The liquidus surface and tie-lines in the iron-nickel-sulfur system between 1473 and 1673 K

The liquidus compositions and the tie-lines for the solid alloy plus liquid sulfide two-phase region were determined for the iron-nickel-sulfur system in the temperature range 1473 to 1673 K. Experiments were conducted by sampling the liquid sulfide in equilibrium with the alloy phase and chemically analyzing the sulfide. The alloy was quenched and analyzed by electron microprobe. The results represent a significant revision to existing data.     

Corrosion of bio implants

Chemical stability, mechanical behaviour and biocompatibility in body fluids and tissues are the basic requirements for successful application of implant materials in bone fractures and replacements. Corrosion is one of the major processes affecting the life and service of orthopaedic devices made of metals and alloys used as implants in the body. Among the metals and alloys known, stainless steels (SS), Co-Cr alloys and titanium and its alloys are the most widely used for the making of biodevices for extended life in human body. Incidences of failure of stainless steel implant devices reveal the occurrence of significant localised corroding viz., pitting and crevice corrosion. Titanium forms a stable TiO₂ film which can release titanium particles under wear into the body environment. To reduce corrosion and achieve better biocompatibility, bulk alloying of stainless steels with titanium and nitrogen, surface alloying by ion implantation of stainless steels and titanium and its alloys, and surface modification of stainless steel with bioceramic coatings are considered potential methods for improving the performance of orthopaedic devices. This review discusses these issues in depth and examines emerging directions.     

Pervaporation of tertiary butanol/water mixtures through chitosan membranes cross‐linked with toluylene diisocyanate

Membranes made from 84% deacetylated chitosan biopolymer were cross‐linked by a novel method using 2,4‐toluylene diisocyanate (TDI) and tested for the separation of t‐butanol/water mixtures by pervaporation. The unmodified and cross‐linked membranes were characterized by Fourier transform infra red (FTIR) spectroscopy, X‐ray diffraction (XRD) studies and sorption studies in order to understand the polymer–liquid interactions and separation mechanisms. Thermal stability was analyzed by differential scanning calorimetry (DSC) and thermo gravimetric analysis (TGA) while tensile strength measurement was carried out to assess mechanical strength. The membrane appears to have good potential for breaking the aqueous azeotrope of 88.2 wt% t‐butanol by giving a high selectivity of 620 and substantial water flux (0.38 kg m^?2 hr^?1). The effects of operating parameters such as feed composition, membrane thickness and permeate pressure on membrane performance were evaluated. Copyright © 2005 Society of Chemical Industry     

Estimation of low-velocity impact damage in laminated composite circular plates using nonlinear finite element analysis

Nonlinear finite element analysis is used for the estimation of damage due to low-velocity impact loading of laminated composite circular plates. The impact loading is treated as an equivalent static loading by assuming the impactor to be spherical and the contact to obey Hertzian law. The stresses in the laminate are calculated using a 48 d.o.f. laminated composite sector element. Subsequently, the Tsai-Wu criterion is used to detect the zones of failure and the maximum stress criterion is used to identify the mode of failure. Then the material properties of the laminate are degraded in the failed regions. The stress analysis is performed again using the degraded properties of the plies. The iterative process is repeated until no more failure is detected in the laminate. The problem of a typical T300/N5208 composite [45 °/0 °/ − 45 °/90 °]_s circular plate being impacted by a spherical impactor is solved and the results are compared with experimental and analytical results available in the literature. The method proposed and the computer code developed can handle symmetric, as well as unsymmetric, laminates. It can be easily extended to cover the impact of composite rectangular plates, shell panels and shells.     

An algorithm for calculation of the Jordan canonical form of a matrix

Jordan canonical forms are used extensively in the literature on control systems. However, very few methods are available to compute them numerically. Most numerical methods compute a set of basis vectors in terms of which the given matrix is diagonalized when such a change of basis is possible. Here, a simple and efficient method is suggested for computing the Jordan canonical form and the corresponding transformation matrix. The method is based on the definition of a generalized eigenvector, and a natural extension of Gauss elimination techniques.     

