The effect of traffic data source on deterioration rates of heavy-duty flexible pavements

The purpose of this study is to assess the effect of traffic data source (estimated vs. actual) on predicted progression rates of roughness and rutting for heavy-duty flexible pavements of rural freeways. Progression rates are predicted using calibrated HDM-4 models. The assessment is performed in terms of variations in maintenance intervention timing associated with the variations in progression rates. Time series pavement condition data (covering 3–5 years) have been collected for 7 sections of rural freeways for use in calibrating HDM-4 deterioration models. They range in length from 10 to 60.8 km and cover different traffic volumes, climate zones and subgrade soil types. For these sections, estimated annual average daily traffic (AADT), growth factors and assumed loading have been extracted from relevant database. Only six segments of these sections have Weigh-in-Motion (WIM) sites so relevant actual AADT, growth factors and axle load distributions have been extracted from WIM reports. The results of running the calibrated HDM-4 deterioration models using different traffic data show that actual traffic data from WIM sites result in higher rates of deterioration to that of estimated data for four sites, resulting in earlier intervention timing and higher present value agency cost. The other two sites have lower rates with actual data due to lower traffic loading than estimated.     

Form-Stabilized Polyethylene Glycol/Palygorskite Composite Phase Change Material: Thermal Energy Storage Properties,Cycling Stability,and Thermal Durability

In this work, polyethylene glycol (PEG) as a phase change material (PCM) was incorporated with palygorskite (Pal) clay to develop a novel form-stable composite PCM (F-SCPCM). The Pal/PEG(40 wt%) composite was defined as F-SCPCM and characterized using SEM/EDS, FT-IR, XRD, DSC, and TGA techniques. The DSC results revealed that the F-SCPCM has a melting temperature of 32.5°C and latent heat capacity of 64.3 J/g for thermal energy storage (TES) applications. Thermal cycling test showed that the F-SCPCM had good cycling thermal/chemical stability after 500 cycles. The TGA data proved that that both cycled and non-cycled F-SCPCMs had considerable high thermal durability. Consequently, the created F-SCPCM could be considered as an additive material for production of green construction components with TES capability. POLYM. ENG. SCI., 60:909–916, 2020. © 2020 Society of Plastics Engineers     

Improving outdoor air quality based on building morphology: Numerical investigation

Due to rapid urbanization around the world, high concentrations of vehicular pollutants have deteriorated the outdoor air quality, which can affect the physical and psychological well-being of humans. Numerous strategies have been proposed to overcome these harmful impacts by improving the dispersion of air pollutants. Consequently, a question arises regarding the potential effects of building morphology on the dispersion of pollutants. Subsequently, transient three-dimensional Computational Fluid Dynamics (CFD) simulations are performed to examine the effect of building morphology on PM₁₀ dispersion. Eleven cases with various prototypes and morphological methods are compared with a simple building form to identify the patterns of PM₁₀ dispersion within a given time sequence under a prevailing inflow condition. The results indicate that the different designs of building morphology with varying Relative compactness (R_C) indicator highlight the importance of considering morphological factors to improve outdoor air quality. In addition, the proposed prototypes can reduce PM₁₀ concentrations by approximately 30%–90% at specific points in the studied time sequence. In particular, the vertical, horizontal, and grid folded prototypes can be considered more effective as an approximate decrease between 70% and 90% in PM₁₀ concentrations is observed, which reflects the influence of building morphology on improving outdoor air quality.     

Uptake of Nickel(II) Ion by Silica-o-Phenylenediamine Derived from Rice Husk Ash

Silicon - The silica-ortho-phenylenediamine(RHAOPDA) derived from Rice Husk Ash and o- phenylenediamine (OPDA) were synthesized. The prepared material was characterized by different techniques; N2-...     

