Hydrolysis of tetracalcium phosphate in H3PO4 and KH2PO4

The activity product of tetracalcium phosphate (TTCP, Ca₄(PO₄)₂O), was determined at 37°C, and the hydrolysis of TTCP was investigated in 0.01–0.1 mol l^–1 H₃PO₄ and KH₂PO₄ solutions by means of calcium and phosphorus analyses, X-ray diffraction and infrared analysis. The activity product, defined as K _sp=(Ca²⁺)⁴ (PO ₄ ^3– )² (OH^–)², was 37.36 as pK _sp, which was smaller than that previously reported (42.4). TTCP easily hydrolysed to form calcium-deficient apatite (Ca-def OHAp, Ca_5–x (HPO₄) _x (PO₄)_3–x (OH)_1–x ), or dicalcium phosphate dihydrate (DCPD, CaHPO₄2H₂O), depending on the initial phosphate concentration. With 0.1 mol l^–1 H₃PO₄, TTCP hydrolysed to form DCPD within several minutes. In 0.025 mol l^–1 H₃PO₄ and 0.1 mol l^–1 KH₂PO₄, TTCP hydrolysed to form Ca-def OHAp through DCPD. In the latter solution, a small amount of octacalcium phosphate (OCP, Ca₈(H₂PO₄)₂(PO₄)₄5H₂O), was detected as an intermediate product. In 0.025 mol l^–1 KH₂PO₄, TTCP hydrolysed directly to form Ca-def OHAp. In 0.01 mol l^–1 H₃PO₄, hydrolysis of TTCP was not completed, although Ca-def OHAp was only a product. Thus the final product and the degree of hydrolysis depended on the pH and the overall Ca/P ratio in the reaction system. The rate of Ca-def OHAp formation seemed to be controlled by the dissolution rate of TTCP rather than the crystallization rate of the OHAp.     

Comparative hall measurements on wet- and dry-oxidized 4H-SiC MOSFETs

Hall measurements have been used to compare the properties of 4H-SiC inversion-mode MOSFETs with “wet” and “dry” gate oxides. While the field-effect mobilities were approximately 3–5 cm²/Vs, the Hall mobilities in 4H-SiC MOSFETs in the wet and dry oxide samples were approximately 70–80 cm²/Vs. The dry-oxidized metal oxide semiconductor field effect transistors (MOSFETs) had a higher transconductance, improved threshold voltage, improved subthreshold slope, and a higher inversion carrier concentration compared to the wet-oxidized MOSFETs. The difference in characteristics between the wet- and the dry-oxidized MOSFETs is attributed to the larger fixed oxide charge in the dry oxide sample and a higher interface trap density in the wet oxide sample.     

Performance evaluation of a multichannel transceiver system forADSL and VHDSL services

The authors study the performance of a multichannel modulation method for asymmetric digital subscriber lines (ADSLs) and very high-speed digital subscriber lines (VHDSLs). In the ADSL case, over all unloaded North American subscriber lines in the test set, a unidirectional 1.536 Mb/s data rate service from the end office to the customer premises is possible on a single twisted pair at an error rate of 10^-7 with at least a 6 dB margin used coded multichannel modulation with sufficient transmit power. In the VHDSL case, data rates in excess of 100 Mb/s can be transmitted reliably, at an error rate of 10^-7, using uncoded multichannel modulation on a single twisted pair over a distance ⩽150 ft with a sufficiently high sampling rate (≈24 MHz) and transmit power. It is shown that a cost-effective multichannel transceiver design suggested for high-speed digital subscriber line (HDSL) service will also work well for ADSL and VHDSL services with only minimal modifications     

An anisotropic theory of elasticity for continuum damage mechanics

This paper presents the development of an anisotropic elastic damage theory. This is achieved by deriving a modified damage effect tensor M(D) for the effective stress equations capable of including the effect of anisotropic material damage. The modified tensor removes the restriction of a priori knowledge of the directions of principal stresses imposed by a damage effect tensor developed earlier and can now be made for general practical engineering applications of failure analysis. Reduction of the proposed tensor to a scalar for isotropic damage is shown to be possible when it is expressed not only in the principal directions but also in any arbitrary coordinate system, a necessary condition to verify the validity of the proposed tensor. Uniaxial tension and pure torsion are chosen to illustrate the application of the theory as well as associated damage variables that may be experimentally determined using laboratory size specimens. The measured damage variables confirm the presence of anisotropic damage from an initially isotropic material specimen and the magnitude is more pronounced at higher stresses and strains.

