黑釉铁锈花产品的试制

本文论述了黑釉铁锈花产品的坯釉料组成及制作工艺．井对黑釉铁锈花产品的起源、形成机理进行了探讨分析。     

Starch,Sucrose, and Rezol® IL800 as Density Modifiers for Polyurethane Rigid Foams Formulated by Recycled Polyol

Waste polyurethane rigid foam (PUF) is recycled by the glycolysis process. The recycled product is used in a polyol blend, applied in a new foam formulation. Polyurethane rigid foams formulated by recycled polyols are highly dense compared to rigid foams formulated by virgin polyols. As these foams are mostly used in insulation, they make an extra mass to the main product or system that is insulated. Therefore, it is important to decrease their density as much as possible.

Some density modifiers such as starch, sucrose, and REZOL^® IL800 were investigated to recognize their effect on PUF's density.     

Radiation crosslinking and sorption properties of hydrogels based on 1‐vinyl‐2‐pyrrolidone,hydroxyethyl methacrylate,and their copolymers

This work has been concerned with the synthesis of the hydrogels of poly (vinyl pyrrolidone) (NVP), poly (hydroxy ethylmethacrylate) (HEMA), and their copolymer under the effect of gamma radiation in the presence of N,N‐methylenebisacryl‐amide (MBAm) as a crosslinking agent. The effect of the different factors that may affect the gelation and yield product, such as solvent composition and irradiation dose, was investigated. The formed hydrogels were characterized in terms of swelling in water and different organic solvents, X‐ray diffraction (XRD), and IR spectroscopic analysis. The sorption capability of these hydrogels towards some commercial basic and acid dyesstuffs was also studied. The results showed that a solvent mixture composed of equal contents of water and methanol is the most suitable to afford the minimum sol fraction and the highest yield product at a minimal irradiation dose of 10 kGy. It was observed that NVP hydrogel displayed the highest swelling in water, alcohols, and dimethyformamide of ～1300% and a lower tendency to swell in nonpolar solvents. The results showed that HEMA hydrogel has a high affinity to absorb basic dyes while NVP has a tendency for acid dyes. Also, the sorption of either the basic or acid dyes by the different hydrogels was found to greatly depend on the concentration of dye in solution and the mass of the used hydrogel. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3274–3280, 2004     

Chemical structure of autoignition in a turbulent lifted H2/N2 jet flame issuing into a vitiated coflow

In the present paper autoignition is studied as the main stabilization mechanism in turbulent lifted H₂/N₂ jet flames issuing into a vitiated hot coflow. The numerical study is performed using the joint scalar PDF approach with detailed chemistry in a two dimensional axisymmetric domain. The SSG Reynolds stress model is used as a turbulence model in the simulation. Chemical structure and characteristics of autoignition are investigated using various methods and parameters. Reaction rate analysis is made to analyze the ignition process at the flame base. The results show the occurrence of a chain branching reaction preceding thermal runaway, which boosts the chain branching process in the flame. This demonstrates the large impact of autoignition at the flame base on the stabilization of the lifted turbulent flame. Further investigation using the scatter-plots of scalars reveals the characteristics of the ignition. The relation between the behavior of temperature and of key intermediate species demonstrates the formation of OH through consumption of HO₂ at nearly isothermal conditions in a very lean-fuel mixture at the flame base. Flux analyses in the conservation equations of species are used to explore the impacts of mass transport on ignition process. Ignition is found to be mainly controlled by chemical features rather than the mixing processes near the flame base. Characteristics of autoignition are also investigated in terms of Damköhler number and progress variable.     

Analysis of autoignition of a turbulent lifted H2/N2 jet flame issuing into a vitiated coflow

Due to energy crisis and concern regarding the environmental emission, hydrogen as an alternative clean fuel has received more attention. To develop new devices or upgrade the conventional combustion systems for hydrogen flames, fundamental concepts necessary for burner design need to be investigated. In the present work, characteristics of flame stabilization for a turbulent lifted H₂/N₂ jet flame issuing into a hot coflow of lean combustion are investigated using the Scalar probability density function (PDF) approach. Calculations are carried out for different coflow temperatures, concentrations of species and equivalence ratio. Reaction rate analyses are used to investigate the dominant chemistry at the flame base for a variety of conditions. The results show the occurrence of autoignition at the flame base that is responsible for the stabilization of the lifted turbulent flame. The coflow temperature plays an important role in the relative contribution of elementary reactions and the determination of the dominant chemistry at the flame base. This leads to a high sensitivity of lift-off height to the coflow temperature. Oxygen and water content in the hot coflow could affect the ignition process and lift-off height depending on the dominant chemistry at the flame base. Furthermore, the effect of oxygen content in hot coflow is found to be very important on the reactions controlling the high temperature combustion.     

Using next generation nuclear power reactors for development of a techno‐economic model for hydrogen production

Nuclear and hydrogen are considered to be the most promising alternatives energy sources in terms of meeting future demand and providing a CO?‐free environment, and interest in the development of more cost‐effective hydrogen production plants is increasing—and nuclear‐powered hydrogen generation plants may be a viable alternative. This paper is a report on investigating the application of new generation nuclear power plants to hydrogen production and development of an associated techno‐economic model. In this paper, theoretical and computational assessments of generations II, III+, and IV nuclear power plants for hydrogen generation scenarios have been reported. Technical analyses were conducted on each reactor type—in terms of the design standard, fuel specification, overnight capital cost, and hydrogen generation. In addition, a theoretical model was developed for calculating various hydrogen generation parameters, and it was then extended to include an economic assessment of nuclear power plant‐based hydrogen generation. The Hydrogen Economic Evaluation Program originally developed by the International Atomic Energy Agency was used for calculating various parameters, including hydrogen production and storage costs, as well as equity, operation and maintenance (O&M), and capital costs. The results from each nuclear reactor type were compared against reactor parameters, and the ideal candidate reactor was identified. The simulation results also verified theoretically proven results. The main objective of the research was to conduct a prequalification assessment for a cogeneration plant, by developing a model that could be used for technical and economic analysis of nuclear hydrogen plant options. It was assessed that high‐temperature gas‐cooled reactors (HTGR‐PM and PBR200) represented the most economical and viable plant options for hydrogen production. This research has helped identify the way forward for the development of a commercially viable, nuclear power‐driven, hydrogen generation plant.