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21.
PATIENT: A 35-year-old man had suffered from leukemia since September 1990. A transplantation of bone marrow was carried out in February 1994. He developed a graft-versus-host disease in November 1995. In December 1995 a keratoplasty was necessary because of a perforated corneal ulcer. 17 days later the patient noted a complete loss of vision, first in the left and one day later in the right eye. The optic nerve head was white and the retina looked ischaemic like in central retinal artery occlusion. A hypodensic area was found in the frontal brain reaching up to the optic chiasm in computer tomography. Inspite of intensive treatment the immunosuppressed patient died 4 days after he had become blind. Autopsy showed a mycotic infiltration by mucormycosis of the brain and the right optic nerve sheath. This human- pathogenic fungal infection belongs to the group of mould as well as aspergillus. CONCLUSION: Mycosis should be considered in the differential diagnosis of acute visual loss in immunosuppressed patients. 相似文献
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Ashish Ganvir Mohit Gupta Nitish Kumar Nicolaie Markocsan 《Ceramics International》2021,47(1):272-283
This paper investigates the influence of suspension characteristics on microstructure and performance of suspensions plasma sprayed (SPS) thermal barrier coatings (TBCs). Five suspensions were produced using various suspension characteristics, namely, type of solvent and solid load content, and the resultant suspensions were utilized to deposit five different TBCs under identical processing conditions. The produced TBCs were evaluated for their performance i.e. thermal conductivity, thermal cyclic fatigue (TCF) and thermal shock (TS) lifetime. This experimental study revealed that the differences in the microstructure of SPS TBCs produced using varied suspensions resulted in a wide-ranging overall TBC performance. All TBCs exhibited thermal conductivity lower than 1 W/(m. K) except water-ethanol mixed suspension produced TBC. The TS lifetime was also affected to a large extent where 10 wt % solid loaded ethanol and 25 wt % solid loaded water suspensions produced TBCs exhibited the highest and the lowest lifetime, respectively. On the contrary, TCF lifetime was not as significantly affected as thermal conductivity and TS lifetime, and all ethanol suspensions showed marginally better TCF lifetime than water and ethanol-water mixed suspensions deposited TBCs. 相似文献
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Aminolytic chemical recycling is performed for obtaining NN′ diethyl 1,4 benzene dicarboxamide, NN′ dibutyl 1,4 benzene dicarboxamide, and NN′ dihexyl 1,4 benzene dicarboxamide from Polyethylene terephthalate bottle waste. The compounds were characterized through Fourier transform Infrared spectroscopy, Raman spectroscopy, UV–Visible spectroscopy, 1H NMR, 13C NMR, mass spectrometry, and elemental analysis. Thermal properties were also analyzed with the help of thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Density Functional Theory (DFT) study has been performed at GGA-BLYP (Becke's and Lee–Yang–Parr) functional using SZ basis set to investigate the vibrational frequencies and physical parameters. Experimental vibrational frequencies were found in good accord with the experimental values. Calorific values of the products have been determined using bomb calorimeter as per standard ASTM D240. The values have been correlated with increment of methylene units from NN′ diethyl BdCA to NN′ dihexyl BdCA using standard molar enthalpies of carbon and hydrogen. SEM and EDX analysis of the char residues after combustion has also been carried out to insight the effect of N-alkyl chain length on calorific values. The calorific values of the recovered compounds are comparable to commercial solid fuels and the compounds may find potential applications in aerospace industry. 相似文献
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Mimicking brain‐like functionality with an electronic device is an essential step toward the design of future technologies including artificial visual and memory applications. Here, a proof‐of‐concept all‐oxide‐based (NiO/TiO2) highly transparent (54%) heterostructure is proposed and demonstrated, which mimics the primitive functions of the visual cortex. Specifically, orientation selectivity and spatiotemporal processing similar to that of the visual cortex are demonstrated using direct optical stimuli under the self‐biased condition due to photovoltaic effect, illustrating an energy‐efficient approach for neuromorphic computing. The photocurrent of the device can be modulated from zero to 80 µA by simply rotating the slit by 90°. The device shows fast rise and fall times of 3 and 6 ms, respectively. Based on Kelvin probe force measurements, the observed results are attributed to a lateral photovoltaic effect. This highly transparent, self‐biased, photonic triggered device paves the way for the advancement of energy‐efficient neuromorphic computation. 相似文献
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Shahid Iqbal Le Thai Duy Hyunwoo Kang Ranveer Singh Mohit Kumar Jucheol Park Hyungtak Seo 《Advanced functional materials》2021,31(46):2102567
To realize the potential of Mott transition of multiphasic vanadium oxides (VOx) for memory applications, the development of VOx memtransistors on SiO2 wafer is introduced. Through electrical characterizations, the volatile memory behaviors of the VOx memtransistors are observed in both two- and three-terminal measurements. Their capacitive memory and resistive switching mechanisms are strongly related to the mixed VOx/SiO2 interface (called VSiOx). VSiOx supports the Mott transition in VOx at low bias voltages (<0.5 V), leading to the low power consumption of the memtransistor. Moreover, the fast switching time (≈35 ns) and tunable memory retention with the synaptic functions (potentiation and depression) of the memtransistors (by using the gate and drain biases) are demonstrated. Overall, the findings open up major opportunities for constructing ultrafast and femto-joule power-consuming neuromorphic devices. 相似文献
28.
