Erosion behavior of EB-PVD 7YSZ coatings under corrosion/erosion regime: Effect of TBC microstructure and the CMAS chemistry

Aero-engines operating in dust-laden environments often encounter a lot of dust/sand that causes a severe problem to the TBCs by means of erosion. As the turbine entry temperatures are rising, molten sand is also a big concern to the life-time of TBCs.This paper deals with the TBC behavior under the combined influence of erosion and corrosion attack. Variations in TBC morphology, CMAS infiltration time and CMAS composition and their influence on the erosion resistance at room temperature were investigated. Two different EB-PVD 7YSZ morphologies consisting of a different porosity arrangement were tested in the erosion/corrosion regime. The more ‘Feathery’ structure has a better resistance to erosion compared to a more columnar ‘Normal’ structure, which leads to less degradation of the TBC. However, under the influence of CMAS infiltration the effect was found to be reversed. In general, CMAS-infiltrated EB-PVD TBCs exhibit a higher erosion resistance than the non-infiltrated ones.     

Crystalline Intermediate Phases in the Sol–Gel-Based Synthesis of La2NiO4+δ

X-ray diffraction and transmission electron microscopy were applied to investigate a sol–gel synthetic process for the mixed oxygen ion and electron conductor La₂NiO_4+δ with a K₂NiF₄ structure type. The development of the La₂NiO_4+δ is elucidated considering the influence of calcination temperatures and dwell times. Following the thermal decomposition of nitrate and organic precursors in an intermediate step, the lanthanum nickel oxide is obtained after a short dwell time above 750°C. This occurs by the transformation of an ultrafinely dispersed powder consisting of lanthanum oxycarbonate, lanthanum oxide, and nickel oxide. The pure La₂NiO_4+δ phase was obtained by similar solid-state reactions between nanocrystalline powder particles at just 950°C.     

A biochemical approach to adaptive service ecosystems

Emerging network scenarios call for innovative open service frameworks to ensure capability of self-adaptability and long-lasting evolvability. In this paper, we assess the need for such innovative service frameworks, and discuss how their engineering should get inspiration from natural ecosystems, i.e., by modelling services as autonomous individuals in an ecosystem of other services and data sources. We introduce a reference conceptual architecture with the goal of clarifying the concepts expressed and framing the several possible nature-inspired metaphors that could be adopted to realise the idea. On this basis, we go into details about one of such possible approaches, in which the rules governing the ecosystem are inspired by biochemical mechanisms. A case study is also introduced to exemplify the potentials of the presented biochemical approach and to experiment with some representative biochemistry-inspired patterns of adaptive service organisation and evolution.     

Time-Resolved Soft X-ray Diffraction Reveals Transient Structural Distortions of Ternary Liquid Crystals

Home-based soft X-ray time-resolved scattering experiments with nanosecond time resolution (10 ns) and nanometer spatial resolution were carried out at a table top soft X-ray plasma source (2.2–5.2 nm). The investigated system was the lyotropic liquid crystal C₁₆E₇/paraffin/glycerol/formamide/IR 5. Usually, major changes in physical, chemical, and/or optical properties of the sample occur as a result of structural changes and shrinking morphology. Here, these effects occur as a consequence of the energy absorption in the sample upon optical laser excitation in the IR regime. The liquid crystal shows changes in the structural response within few hundred nanoseconds showing a time decay of 182 ns. A decrease of the Bragg peak diffracted intensity of 30% and a coherent macroscopic movement of the Bragg reflection are found as a response to the optical pump. The Bragg reflection movement is established to be isotropic and diffusion controlled (1 μs). Structural processes are analyzed in the Patterson analysis framework of the time-varying diffraction peaks revealing that the inter-lamellar distance increases by 2.7 Å resulting in an elongation of the coherently expanding lamella crystallite. The present studies emphasize the possibility of applying TR-SXRD techniques for studying the mechanical dynamics of nanosystems.     

Targeting Mitochondria in Diabetes

Type 2 diabetes (T2D), one of the most prevalent noncommunicable diseases, is often preceded by insulin resistance (IR), which underlies the inability of tissues to respond to insulin and leads to disturbed metabolic homeostasis. Mitochondria, as a central player in the cellular energy metabolism, are involved in the mechanisms of IR and T2D. Mitochondrial function is affected by insulin resistance in different tissues, among which skeletal muscle and liver have the highest impact on whole-body glucose homeostasis. This review focuses on human studies that assess mitochondrial function in liver, muscle and blood cells in the context of T2D. Furthermore, different interventions targeting mitochondria in IR and T2D are listed, with a selection of studies using respirometry as a measure of mitochondrial function, for better data comparison. Altogether, mitochondrial respiratory capacity appears to be a metabolic indicator since it decreases as the disease progresses but increases after lifestyle (exercise) and pharmacological interventions, together with the improvement in metabolic health. Finally, novel therapeutics developed to target mitochondria have potential for a more integrative therapeutic approach, treating both causative and secondary defects of diabetes.     

Steerable miniature jumping robot

Jumping is used in nature by many small animals to locomote in cluttered environments or in rough terrain. It offers small systems the benefit of overcoming relatively large obstacles at a low energetic cost. In order to be able to perform repetitive jumps in a given direction, it is important to be able to upright after landing, steer and jump again. In this article, we review and evaluate the uprighting and steering principles of existing jumping robots and present a novel spherical robot with a mass of 14 g and a size of 18 cm that can jump up to 62 cm at a take-off angle of 75°, recover passively after landing, orient itself, and jump again. We describe its design details and fabrication methods, characterize its jumping performance, and demonstrate the remote controlled prototype repetitively moving over an obstacle course where it has to climb stairs and go through a window. (See videos 1–4 in the electronic supplementary material.)     

More decidable instances of Post's correspondence problem: beyond counting

We present a new technique to decide or reduce instances of Post's correspondence problem. It generalizes balance arguments to a consideration about some special context-free languages which allow the combination with other decision (or reduction) techniques. In spite of its simplicity, the new technique is able to decide more instances than known techniques.     

Soft information and the stewardship value of accounting disclosure

In light of IASB??s statement to drop stewardship as a separate objective of financial accounting and the ongoing debate about increasing the disclosure of soft information, we investigate the economic consequences of publicly reported soft information from a stewardship perspective. In an LEN model we include market price as a performance measure and investigate whether the principal benefits from disclosing additional information. While the principal can only use contractible performance measures in the contract with the agent, capital market participants can only use disclosed information when pricing firm value. We find that the disclosure of information can decrease the principal??s expected net profit. This result follows from either a noisier or a less congruent market price as a consequence of disclosing additional information. Thus, we present a rationale for partial disclosure in the absence of proprietary costs or the uncertainty of information endowment.