using copper slag modified by NiO as an oxygen carrier

Chemical looping gasification (CLG) provides a novel approach to dispose the sewage sludge. In order to improve the reactivity of the calcined copper slag, NiO modification is considered as one of the good solutions. The copper slag calcined at 1100 ℃ doped with 20 wt% NiO (Ni20-CS) was used as an oxygen carrier (OC) in sludge CLG in the work. The modification of NiO can evidently enhance the reactivity of copper slag to promote the sludge conversion, especially for sludge char conversion. The carbon conversion and valid gas yield (V_g) increase from 67.02% and 0.23 m³·kg^-1 using the original OC to 78.34% and 0.29 m³·kg^-1 using the Ni20-CS OC, respectively. The increase of equivalent coefficient (Ω) facilitates the sludge conversion and a suitable Ω value is determined at 0.47 to obtain the highest valid gas yield (0.29 m³·kg^-1). A suitable steam content is assigned at 27.22% to obtain the maximum carbon conversion of 87.09%, where an acceptable LHV of 12.63 MJ·m^-3 and V_g of 0.39 m³·kg^-1 are obtained. Although the reactivity of Ni20-CS OC gradually decreases with the increase in cycle numbers because of the generation of NiFe₂O_4-δ species, the deposition of sludge ash containing many metallic elements is beneficial to the sludge conversion. As a result, the carbon conversion shows a slight uptrend with the increase of cycle numbers in sludge CLG. It indicates that the Ni20-CS sample is a good OC for sludge CLG.     

CuO对BaTiO3基PTC材料性能的影响

通过阻温测试、介温测试及XRD等测试分析手段,研究了CuO的加入对BaTiO3基PTC材料性能的影响,结果表明:加入0.1mol%的CuO可以明显改善材料的PTC效应,升阻比提高到106;CuO的加入可明显降低烧结温度,当CuO的加入量为4mol%时,烧结温度降低65℃,最低烧结温度为1210℃;加入2.0mol%的CuO,材料的居里温度提高了近40℃,同时CuO的加入能提高材料的介电常数,并有压峰作用,对高介电常数材料的研究有一定的意义。     

Effects of Zn substitution on high-frequency properties of Ba1.5Sr1.5Co2-xZnxFe22O41 hexaferrites

Ba_1.5Sr_1.5Co_2-xZn_xFe₂₂O₄₁(x = 0,0.4,0.8,1.2,1.6,2.0) hexaferrites substituted by Zn were prepared via conventional solid-state reaction. The influences of Zn substitution content on phase formation, microstructure, and magnetic properties, especially high-frequency magnetic properties, were systematically investigated. Results indicate that, when sintering temperature is 1200 °C, pure ferrite phase of Co₂Z is formed, and Zn²⁺ is successfully incorporated into the lattice. Appropriate amount of Zn substitution can improve the densification and saturation magnetization ($M_s$) of Z-type ferrite, thereby effectively promoting permeability. However, due to limitations of Snoek's law, cut-off frequency is found to be reduced with Zn substitution. For x = 0.4, the sample exhibits both high permeability (up to 22.49) and high cut-off frequency (~900 MHz), with Snoek constant $({\mu }_i?1)\times f_r$ reaching 19.337 GHz. Furthermore, magnetic loss for the sample with x = 0.4 is found to be low. It is anticipated that this material will have extensive application prospects for miniaturization and high frequency antenna applications.     

Cr对20MnSiV门架型钢动态CCT曲线和性能的影响

利用热膨胀相变仪研究了不含Cr和含0.3％(质量分数)Cr的叉车门架用20MnSiV钢的连续冷却转变行为,通过光学显微镜观察试验钢在不同冷速下的显微组织,并检测其维氏硬度,得到了试验钢的动态连续冷却转变(CCT)曲线.结果表明,0.1～10℃/s的冷速范围内,试验钢在添加0.3％Cr后,贝氏体转变的临界冷速降低,综合力...