Oana Cojocaru-Mirédin Mohit Raghuwanshi Roland Wuerz Sascha Sadewasser 《Advanced functional materials》2021,31(41):2103119
Cu(In,Ga)Se2 thin-film solar cells have attracted significant research interest in recent decades due to their high efficiency in converting solar energy into electricity for enabling a sustainable future. Although the Cu(In,Ga)Se2 absorber can be grown as a single crystal, its polycrystalline form is dominating the market not only due to its lower costs, but also due to its unexpectedly higher cell efficiency. However, this absorber contains a high fraction of grain boundaries. These are structural defects where deep-trap states can be localized leading to an increase in recombination activity. This controversy is mirrored in the existing literature studies where two main contradictory believes exist: 1) to be crucial grain boundaries in Cu(In,Ga)Se2 absorber are anomalous, being benign in terms of cell performance, and 2) grain boundaries are regions characterized by an increased recombination activity leading to deteriorated cell performance. Therefore, the present review tackles this issue from a novel perspective unraveling correlations between chemical composition of grain boundaries and their corresponding electronic properties. It is shown that features such as Cu depletion/In enrichment, segregation of 1-2at.% of alkali dopants, and passivation by a wide-bandgap or type inversion at grain boundaries are crucial ingredients for low open-circuit voltage loss and, hence, for superior cell performance. 相似文献
29.
A systematic method to synthesize all dividing wall columns for n‐component separation—Part I
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Gautham Madenoor Ramapriya Mohit Tawarmalani Rakesh Agrawal 《American Institute of Chemical Engineers》2018,64(2):649-659
We present an easy‐to‐use step‐wise procedure to synthesize an initial‐dividing wall column (i‐DWC) from any given n‐component basic distillation column sequence or its thermally coupled derivative. The procedure to be used is dependent on the nature of the distillation column sequence that is to be converted into a DWC, and comprises of an intuitive set of steps that we demonstrate through examples. It is noteworthy that, even for a ternary distillation, 15 potentially useful DWCs, some of which had been missing from the literature, have now been identified. This work significantly expands the search space of useful DWCs to separate any given multicomponent mixture. © 2017 American Institute of Chemical Engineers AIChE J, 64: 649–659, 2018 相似文献
30.
Modeling and performance analysis of VI‐CRA: A congestion control algorithm for vehicular networks
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This study proposes a Vehicle ID‐based CAM Rate Adaptation (VI‐CRA) algorithm for beacon messages in the vehicular network. Foremost, an improved vehicle ID–based analytical model is proposed at the MAC layer of vehicular network. The model weighs the random back‐off number chosen by vehicles participating in the back‐off process, with the vehicle ID incorporated in their respective CAMs. This eventually leads to the selection of a vehicle ID–based random back‐off number, minimizing the probability of collision due to same back‐off number selection. It is worth noting that the improved analytical model outperforms the existing works in terms of average packet delay since only one fourth of the contention window size is used throughout the simulation. To enhance the performance of the analytical model, the paper incorporates a congestion control algorithm, by adapting the rate of CAM broadcast over the control channel. The algorithm is designed considering a wide range of scenarios, ranging from nonsaturated to extremely saturated network (in terms of collision probability) and sparsely distributed to teemed network (in terms of vehicular density). For better analyses of simulation results, the algorithm is applied over different vehicle ID–based back‐off numbers. Simulation results for all the back‐off numbers show that vehicle ID–based CAM rate adaptation algorithm performs better than the traditional fixed CAM rate IEEE 802.11p, even at high vehicular density. 相似文献