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Résumé On présente un développement d'une théorie sur l'endommagement élastique anisotrope en déduisant un tenseur modifié décrivant l'effet de l'endommagement pour un système d'équations de contraintes effectives susceptible d'inclure l'effet d'un endommagement dans un matériau anisotrope. Le tenseur modifié supprime la restriction de la connaissance a priori des directions des contraintes principales imposées par un tenseur d'effet d'endommagement développé précédemment; il peut à présent entrer dans les applications pratiques en construction de l'analyse des ruptures.On montre qu'il est possible de réduire le tenseur proposé à une valeur scalaire dans le cas d'un dommage isotrope, dès lors qu'il est exprimé non seulement suivant les directions principales, mais dans un système de coordonnées arbitraires, ce qui est une condition nécessaire pour en vérifier la validité.On choisit une traction multiaxiale et une torsion pure pour illustrer l'application de la théorie ainsi que des variables d'endommagement associées, susceptibles d'être déterminées expérimentalement à l'aide d'éprouvettes de laboratoire.Les variables d'endommagement mesurées confirment la présence d'un dommage anisotrope dans le cas d'une éprouvette d'un matériau initialement isotrope; son amplitude est plus prononcée à des contraintes ou des déformations plus importantes.

     

Coplanar waveguide with top and bottom shields in place ofair-bridges

A convenient technique for the elimination of the coupled slot-line mode in coplanar waveguide (CPW) nonsymmetric circuits is proposed. This technique simply uses top and/or bottom ground plane shields and avoids the more costly airbridges. These shields are easy to fabricate; however, they may slightly affect the propagation of the CPW mode in the form of power leakage into the parallel plate TEM mode. This effect can be avoided by restricting operation to lower frequencies. Numerical comparisons between the effect of the shields and the airbridges on a CPW filter are presented     

A simplified method for calculating the substation grounding gridresistance

A simple and accurate formula for calculating the grounding grid resistance is proposed in this paper. This method is based on a theoretical manipulation of the numerical moment method and of the current image. The formula is dependent on the substation grounding grid design, such as grid depth, grid size, number of meshes, grid-conductor diameter, etc. A comparison study is performed to check the accuracy of the proposed formula with respect to six different formulas and methods in the literature. An excellent agreement was found between the results of this formula and the results of a sophisticated computerized method     

Effect of storage temperature on phenolics stability in hawthorn (Crataegus pinnatifida var. major) fruits and a hawthorn drink

The stability of five major phenolics, namely (−)-epicatechin (EC), procyanidin B₂ (PC-B₂), chlorogenic acid (ChA), hyperoside (HP) and isoquercitrin (IQ), in hawthorn fruits and a canned hawthorn drink were evaluated during 6 months of storage in the dark at three different temperatures (4, 23 and 40 °C). HPLC with a diode-array detector was used to determine the contents of the individual compounds. The results showed that the studied phenolics in the hawthorn fruits and the drink were both stable at 4 °C and relatively unstable at 23 and 40 °C with varied extents of degradation. At room temperature (23 °C), marked degradations of EC and PC-B₂ were observed in both the fruits and the drink with around 50% and 30% decrease after a 6-month storage, respectively. A more significant decrease of the phenolics was observed at 40 °C, especially for EC and PC-B₂, which were almost completely degraded after a 6-month storage. HP, IQ and ChA were relatively stable at 23 °C, but unstable at 40 °C. Therefore, low-temperature storage is recommended for maintaining the quality and efficacy of hawthorn fruits and its preparations.