Sorption potential of rice husk for the removal of 2,4-dichlorophenol from aqueous solutions: kinetic and thermodynamic investigations

The sorption potential of chemically and thermally treated rice husk (RHT) for the removal of 2,4-dichlorophenol (DCP) from aqueous solutions has been investigated. Sorption of DCP by rice husk was observed over a wide pH range of 1-10. The effect of contact time between liquid and solid phases, sorbent dose, pH, concentration of sorbate and temperature on the sorption of DCP onto rice husk has been studied. The pore area and average pore diameter of RHT by BET method are calculated to be 17+/-0.6 m2g-1 and 51.3+/-1.5 nm, respectively. Maximum sorption (98+/-1.2%) was achieved for RHT from 6.1x10(-5) moldm(-3) of sorbate solution using 0.1g of rice husk for 10 min agitation time at pH 6 and 303K, which is comparable to activated carbon commercial (ACC) 96.6+/-1.2%, but significantly higher than chemically treated rice husk (RHCT) 65+/-1.6% and rice husk untreated (RHUT) 41+/-2.3%. The sorption data obtained at optimized conditions was subjected to Freundlich, Langmuir and Dubinin-Radushkevich (D-R) isotherms. Sorption intensity 1/n (0.31+/-0.01) and sorption capacity multilayer C(m) (12.0+/-1.6 mmolg(-1)) have been evaluated using Freundlich sorption isotherm, whereas the values of sorption capacity monolayer Q (0.96+/-0.03 mmolg(-1)) and binding energy, b, (4.5+/-1.0)x10(4)dm(3)mol(-1) have been estimated by Langmuir isotherm. The Langmuir constant, b, was also used to calculate the dimensionless factor, R(L), in the concentration range (0.6-6.1)x10(-4) moldm(-3), suggesting greater sorption at low concentration. D-R sorption isotherm was employed to calculate sorption capacity X(m) (2.5+/-0.07 mmolg(-1)) and sorption energy E (14.7+/-0.13 kJmol(-1)). Lagergren and Morris-Weber equations were employed to study kinetics of sorption process using 0.2g of RHT, 25 cm(3) of 0.61x10(-4)moldm(-3) sorbate concentration at pH 6, giving values of first-order rate constant, k, and rate constant of intraparticle transport, R(id), (0.48+/-0.04 min(-1) and 6.8+/-0.8 nmolg(-1)min(-1/2), respectively) at 0.61x10(-4)moldm(-3) solution concentration of DCP, 0.1g RHT, pH 6 and 2-10min of agitation time. For thermodynamic studies, sorption potential was examined over temperature range 283-323 K by employing 6.1x10(-4)moldm(-3) solution concentration of DCP, 0.1g RHT at pH 6 and 10 min of agitation time and values of DeltaH (-25+/-1 kJmol(-1)), DeltaS (-61+/-4 Jmol(-1)K(-1)) and DeltaG(303K) (-7.1+/-0.09 kJmol(-1)) were computed. The negative values of enthalpy, entropy, and free energy suggest that the sorption is exothermic, stable, and spontaneous in nature.     

Dynamic modeling and nonlinear tracking control of a novel modified quadrotor

In this article, a nonlinear tracking controller is designed based on Lyapunov stability for a novel aerial robot. The proposed 6‐rotor configuration improves stability and payload lifting capacity of the robot compared with conventional quadrotors while avoiding further complexities in the robot dynamics and steering principles. The dynamical model of the robot is derived using Newton‐Euler method. The model represents a nonlinear, coupled, and underactuated system. The proposed control strategy includes 2 main parts: an attitude controller and a position controller. Both the attitude and position controls are Lyapunov‐based nonlinear tracking controllers that guarantee the asymptotic convergence of the states' tracking errors to zero. Simulation results are presented to illustrate appropriate performance of the closed‐loop system in terms of position/attitude tracking even in the presence of wind disturbance.     

New scheme for discrete observer design with estimation error covariance assignment

This article presents an innovative method for solving an estimation error covariance assignment problem to design an observer for a stochastic linear system. In the proposed method, the covariance assignment problem is converted to the problem of finding an extra noise-like input to the observer. Using appropriate matrix manipulation, the Riccati equation of the estimation error covariance assignment problem, is converted to a new deterministic linear state-space model. Also, the extra noise-like input to the observer is modelled as an input to the new deterministic linear state-space model. Therefore, all the conventional and well-defined control strategies could be applied and there is no need to solve a complicated Riccati equation. Moreover, using the proposed method, a multi-objective estimation error covariance tracking problem would be easily converted to the problem of controlling a standard deterministic linear state-space system. Based on the integral control method, which is applied to the new state-space model, formulations for the proposed covariance feedback law are presented. The control law results in a stable closed-loop covariance system and assigns a pre-specified covariance matrix to the estimation errors.     

Optical Nondestructive Evaluation for Structures

Abstract

This paper presents a new technique for evaluation of engineering structures, using optical measurement and probabilistic advancing cross-diagnosis. Its application is first computersimulated, and then it is tested in the laboratory. With the cooperation of the U.S. Federal Highway Administration, a recently developed coherent laser radar system was used to measure structural deformation. The data are treated to reduce noise and used to derive multiple features for reliable diagnosis. Both the simulation and laboratory test results show consistent effectiveness of the proposed technique, indicating a promising direction of nondestructive evaluation combining optical and computer technology.     

