Thermotransport in γ(bcc) U-Zr alloys: A phase-field model study

Atomic transport in the presence of a temperature gradient, commonly known as thermotransport or the thermomigration phenomenon, was simulated for U-Zr alloys using a phase-field model derived from irreversible thermodynamics. The free energy of the U-Zr system, a necessary ingredient for the phase-field-model, was directly incorporated from the available thermodynamic database. Kinetic parameters such as atomic mobility and heat of transport terms were obtained from experimental values reported in the literature. The model was applied to a single-phase (bcc-γ phase) alloy and to a diffusion couple consisting of two single-phase (bcc-γ phase) alloys of different compositions, both subjected to a constant temperature gradient. Constituent redistribution in the absence and presence of a compositional gradient was examined. An enrichment of Zr with a corresponding depletion of U was observed at the hot end of the initially homogeneous single-phase alloy. A similar atomic transport behavior was observed in the diffusion couple, where the magnitude and direction of the final composition gradient was dictated by the combined influence of atomic mobility and heat of transport terms.     

Solution precursor plasma deposition of nanostructured ZnO coatings

Zinc oxide (ZnO) is a wide band gap semiconducting material that has various applications including optical, electronic, biomedical and corrosion protection. It is usually synthesized via processing routes, such as vapor deposition techniques, sol-gel, spray pyrolysis and thermal spray of pre-synthesized ZnO powders. Cheaper and faster synthesis techniques are of technological importance due to increased demand in alternative energy applications. Here, we report synthesis of nanostructured ZnO coatings directly from a solution precursor in a single step using plasma spray technique. Nanostructured ZnO coatings were deposited from the solution precursor prepared using zinc acetate and water/isopropanol. An axial liquid atomizer was employed in a DC plasma spray torch to create fine droplets of precursor for faster thermal treatment in the plasma plume to form ZnO. Microstructures of coatings revealed ultrafine particulate agglomerates. X-ray diffraction confirmed polycrystalline nature and hexagonal Wurtzite crystal structure of the coatings. Transmission electron microscopy studies showed fine grains in the range of 10-40 nm. Observed optical transmittance (∼65-80%) and reflectivity (∼65-70%) in the visible spectrum, and electrical resistivity (48.5-50.1 mΩ cm) of ZnO coatings are attributed to ultrafine particulate morphology of the coatings.     

Synthesis and analysis of lead-free tungsten bronze ferroelectrics

The polycrystalline Ba₂Sr₃GdTi₃V₇O₃₀, a member of tungsten bronze structural family, was prepared by a solid-state reaction method at high temperature (calcination and sintering temperatures at 950 and 1,000 °C, respectively). Preliminary structural study showed that the compound has orthorhombic crystal structure at room temperature. Study of surface morphology of the compound by scanning electron microscopy exhibits the uniform grain distribution on the surface of the sample with less number of voids. The dielectric anomaly observed at 313 °C is considered as a ferroelectric-paraelectric phase transition temperature which has been confirmed by appearance of hysteresis loop at room temperature. The trend of variation of ac conductivity with inverse of absolute temperature provides the nature of conduction mechanism in the material. The different value of activation energy in different temperature regions suggests that the conduction process in the material is of mixed-type (i.e., ionic–polaronic and space charge due to the oxygen ion vacancies).     

Prediction of Mass Transfer Coefficients in a Packed Bed using Tamarind Nut Shell Activated Carbon to Remove Phenol

Phenol is a refractive pollutant that is generated from almost all the types of industries. Removal of phenol can be achieved economically by using a cost effective technique like adsorption on to activated carbon. The present paper reports on the preparation and characterization of activated carbon from tamarind nutshell, an agricultural waste byproduct, and its use in a packed bed for the removal of phenol. The breakthrough curves for column sorption of phenol from aqueous solutions to TNSAC have been measured at various flow rates and different particle sizes at 28 °C. The results obtained showed that the sorption of phenol is dependent on both the flow rate and the particle size of the adsorbent, and that the breakpoint time and phenol removal yield decrease with increasing flow rate and particle size. The overall mass transfer coefficient is calculated from the experimental data and compared with the values obtained from the correlation. Experimental values are in excellent agreement with the predicted values from the correlation.     

A ubiquitous mobile communication architecture for next-generation heterogeneous wireless systems

Rapid progress in research and development of wireless networking and communication technologies have created different types of wireless systems (e.g., Bluetooth, IEEE 802.11, UMTS, and satellite networks). These systems are envisioned to coordinate with each other to provide ubiquitous high-data-rate services to mobile users. In this article, the architecture for ubiquitous mobile communications (AMC) is introduced that integrates these heterogeneous wireless systems. AMC eliminates the need for direct service level agreements among service providers by using a third party, a network interoperating agent. Instead of deploying a totally new infrastructure, AMC extends the existing infrastructure to integrate heterogeneous wireless systems. It uses IP as the interconnection protocol. By using IP as the gluing protocol, transparency to the heterogeneities of the individual systems is achieved in AMC. Third-party-based authentication and billing algorithms are designed for AMC. New mobility management protocols are also developed to support seamless roaming between different wireless systems.     

