含泥砂河流水轮机增容改造的探讨─刘家峡2~＃水轮机增容改造

本文简要叙述了刘家峡电厂水轮机增容改造中的水力研究、结构设计、中间试验、材料选择以及制造工艺等方面内容,并探讨了减轻泥砂磨蚀的措施。该水轮机的增容改造经验对含泥砂河流水轮机的设计与改造是有益的。     

基于1.55μm激光雷达的晴空风切变结构研究北大核心CSCD

晴空风切变是公认的航空危险天气。为了研究155μm激光测风雷达对晴空风切变的探测效果,利用激光测风雷达数据,结合自观系统实时风场数据,对2022年2月13日影响银川机场的晴空风切变过程进行详细分析。激光雷达探测结果表明风切变发生前高空偏北风有下沉特征,动量下传导致地面北风增强;此次风切变由东北风与西南风交汇形成,东北大风呈楔形从近地层嵌入,形成水平风切变,随后向西南传播影响机场跑道。预报员利用激光测风雷达可以提前15min对此次风切变进行预警。     

基于子模块电容电压允许值的MMC均压控制策略

针对模块化多电平变换器（modular multilevel converter,MMC）传统子模块（sub-module,SM）均压策略存在的开关频率高、开关损耗量多、计算量大等问题,提出基于子模块电容电压允许值的均压控制策略。通过引入电容电压允许值变量,使得SM电压始终在规定的范围内运行,降低了功率器件损耗。与此同时,由于不需要每个控制周期对全部SM进行排序,进一步减少了控制策略的计算量。通过仿真结果验证了所提策略的有效性,可以显著减少单位时间内功率器件的开关次数。     

考虑同步机调差系数灵敏度与频率约束的机组组合

为解决高比例新能源并网带来的系统惯量水平降低及频率安全问题,有必要从同步机的角度出发,进一步发挥同步机组的调频能力,提高系统的频率稳定。考虑系统中各同步机组频率支撑能力的不同,基于灵敏度的方法分析不同机组调差系数的改变对最大频率偏差的影响程度。综合考虑同步机与风机参与调频,推导最大频率偏差的解析表达式。在考虑频率安全约束的基础上,提出考虑同步机调差系数灵敏度的多目标机组组合模型,并采用快速非支配多目标优化算法(non-dominated sorting genetic algorithms-II, NSGA-II)进行模型求解。仿真结果表明,所提模型在考虑频率约束的机组组合模型基础上,进一步发挥了同步机组的调频能力,抑制了最低点频率的跌落,改善了系统的频率响应。     

基于柔性多状态开关和动态重构的配电网灵活运行方法

未来电动汽车(electric vehicle, EV)以及光伏(photovoltaic, PV)在配电网中的接入比例逐渐增高,这不仅带来了复杂的不确定性问题,而且导致了配电网净负荷时空分布的不均衡,从而产生了弃光、失负荷以及潮流分布不均匀的问题。基于此,考虑电动汽车充电负荷以及光伏的不确定性,提出了一种基于柔性多状态开关(flexible multi-state switch, FMS)和动态重构的含高比例电动汽车-光伏配电网灵活运行方法。首先,基于FMS灵活功率调控和网络动态重构,构建了支撑高比例电动汽车-光伏接入的配电网灵活运行框架。其次,利用蒙特卡洛随机模拟法对各类电动汽车充电负荷以及光伏出力进行不确定性建模,建立了基于场景集以及场景缩减法的随机规划模型。然后,建立了以弃光、失负荷、FMS损耗、网损成本最小和负荷均衡度最优为目标的配电网灵活运行模型。最后,在158节点系统上通过算例验证了所提方法的有效性。     

Floating Catalyst Chemical Vapor Deposition Patterning Nitrogen-Doped Single-Walled Carbon Nanotubes for Shape Tailorable and Flexible Micro-Supercapacitors

Micro-supercapacitors (MSCs) as high-power density energy storage units are designed to meet the booming development of flexible electronics, requiring simple and fast fabrication technology. Herein, a fast and direct solvent-free patterning method is reported to fabricate shape-tailorable and flexible MSCs by floating catalyst chemical vapor deposition (FCCVD). The nitrogen-doped single-walled carbon nanotubes (N-SWCNTs) are directly deposited on a patterned filter by FCCVD with designable patterns and facilely dry-transferred on versatile substrates. The obtained MSCs deliver an excellent areal capacitance of 3.6 mF cm⁻² and volumetric capacitance of 98.6 F cm⁻³ at a scan rate of 5 mV s⁻¹ along with excellent long-term cycle stability over 125 000 circles. Furthermore, the MSCs show good performance uniformity, which can be readily integrated via connection in parallel or series to deliver a stable high voltage (4 V with five serially connected devices) and large capacitance (5.1 mF with five parallel devices) at a scan rate of 100 mV s⁻¹, enabling powering the light emitting displays. Therefore, this method blazes the trail of directly preparing flexible, shape-customizable, and high-performance MSCs.     

Stabilizing Redox-Active Hexaazatriphenylene in a 2D Conductive Metal–Organic Framework for Improved Lithium Storage Performance

Organic redox-active materials are promising electrode candidates for lithium-ion batteries by virtue of their designable structure and cost-effectiveness. However, their poor electrical conductivity and high solubility in organic electrolytes limit the device's performance and practical applications. Herein, the π-conjugated nitrogen-containing heteroaromatic molecule hexaazatriphenylene (HATN) is strategically embedded with redox-active centers in the skeleton of a Cu-based 2D conductive metal–organic framework (2D c-MOF) to optimize the lithium (Li) storage performance of organic electrodes, which delivers improved specific capacity (763 mAh g⁻¹ at 300 mA g⁻¹), long-term cycling stability (≈90% capacity retention after 600 cycles at 300 mA g⁻¹), and excellent rate performance. The correlation of experimental and computational results confirms that this high Li storage performance derives from the maximum number of active sites (CN sites in the HATN unit and CO sites in the CuO₄ unit), favorable electrical conductivity, and efficient mass transfer channels. This strategy of integrating multiple redox-active moieties into the 2D c-MOF opens up a new avenue for the design of high-performance electrode materials.     

Interfacial Proton Supply/Filtration Regulates the Dynamics of Electrocatalytic Nitrogen Reduction Reaction: A Perspective

As a promising energy carrier, ammonia synthesis by electrocatalytic nitrogen reduction reaction (eNRR) is a promising green and low-carbon ammonia synthesis strategy that can replace the traditional Haber–Bosch process. However, the development of eNRR processes is mainly severely constrained by competitive hydrogen evolution reaction (HER), and the corresponding strategies to inhibit this adverse side reaction to obtain high eNRR selectivity are still limited. In addition, for this complex reaction involving gas–liquid–solid three-phase interface and proton/electron transfer, it is great significance to analyze and summarize the existing inhibition HER strategies from the viewpoint of dynamics. In view of this, this work reviews proton supply/filtration regulation strategy in catalytic system, allowing a systematic survey of the literature focusing on interface membrane regulation (inorganic membrane and organic membrane), electrolyte regulation (metal-mediated strategy and electrolyte ion regulation strategy) and system device design (electrode structure design and electrolytic cell device design). Constructive catalytic system design guidance is also suggested to inhibit hydrogen evolution and improve NH₃ selectivity, aiming for scalable and economically feasible applications.