Environmental sustainability assessment of buildings in hot climates: the case of the UAE

Sustainability has acquired great importance due to the negative impact of various developments on the environment. The rapid growth during the last decade has been accompanied by active construction which, in some instances, neglected the impact on the environment and human activities. The impact of developments on the traditional heritage has not been taken into consideration although the latter represents a rich resource for sustainable building practices. The study aims at examining these developments in the UAE using an assessment tool that measures the performance of buildings in terms of their sustainability. This study attempts to: (a) develop a comprehensive definition of sustainability to suit UAE needs; (b) classify sustainable building practices at international and regional levels; (c) assess building performance in the UAE; and (d) establish guidelines for future sustainable architecture. T-Sol software was used to predict the CO₂ emission level in selected buildings in the UAE. Results illustrate that average energy use/area in domestic buildings is high (213 kWh/m²) and public buildings showed less sustainable measures in terms of energy features, energy performance and environmental features. Issues considered in the assessment of buildings such as energy use per square metre and CO₂ emission are alarming. Traditional buildings in the UAE were more sustainable than contemporary buildings, however.     

Generalized Gabor filters for palmprint recognition

Orientation-based coding approaches have recently been widely employed for face and palmprint recognition where generally, one starts with a set of Gabor filters to extract orientation information and then proceeds to code dominant orientations as features for each point of the palmprint. However, as the Gabor filter is developed to model two-dimensional receptive fields of simple cells in straits cortex, it might not be our best choice when dealing with curved and complex structures inherent in the palmprint texture. Motivated by this intuition, this paper shows that Gabor filters are a subset of a bigger family of filters which we refer to as generalized Gabor filter (GGF). Depending on the values of its parameters, a GGF takes a rather diverse shapes and orientations, which results in a potentially finer feature extraction capability. We show this improved capability by employing GGFs in the palmprint verification process. In applying our method, two different sub-banks of GGFs are defined for the orientation-based feature extraction of palmprints, and when compared with Gabor filters, it will be shown that GGFs have the upper hand in capturing orientation features. Furthermore, compared with the competitive code—one of the well-known orientation-based coding methods—the number of employed orientations is reduced to half. This would automatically compensate for a double usage of the filter banks, which otherwise could increase the time complexity of using GGFs. These ideas are further elaborated using a set of experiments on PolyU II and PolyU 2D/3D palmprint databases. The results show the preeminence of using GGFs both in terms of accuracy and efficiency.     

Bioactive Peptides: Synthesis,Sources, Applications,and Proposed Mechanisms of Action

Bioactive peptides are a group of biological molecules that are normally buried in the structure of parent proteins and become active after the cleavage of the proteins. Another group of peptides is actively produced and found in many microorganisms and the body of organisms. Today, many groups of bioactive peptides have been marketed chemically or recombinantly. This article reviews the various production methods and sources of these important/ubiquitous and useful biomolecules. Their applications, such as antimicrobial, antihypertensive, antioxidant activities, blood-lipid-lowering effect, opioid role, antiobesity, ability to bind minerals, antidiabetic, and antiaging effects, will be explored. The types of pathways proposed for bioactive applications will be in the next part of the article, and at the end, the future perspectives of bioactive peptides will be reviewed. Reading this article is recommended for researchers interested in various fields of physiology, microbiology, biochemistry, and nanotechnology and food industry professionals.     

Effect of Immersion Time on Corrosion Behavior of Single-Phase Alloy and Nanocomposite Bismuth Telluride-Based Thermoelectrics in NaCl Solution

The corrosiveness of bismuth telluride-based thermoelectric materials (n-type single-phase alloy and a nanocomposite with MoS₂ nanoinclusions), in 0.1 molar solution of sodium chloride (NaCl), was investigated. The electrochemical impedance spectroscopy curves obtained after 1, 24, 48 and 72 h immersion time revealed the enhancement of the corrosion resistance of the nanocomposite specimen in a 0.1 molar NaCl solution in comparison with the single-phase bismuth telluride-based alloys, and the passivity increased by immersion time up to 72 h. The nanocomposite sample with submicron grains provided suitable nucleation sites for passive film nucleation that led to higher protective behavior.     

Study on single and binary catalytic systems of pyridine-imine catalysts based on nickel and iron in synthesis of reactor blends and low-density polyethylene nanocomposites

In the presence of modified methylaluminoxane as cocatalyst, the behavior of a binary catalytic system based on pyridine-imine nickel ( N ) and iron ( F ) catalysts was evaluated in order to reach a proper mixture of polyethylene (PE). A computational study along with kinetic profile suggested that the catalyst F with higher electron affinity (A) and electrophilicity (ω) in the methyl cationic active center and stronger interaction with the monomer led to high integrated monomer consumption and higher activity. In addition, the samples produced by the mixture of catalysts showed a higher value of [19.4 × 10⁴ g (PE) mol (Fe+Ni)⁻¹ h⁻¹)], melting point (127.8 °C), and crystallinity extent (41.29%) than the samples produced by the single catalysts. The addition of multiwalled carbon nanotubes (MWCNT) into the polymerization media reduced the activity of catalysts [from 7.50 × 10⁴ to 0.66 × 10⁴ g (PE) mol (Fe+Ni)⁻¹ h⁻¹] and the thermal properties of the low-density polyethylene nanocomposite samples. However, the sample containing 2.33% MWCNT_20-30 improved the total thermal stability of the neat polyethylene blend up to 400 °C. Scanning electron microscope images of the samples demonstrated irregular to virtually uniform morphologies were obtained through the in situ and solution-mixing techniques. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47376.     