Physical model for the power-law voltage and current acceleration of TDDB

As gate voltages scale in ultra-thin gate oxide CMOS and single carrier energy drops below the threshold required for defect generation, we postulate that multiple carrier induced defect generation becomes the dominant degradation mechanism resulting in a power-law voltage and local current acceleration of time-dependent dielectric breakdown (TDDB). Data from multiple technology nodes is presented to corroborate our hypothesis, which is also demonstrated to be consistent with literature reports from several different companies. To the best of our knowledge, this is the first time the power-law local gate current acceleration is proposed in contrast to earlier formulations based on total gate current.     

ST Logistics: Distributing Consumer Goods in China

This paper describes the experience gained from a research collaboration between a group of researchers at the National University of Singapore and logistics executives in Sembcorp Logistics (formerly ST Logistics), in the latter's effort to develop a marketing and strategic planning software tool to enhance its third party logistics (3PL) services in China. As China opened up its economy in the late 1980s, many Western consumer goods manufacturers set up plants or formed joint ventures in China in an attempt to capture this huge market. While the production process can be easily built on the existing technologies and can be efficient costwise, the distribution process is still a challenge because of the backward nature of the infrastructure and the bureaucratic roadblocks, resulting in very high supply chain transaction costs. Consequently, most manufacturers turn to third-party logistics providers (3PLs) who have the required logistics expertise to operate in China. One of the leading 3PLs in China is Shenzhen ST-Anda Logistics (ST-Anda), a joint venture between Sembcorp Logistics and China Merchant Holdings. It has an existing pan-China network of distribution centers. Recently, to improve services to their customers, ST-Anda started planning for the expansion of their logistics distribution network. An OR/MS modeling approach was taken to help them in this venture.     

Fat oxidation in freeze-dried grouper during storage at different temperatures and moisture contents

The effects of moisture content levels and storage temperature on the lipid oxidation in freeze-dried grouper were studied. Three trends were observed in the changes of PV (peroxide value) depending on the moisture content and storage temperature. An exponential rise of PV was observed (p < 0.05) at lower temperatures (−20 °C and 5 °C for samples at moisture 5 g/100 g; and −20 °C for samples at moisture 20 g/100 g). At temperatures 25 °C for samples at moisture 5 g /100 g, and 5 and 25 °C for samples at 20 g moisture/100 g peaks of PV were observed (p < 0.05). At higher temperatures (40 °C for both moisture content levels) an exponential decay instead of increase were observed (p < 0.05). Moisture content levels had no significant effect (p > 0.05) on PV stored at temperature of −40 °C. The monolayer moisture for freeze-dried grouper was estimated as 6.2 g/100 g dry solids using BET-isotherm. Differential scanning calorimetry (DSC and modulated DSC) thermogram line showed two shifts (i.e. glass transition) and two endothermic peaks, one for melting of oil and another for decomposition. The validity of the water activity and glass transition concepts were evaluated. It is concluded that glass transition concept may be used to explain the process more adequately.     

Effect of yttrium additions to nickel on the volume and grain boundary diffusion of Ni in the scale formed on the alloy

NiO scales were formed on pure Ni and Ni-0.1 wt.% Y alloy by oxidation in pure O₂ at 1200°C, and the grain boundary self-diffusion coefficients of Ni in the dense region of the scale were measured by the tracer-sectioning technique. The volume diffusion coefficient was also measured in the alloy scale. The grain boundary and volume diffusion coefficients and the grain boundary width were found to be the same for the two materials within the experimental uncertainty.Work supported by the Division of Basic Energy Sciences, U.S. Department of Energy.     

Effect of yttrium additions on the oxidation of nickel

The oxidation of Ni, Ni-0.1 wt.% Y, and Ni-0.3 wt.% Y alloys was carried out in the temperature range 500–900°C at p_{O 2}= 1 atm.Work supported by the Division of Basic Energy Sciences, U.S. Department of Energy.     

Sorption profile of Cd(II) ions onto beach sand from aqueous solutions

Sorption of traces of Cd(II) ions onto beach sand is investigated as a function of nature and concentration of electrolyte (10(-4) to 10(-2)M nitric, hydrochloric and perchloric acids, pH 2-10 buffers and deionized water), shaking time 5-40min, shaking speed 50-200strokes/min, dosage of sand (50-1000mg/15cm(3)), concentration of sorbate (1.04x10(-6) to 1.9x10(-4)M) and temperature (293-323K). Maximum sorption of Cd(II) ions (approximately 66%) is achieved from deionized water using 300mg/15cm(3) sand in 20min. The data are successfully tested by Langmuir, Freundlich and Dubinin-Redushkevich (D-R) sorption isotherms. The values for characteristic Langmuir constants Q=13.31+/-0.20micromol/g and of b=(6.56+/-0.53)x10(3)dm(3)/mol, Freundlich constants A=2.23+/-1.16mmol/g and 1/n=0.70+/-0.05 of (D-R) constants beta=-0.005068+/-0.000328kJ(2)/mol(2), X(m)=46.91+/-11.91micromol/g and energy E=9.92+/-0.32kJ/mol have been estimated. Kinetics of sorption has been studied by applying Morris-Weber, Richenberg and Lagergren equations. The sorption follows first order rate equation resulting 0.182+/-0.004min(-1) The thermodynamic parameters DeltaH=32.09+/-2.92kJ/mol, DeltaS=111.0+/-9.5J/molK and DeltaG=-1.68+/-0.02kJ/mol are evaluated. The influence of common ions on the sorption of Cd(II) ions is also examined. Some common ions reduce the sorption while most of the ions have very little effect. It can be concluded that beach sand may be used as an alternative for the expensive synthetic sorbents.