High Stable Al-MCM-41: Structural Characterization and Evaluation for Removal of Methylene Blue from Aqueous Solution

Aluminosilicate (Al-MCM-41) was synthesized via a modified wet-method in a Si/Al atomic ratio of 13.64:1.00 and calcination at 500 °C. The structural     

Thermal stability of natural fibers and their polymer composites

Natural fiber-based composites are applied in many structural engineered products from civil constructions to automobile manufacturing due to the properties such as low density, high aspect ratio, biodegradability and ease to work. During the past decades such composites have been thoroughly studied for their mechanical properties and failure behavior and their properties compared with those of synthetic fiber-based composites. Other properties, such as the thermal behavior of natural fibers and composites, have also been studied because they determine the performance of their products possible. It deals with the effect of temperature on adhesive curing, effect of high temperature and fire damage during fabrication. Further, the thermal properties have equal importance in structural applications such as temperature transfer from end to end, load capacity at specific temperature, material behavior and dimensional stability at high temperature. In this respect the isothermal and non-isothermal thermogravimatric analyses are discussed and the improtance of glass transition temperature is studied during prepapration of composites to ensure their ultimate properties. Although there are several works that have been done on thermal behavior, especially thermogravimetric analysis of natural fibers and their composites, there is no review article available specially focused on natural fiber-based composites, hybrid composites, and nanocomposites. The aim of this review was to focus on the advances in the comprehension of thermogravimetric behavior of natural fibers and compare the effect of natural fibers as reinforced materials in polymer composites.     

Sustainability of the four generations of biofuels – A review

Biofuel has emerged as an alternative source of energy to reduce the emissions of greenhouse gases in the atmosphere and combat global warming. Biofuels are classified into first, second, third and fourth generations. Each of the biofuel generations aims to meet the global energy demand while minimizing environmental impacts. Sustainability is defined as meeting the needs of the current generations without jeopardizing the needs of future generations. The aim of sustainability is to ensure continuous growth of the economy while protecting the environment and societal needs. Thus, this paper aims to evaluate the sustainability of these four generations of biofuels. The objectives are to compare the production of biofuel, the net greenhouse gases emissions, and energy efficiency. This study is important in providing information for the policymakers and researchers in the decision-making for the future development of green energy. Each of the biofuel generations shows different benefits and drawbacks. From this study, we conclude that the first generation biofuel has the highest biofuel production and energy efficiency, but is less effective in meeting the goal of reducing the greenhouse gases emission. The third generation biofuel shows the lowest net greenhouse gases emissions, allowing the reduction of greenhouse gases in the atmosphere. However, the energy required for the processing of the third generation biofuel is higher and, this makes it less environmentally friendly as fossil fuels are used to generate electricity. The third and fourth generation feedstocks are the potential sustainable source for the future production of biofuel. However, more studies need to be done to find an alternative low cost for biofuel production while increasing energy efficiency.     

Synthesis of Novel Tetra(µ3-Methoxo) Bridged with [Cu(II)-O-Cd(II)] Double-Open-Cubane Cluster: XRD/HSA-Interactions,Spectral and Oxidizing Properties

A new double-open-cubane core Cd(II)-O-Cu(II) bimetallic ligand mixed cluster of type [Cl₂Cu₄Cd₂(NNO)₆(NN)₂(NO₃)₂].CH₃CN was made available in EtOH/CH₃CN solution. The 1-hydroxymethyl-3,5-dimethylpyrazole (NNOH) and 3,5-dimethylpyrazole (NNH) act as N,O-polydentate anion ligands in coordinating the Cu(II) and Cd(II) centers. The structure of the cluster in the solid state was proved by XRD study and confirmed in the liquid state by UV-vis analysis. The XRD result supported the construction of two octahedral and one square pyramid geometries types around the four Cu(II) centers and only octahedral geometry around Cd(II) two centers. Interestingly, NNOH ligand acts as a tetra-µ³-oxo and tri-µ²-oxo ligand; meanwhile, the N-N in NNH acts as classical bidentate anion/neutral ligands. The interactions in the lattice were detected experimentally by the XRD-packing result and computed via Hirschfeld surface analysis (HSA). The UV-vis., FT-IR and Energy Dispersive X-ray (EDX), supported the desired double-open cubane cluster composition. The oxidation potential of the desired cluster was evaluated using a 3,5-DTB-catechol 3,5-DTB-quinone as a catecholase model reaction.