Physical characterization and rheological behavior of polyurethane/poly(ϵ-caprolactone) blends,prepared by solution blending using dimethylacetamide

Blending effects of thermoplastic polyurethane based on polycaprolactone diol, PU (PCL diol), and poly (ϵ-caprolactone) (PCL) on the rheological properties and morphological behavior of the solvent-cast blends were investigated by parallel plate rheometer. The amount of PCL was varied from 20 to 50% by weight. Fourier transform infrared (FTIR) results showed existence of hydrogen bonding in PU/PCL blends. From FTIR, we also found the increase of PCL composition tends to reduction of intermolecular hydrogen bonding and enhancing of microphase separation in blends. Differential scanning calorimetry (DSC) indicated that these blend systems are partially miscible. Based on rheological characterization, decrease can be seen in the moduli, zero shear viscosity and plateau modulus of blends, as compared with net PU. Using Cole-Cole plots and composition dependencies of η₀ and the other viscoelastic functions expressed variation of morphology of blends due to increase of PCL content. Frequency sweep tests on PU/PCL (80/20) at five temperatures showed validity of time-temperature superposition in this blend. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Sensitivity analysis of the effects of the thermal parameters of exhaust gases on the output of a thermoelectric generator

Recovering the dissipated heat from exhaust is a useful means of reducing the energy consumption level as well as cutting down on environmental pollution. An efficient technique for recovering this lost heat is the use of thermoelectric generators, which directly convert the dissipated heat into useful electrical energy. In this paper, a whole thermoelectric generator system installed on the exhaust pipe of a vehicle has been modeled, and the effects of thermal parameters on the output of this thermoelectric generator have been measured and evaluated by means of sensitivity analysis. The E‐Fast sensitivity analysis method has been used in this study. The sensitivity analysis results indicate that, among the thermal parameters examined, the temperature of gases entering the heat sink installed at exhaust pipe outlet () has the greatest influence (37%) and the flow rate of fluid entering the heatsink installed on the cold side of thermoelectric modules () has the second greatest influence (17%) on the output power of the considered thermoelectric generator. By using these results, the best cases of hot exhaust gases from various industries and vehicles with the highest potential of recovering the dissipated energy and heat from them by thermoelectric generators can be identified.     

Ionic liquid ultrasound assisted dispersive liquid-liquid microextraction method for preconcentration of trace amounts of rhodium prior to flame atomic absorption spectrometry determination

In this article, we consider ionic liquid based ultrasound-assisted dispersive liquid-liquid microextraction of trace amounts of rhodium from aqueous samples and show that this is a fast and reliable sample pre-treatment for the determination of rhodium ions by flame atomic absorption spectrometry. The Rh(III) was transferred into its complex with 2-(5-bromo-2-pyridylazo)-5-diethylamino phenol as a chelating agent, and an ultrasonic bath with the ionic liquid, 1-octyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide at room temperature was used to extract the analyte. The centrifuged rhodium complex was then enriched in the form of ionic liquid droplets and prior to its analysis by flame atomic absorption spectrometry, 300 μL ethanol was added to the ionic liquid-rich phase. Finally, the influence of various parameters on the recovery of Rh(III) was optimized. Under optimum conditions, the calibration graph was linear in the range of 4.0-500.0 ng mL(-1), the detection limit was 0.37 ng mL(-1) (3S(b)/m, n = 7) and the relative standard deviation was ±1.63% (n = 7, C = 200 ng mL(-1)). The results show that ionic liquid based ultrasound assisted dispersive liquid-liquid microextraction, combined with flame atomic absorption spectrometry, is a rapid, simple, sensitive and efficient analytical method for the separation and determination of trace amounts of Rh(III) ions with minimum organic solvent consumption.     

Microfluidic Synthesis of Ultrasmall Chitosan/Graphene Quantum Dots Particles for Intranasal Delivery in Alzheimer's Disease Treatment

Nanoparticles (NPs) based therapies for Alzheimer's disease (AD) attract interest due to their ability to pass across or bypass the blood-brain barrier. Chitosan (CS) NPs or graphene quantum dots (GQDs) are promising drug carriers with excellent physicochemical and electrical properties. The current study proposes the combination of CS and GQDs in ultrasmall NP form not as drug carriers but as theranostic agents for AD. The microfluidic-based synthesis of the CS/GQD NPs with optimized characteristics makes them ideal for transcellular transfer and brain targeting after intranasal (IN) delivery. The NPs have the ability to enter the cytoplasm of C6 glioma cells in vitro and show dose and time-dependent effects on the viability of the cells. IN administration of the NPs to streptozotocin (STZ) induced AD-like models lead to a significant number of entrances of the treated rats to the target arm in the radial arm water maze (RAWM) test. It shows the positive effect of the NPs on the memory recovery of the treated rats. The NPs are detectable in the brain via in vivo bioimaging due to GQDs as diagnostic markers. The noncytotoxic NPs localize in the myelinated axons of hippocampal neurons. They do not affect the clearance of amyloid β (Aβ) plaques at intercellular space. Moreover, they showed no positive impact on the enhancement of MAP2 and NeuN expression as markers of neural regeneration. The memory improvement in treated AD rats may be due to neuroprotection via the anti-inflammation effect and regulation of the brain tissue microenvironment that needs to be studied.     

Simple electromagnetic detection of variations in properties ofmetal surfaces

Recently, a significant improvement in the sensitivity of the nonuniform AC field measurement technique for the detection of cracks was reported. In this paper, the results of the application of the improved technique in the detection of heat-effected zones and ground welds are presented and briefly discussed. In such applications, the use of a long probe is essential     

Thermodynamic analysis of combined diesel engine and absorption refrigeration unit—supercharged engine with intercooling

This paper traces the thermodynamic analysis of a combined supercharged diesel engine with intercooling and an absorption refrigeration unit. Based on thermodynamic laws, the amount of net work, efficiency, and also the amount of cooling capacity available in the exhaust gases, which can be used for engine intercooling or external air-conditioning purposes or both, have been calculated. The influence of the engine configuration and performance parameters on the performance of an ideal system is examined and the acceptable envelope identified. Graphs of net work, efficiency and cooling capacity of the exhaust gases as a function of pressure ratio and temperature ratio of the cycle are given.     

Optimal Routing Policy

We investigate the problem of resource allocation in heterogeneous networks of computational resources. We provide an explicit analytical solution for a situation where the computational environment can be described by M/M/l queueing theory. We illustrate the quality of our solution by comparing results with those obtained via a simple ad hoc resource allocation in large heterogeneous networks consisting of N = 10⁴ nodes with computational resources distributed either uniformly in a given interval, or exponentially in R⁺.