Binary polymer blend of ArPTU/PI with advanced comprehensive dielectric properties and ultra-high thermally stability

Flexible high-temperature polymeric dielectrics with advanced dielectric properties are urgently demanded in various applications. In this work, series of polymer blend films were prepared from aromatic polythiourea (ArPTU) and polyimide (PI). The experimental results revealed that the blend films were properly engineered to achieve higher breakdown strength, greater dielectric constant, and larger energy density than pure PI film. For instance, the optimum property was obtained from the blend film with 10 wt% ArPTU, exhibiting prominent dielectric properties (K = 4.52, E_b = 443 MV/m), enhanced energy density (4.00 J/cm³) as well as excellent heat resistance (T_g = 419°C). In addition, stable dielectric properties at broad temperature range from −50 to 250°C were also acquired. It is deduced that the good compatibility from ArPTU and PI with similar polarity are responsible for the improved properties. The superior comprehensive properties which combine the advantages of ArPTU and PI suggest the potential applications of ArPTU/PI blend film in high-temperature dielectric areas.     

Influence of deposited amine-functionalized Si-MCM-41 in polyacrylonitrile electrospun membranes applied for separation of water in oil emulsions

Among several oil/water emulsion separation technologies, the utilization of nanoparticle-decorated membranes with diverse functionalities has received considerable attention in recent years, particularly if the antifouling capacity can be improved. In this article, we propose a new membrane based on surface-hydrolyzed polyacrylonitrile electrospun membranes and/or decorated with amine-functionalized Si-MCM-41 nanoparticles to be used as oil/water emulsion separation treatment and to determine their antifouling ability. X-Ray photoelectron spectrometry, attenuated total reflectance Fourier transform infrared spectroscopy, and toluidine blue O assay, scanning electron microscopy, contact angle measurements for oil under water and thermogravimetry were used for characterizing the membranes and an assay of permeability was developed to quantify the diffusion of oil molecules across the electrospun membrane. The electrospun and/or decorated membranes showed an underwater oleophobic wettability, which can separate oil-in-water emulsions with 87% separation efficiency, results of fouling experiments, evaluated in terms of rejection and flux recovery ratio, exhibited good antifouling ability, but the membrane decoration process did not lead to superior outcomes compared with undecorated membranes.     

Enginered Interfaces for Adherent Coatings

ＥｎｇｉｎｅｒｅｄＩｎｔｅｒｆａｃｅｓｆｏｒＡｄｈｅｒｅｎｔＣｏａｔｉｎｇｓＨｏｕＱｉｎｇｒｕｎａｎｄＧａｏＪｕ（侯清润）（高炬）ＤｅｐａｒｔｍｅｎｔｏｆＰｈｙｓｉｃｓ，ＴｈｅＵｎｉｖｅｒｓｉｔｙｏｆＨｏｎｇＫｏｎｇ，ＰｏｋｆｕｌａｍＲｏａｄ，Ｈｏｎ...     

一种钛合金冷拉伸用润滑涂层研制

采用化学方法研制出1种新的冷拔用润滑剂涂层，该表面涂层与钛基材结合力强，表面呈灰色，主要成分为Na3TiOF5。该涂层与石墨乳和二硫化钼混合配套使用可大大减小拉伸摩擦阻力，提高钛材表面质量。     

阴极保护用阳极

介绍了牺牲阳极材料中镁基、锌基、铝基阳极的化学成分和性能特点，以及多种外加电流阴极保护用阳极材料的特点。通过对石墨阳极、高硅铸铁阳极和铅银合金阳极、镀铂阳极和混合金属氧化物阳极的性能比较，认为混合金属氧化物阳极是最为理想和最有前途的辅助阳极材料。     

基于ProCAST的消失模铸造工艺的数值模拟研究

运用ProAST软件对链轮铸钢件的消失模铸造工艺进行了充型和凝固过程的数值模拟评价,分析了缺陷产生的原因,对铸造工艺进行了优化,并结合实际生产情况,给出了影响消失模铸造的六大基本因素。     

阿根廷Φ139.7mm套管探伤缺陷的解剖分析

中原油田所用的阿根廷套管大量不合格，对其进行无损探伤和解剖分析后发现，主要缺陷是折叠和大型非金属夹杂物。     

再结晶退火对Ni_（47）Ti_（44）Nb_9合金冷轧板相组成及板材织构的影响

采用Ｘ射线衍射术和ＯＤＦ研究了再结晶退火对Ｎｉ４７Ｔｉ４４Ｎｂ９合金冷轧板相组成和织构的影响。结果表明，冷轧板材的相组成为Ｂ２＋β－Ｎｂ＋Ｂ１９＇；织构类型为面织构｛００１｝ｐ＋｛１１０｝ｐ再结晶退火期间，马氏体相Ｂ１９＇逆转变为母相Ｂ２，合金的相组成为：Ｂ２十β－Ｎｂ，而再结晶织构为：｛００１｝＜１１０＞ｐ。     

钨板轧制的轧制力模型研究

为了使钨板轧制过程中的各项轧制参数得到有效控制，对钨板轧制数学模型进行了研究。首先在Gleeble热模拟机上进行热压缩试验，研究了变形抗力与各种变形条件的关系，确定了变形抗力模型：通过550mm轧机轧制钨板时采集到的有关数据，建立了应力状态影响系数数学模型、变形区长度等模型：最终建立了550mm钨板轧机轧制力模型。利用模型计算值与实际测量参数进行了对比，结果比较满意。     

铝电解槽内衬热阻与电流效率的关系

介绍了热阻的概念 ,并以我厂四种形式内衬结构为例 ,计算了热阻 ,列出了热阻与电流效率的关系 ,并指出合理设计内衬热阻 ,有利于电流效率的提高