Discrimination of pathological voices using a time-frequency approach

Acoustical measures of vocal function are routinely used in the assessments of disordered voice, and for monitoring the patient's progress over the course of voice therapy. Typically, acoustic measures are extracted from sustained vowel stimuli where short-term and long-term perturbations in fundamental frequency and intensity, and the level of "glottal noise" are used to characterize the vocal function. However, acoustic measures extracted from continuous speech samples may well be required for accurate prediction of abnormal voice quality that is relevant to the client's "real world" experience. In contrast with sustained vowel research, there is relatively sparse literature on the effectiveness of acoustic measures extracted from continuous speech samples. This is partially due to the challenge of segmenting the speech signal into voiced, unvoiced, and silence periods before features can be extracted for vocal function characterization. In this paper we propose a joint time-frequency approach for classifying pathological voices using continuous speech signals that obviates the need for such segmentation. The speech signals were decomposed using an adaptive time-frequency transform algorithm, and several features such as the octave max, octave mean, energy ratio, length ratio, and frequency ratio were extracted from the decomposition parameters and analyzed using statistical pattern classification techniques. Experiments with a database consisting of continuous speech samples from 51 normal and 161 pathological talkers yielded a classification accuracy of 93.4%.     

The multiaxial yield behaviour of an aluminium alloy foam

The multi-axial yield behaviour of the aluminium alloy foam Alulight has been measured. Triaxial tests have been performed on a range of relative densities in order to compare the hydrostatic stress versus strain response with the uniaxial compressive response, and to probe the yield surface after prior hydrostatic compression. It is found that the degree of strain hardening in hydrostatic compression exceeds that for uniaxial compression, and the yield surface remains almost self-similar in shape after hydrostatic compaction. The measured yield surface provides support for the phenomenological yield model of Deshpande and Fleck (V. S. Deshpande, N. A. Fleck, Journal of Mechanics and Physics of Solids, 48, (2000), 1253). Upon reviewing the available experimental evidence from this and previous studies it is found that a broad correlation emerges between the relative density and the shape of the yield surface for metallic foams.     

Investigation of the kinetics of reduction of nickel tungstate by hydrogen

In the present work, the kinetics of reduction of nickel tungstate, NiWO₄, by hydrogen was investigated by a thermogravimetric method in the temperature range 891 to 1141 K. The experiments were conducted under both isothermal and nonisothermal conditions. The products were examined by X-ray diffraction analysis. The results indicate that the reduction reaction proceeds in two steps; first, reduction of NiWO₄ to nickel as well as WO₂ and then WO₂ to tungsten. From the isothermal experiments, the activation energies of the two reaction steps were calculated to be 95.3 ± 4.9 and 80.8 ± 6.4 kJ · mol⁻¹, respectively. The activation energy value obtained from nonisothermal experiments for the first step is in agreement with the isothermal experiments. The values are compared with the activation energies reported in other literature for the individual oxides. Formerly with Royal Institute of Technology, Stockholm, Sweden     

Dapsone poisoning

Two cases of suicidal dapsone ingestion are reported. These patients presented with marked cyanosis and had significant methaemoglobinaemia on admission. One patient also had acute psychosis and haemolytic anaemia. Both patients responded to intravenous methylene blue therapy and nasal oxygen inhalation and recovered without any sequelae.     

Effect of particle size on cesium exchange kinetics by K-depleted phlogopite

Cation exchange mechanism and rate of Cs⁺ exchange were investigated in < 2 μm and 20–2 μm particle size fractions of K-depleted phlogopite (Na-phlogopite). The K-depleted phlogopite was prepared from a natural phlogopite by a potassium removal method using sodium tetraphenylborate (NaTPB) at room temperature. X-ray diffraction (XRD) patterns revealed that interlayer K⁺ ions were completely replaced with sodium ions after the potassium removal treatment. Ion exchange isotherms and kinetics were determined for Na⁺ → Cs⁺ exchange with two particle size fractions. The isotherms indicated that both particle size fractions showed high selectivity for Cs⁺. Based on the isotherm tests, ΔG^o values of < 2 μm and 20–2 μm particle fractions were − 6.83 kJ/mol and − 7.08 kJ/mol, respectively. Kinetics of Cs exchange revealed that the 20–2 μm particle size fraction of the K-depleted phlogopite took up more Cs⁺ ions than the < 2 μm particle size fraction. Various kinetic models were applied to describe Na⁺ → Cs⁺ exchange process. Elovich model described the kinetic data of the < 2 μm particle size fraction well, while the modified first-order model or parabolic diffusion model described the data of the 20–2 μm particle size fraction well.