A dual voltage-frequency VLSI chip for image watermarking in DCT domain

In this brief, we present a new VLSI architecture that can insert invisible or visible watermarks in images in the discrete cosine transform domain. The proposed architecture incorporates low-power techniques such as dual voltage, dual frequency, and clock gating to reduce the power consumption and exploits pipelining and parallelism extensively in order to achieve high performance. The supply voltage level and the operating frequency are chosen for each module so as to maintain the required bandwidth and throughput match among the different modules. A prototype VLSI chip was designed and verified using various Cadence and Synopsys tools based on TSMC 0.25-/spl mu/m technology with 1.4 M transistors and 0.3 mW of estimated dynamic power.     

Classification and assessment of power system static security using decision tree and random forest classifiers

The power system static security classification and assessment is essential in order to identify the post‐contingency problems and take corrective measures and to protect the system from blackout. In this paper, application of two data mining classifiers have been proposed for the security classification and assessment of a multiclass security problem. To design the security problem, contingency analysis is carried out under N‐1 line outage, and static severity index (SSI) is computed, which is a function of the line overload and the voltage deviation using Newton–Raphson load flow method, considering the variable load and generating conditions. Corresponding to the computed values of SSI, the voltage, phase angle, Mega Volt Ampere line flow and so on, a 1 × 7 pattern vector is generated. The generated pattern vectors are used to design a multiclass security problem. The designed security pattern vectors are given as inputs to the decision tree (DT) and random forest (RF) model in order to classify the security status of the power system. The proposed classifiers are investigated on an IEEE 30‐bus test system. The classification accuracy of the DT and the RF are compared with state‐of‐the‐art classifier models, namely, multilayer perceptron (MLP), radial basis function (RBF), and support vector machine (SVM).The simulation results clearly indicate that the proposed DT and RF classifiers are more efficient, reliable, and out performs MLP, RBF, and SVM classifiers for the assessment of the security status of the power system. Hence, DT and RF classifiers are found to be suitable for online implementation. Copyright © 2015 John Wiley & Sons, Ltd.     

Preparation and performance evaluation of castor oil-based polyurethane prepolymer/polylactide blends

Polylactide (PLA) is an important biodegradable polymer, used for numerous applications ranging from industrial packaging to tissue engineering. However, its inherent brittleness and limited thermal stability have restricted its penetration to niche markets. In this communication, the authors demonstrate that blending of PLA with castor oil-based polyurethane prepolymer (COPUP), with the addition of COPUP, dispersed in the PLA matrix can overcome the inherent brittleness of the matrix polymer. NCO-terminated COPUP was successfully synthesized and subsequently mixed with variable concentration of PLA matrix using melt blending technique. The interfacial compatibilization between COPUP and PLA phase happened by the reaction of ?NCO groups with terminal hydroxyl groups of PLA was confirmed by FT-IR peak deconvolution technique. As indicated by the results of DMA and DSC, the glass transition temperature (T _g) of both PLA and COPUP shifted closer together, indicating that the blend compatibility increased. The tensile properties and notched Izod impact strength of the PLA and toughened PLA are also investigated. With the addition of 30 % COPUP concentration, the elongation at break of the blend reached 377.46 %, and a notched Izod impact 269.62 J m^?1. With improved toughness, the PLA/COPUP blends could be used as replacements for some traditional petroleum-based polymers.     

Electrospinning highly oriented and crystalline poly(lactic acid) fiber mats

In recent years, there has been an increased focus on sustainable, green alternatives with similar properties to conventional petroleum-based polymers. Poly(lactic acid) (PLA) is a biodegradable biopolymer which exhibits mild piezoelectric properties and has good processability which gives it potential for use in numerous existing and novel applications. The purpose of this study was to produce highly oriented and crystalline PLA electrospun fiber mats for piezoelectric applications. In order to yield a high piezoelectric constant, high crystallinity and fiber orientation are necessary. A two parallel collector set up was used to mechanically orient the fibers in the space between two copper electrodes. Voltage and feed rate were adjusted to produce smooth, oriented fibers with average diameters ranging 0.73–1.19 μm. Crystallinity and orientation were increased via hot drawing of the fiber mats and were maximized between 40 and 50 % and greater than 50 %, respectively.