Structural,morphological, and optical properties of W-doped VO2 thin films prepared by sol-gel spin coating method

Thermochromic VO₂ thin films were deposited on soda-lime glass via sol-gel method. Doping was done through adding tungstic acid solution to the vanadium solution precursor. Grazing incidence x-ray diffractometer (GIXRD) results showed that VO₂ and V₆O₁₃ phases were formed together in the heat-treated sample. According to the GIXRD result of the W-doped sample, only VO₂ remained. Field-emission scanning electron microscopy (FESEM) micrographs showed that the VO₂ grain size decreased from about 70 to about 25 nm for undoped film and 2 wt% W-doped films, respectively. Atomic force microscopy (AFM) results showed that the root mean square roughness for the film with 180 nm thickness was about 18 nm, and 2 wt% W-doped film had a smoother surface. Diffuse reflectance spectroscopy (DRS) results showed that the band gap energy for undoped, 1 wt% W- doped, and 2 wt% W-doped VO₂ thin films was 1.7, 1.3, and 0 eV, respectively. Four-point probe resistivity measurements showed a significant decrement, from approximately 1 MΩ at 15°C to <100 Ω at 80°C. Regarding Vis-NIR spectroscopy results, maximum optical transmission for undoped and W-doped films was approximately 75% and 35%, respectively.     

Refractory concretes uniaxial compression behaviour under high temperature testing conditions

Two refractory concretes with the same matrix composition, one based on andalusite aggregate and the other on bauxite aggregate, have been studied at temperatures ranging from room temperature to 1200 °C maximal temperature. Samples dried at 110 °C during 24 h to create dried standard specimens and others, fired at different temperatures, were subjected to several uniaxial compression test conditions conducted at various temperatures. The evolution of the materials’ global behaviour from quasi-brittle to viscous was evidenced and correlated to their microstructure evolution. Loading/unloading, creep, and strain rate jump tests helped define the damageable and viscoplastic nature of the behaviour. The influence of the firing temperature and duration on the materials’ behaviour is also reported and discussed. In conclusion, potential constitutive equations that are able to fit the material recorded behaviour are suggested.     

Theoretical challenges in understanding the inhibition mechanism of aluminum corrosion in basic media in the presence of some p-phenol derivatives

Using quantum electrochemical/thermodynamical approaches based on coupled cluster/polarized continuum models and density functional theory (CM/PCM–DFT), we investigated the corrosion inhibition mechanism of Al/NaOH system in the presence of some p-phenol derivatives. The influencing parameters on inhibitory action, i.e. charges on oxygen and hydrogen atoms of hydroxyl group, charge transfer, interaction energy, molecular activity and softness, electric dipole moment and de-solvation free energy, were determined for both neutral and deprotonated species at metal|solution interface. A good correlation was observed between these parameters and inhibition efficiency data reported in the literature. By introducing an appropriate thermodynamic procedure, we also determined the proton-loss tendency of the molecules nearby interface. The results were amazing and revealed a complicated protonation/deprotonation cycle for inhibitor species inside electrical double layer; the corrosive agents in the vicinity of metal surface become locally neutralized and pushed away.     

Pomegranate seed oil as a functional ingredient in beverages

Pomegranate seeds are by‐products of pomegranate juice industry. Since the seeds contain valuable oil that has nutritional and medicinal properties, they can be useful for food applications (especially in juice and beverage industries) as a functional agent. In this study, the possibility of producing a stable pomegranate‐seed‐oil‐in‐water emulsion to be used as a base formula for a new functional beverage was investigated. The influence of gum Arabic (GA) concentration (10.0, 12.5, and 15.0%, w/w) with a constant oil phase content (6.0% w/w) on the turbidity loss rate, emulsion stability index, and droplet size distribution was investigated. Turbidity loss rate was inversely proportional to the GA concentration for all the formulations studied here. Compared to other emulsions, emulsion with 15.0% w/w GA did not show a discernible cream layer during 42 days of storage. Emulsion with 15.0% w/w GA indicated the smallest polydispersity index during this period. The results of this study showed that it was possible to produce a relatively stable pomegranate‐seed‐oil‐in‐water emulsion for use as a functional agent in beverages.     

Effect of a coalescing aid on the earliest stages of polymer diffusion in poly(butyl acrylate-co-methyl methacrylate) latex films

In this article we use fluorescence resonance energy transfer (FRET) to investigate how a classic coalescing aid, such as 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate (Texanol?) (TX), acts on the earliest stages of polymer diffusion as the latex film is still drying. In our approach, we temporarily arrest the drying process of a partially wet latex film by sealing it in an airtight chamber previously cooled to near the latex T_g. At these conditions, we are able to effectively stop the drying process and the polymer diffusion. FRET measurements at various locations on such a sample provide us information about the mechanism operating at the initial stages of polymer diffusion as the latex film is still drying. We complete our study with FRET measurements carried out at longer aging times on predried latex films. We analyze our diffusion data in terms of free volume theory and propose a mechanism that can account for the results obtained.