Creep-fatigue crack growth in austenitic stainless steel centre cracked plates at 650°C. Part II: Defect assessment according to the A16 document

In this paper, a defect assessment according to the simplified methods proposed in the French A16 document is presented. These methods allow one to estimate fracture mechanic parameters such as δK or C* based on a reference stress approach. The overall objective of the study is to evaluate the ability of such methods to predict creep-fatigue crack growth obtained in a large component containing a semi- elliptical surface notch. The experiment consists of a wide austenitic stainless steel centre cracked plate heated up to a temperature of 650°C and subjected to more than 3000 bending cycles with a one hour holdtime at the maximum load of the cycle. The analysis according to the A16 document together with the material properties necessary for the analysis are detailed in the paper. The experimental crack growth rates are modelled both on the surface and through the thickness of the plate using a linear summation of cyclic and creep contributions. The applicability of two models, consisting for the first one in re-initialising the creep law at the beginning of the holdtime and for the second one in accounting for creep history is investigated. The results predicted with the first model are found to be very conservative whilst those obtained using the second model are found to be in good agreement with the experimental measurements.     

Complexity-regularized image denoising

We study a new approach to image denoising based on complexity regularization. This technique presents a flexible alternative to the more conventional l²,l¹, and Besov regularization methods. Different complexity measures are considered, in particular those induced by state-of-the-art image coders. We focus on a Gaussian denoising problem and derive a connection between complexity-regularized denoising and operational rate-distortion optimization. This connection suggests the use of efficient algorithms for computing complexity-regularized estimates. Bounds on denoising performance are derived in terms of an index of resolvability that characterizes the compressibility of the true image. Comparisons with state-of-the-art denoising algorithms are given     

Inactivation of Peroxidase by Ultraviolet–Visible Irradiation: Effect of pH and Melanoidin Content

Ultraviolet–visible irradiation has been proved to be effective in inactivating microorganisms and some enzymes in some foodstuff such as fruit juices and other derivatives. This piece of work provides some details that may help to understand the interaction between ultraviolet–visible radiation and horseradish peroxidase. When this enzyme is subjected to this process, the first stage of activation is observed, followed by the second stage of inactivation. Both activation and inactivation phases largely depend on the pH and less so on the temperature at which irradiation is performed. Peroxidase inactivation can be properly described by a kinetic model in which two consecutive steps are assumed and also by means of the Weibull equation. The study of the behavior of peroxidase in irradiated solutions that contain different concentrations of melanoidin leads to the conclusion that the enzyme is most affected by the radiation between 225 and 275 nm.     

Paraoxonase protection of LDL against peroxidation is independent of its esterase activity towards paraoxon and is unaffected by the Q-->R genetic polymorphism

Male-killing bacteria, which are inherited through the female line and kill male progeny only, are known from five different orders of insect. Our knowledge of the incidence of these elements has stemmed from discovery of their phenotype in different species. Our estimate of the frequency with which insects have been invaded by these elements therefore depends on each observation of the male-killing phenotype within a species being associated with a single microorganism. We here record an example of a single insect species being infected with two taxonomically distinct male-killing bacteria. Western European populations of the two-spot ladybird, Adalia bipunctata, have previously been shown to bear a male-killing Rickettsia. However, we here show that the majority of the male-killing lines tested from Central and Eastern Europe do not bear this bacterium. Rather, 16S rDNA sequence analysis suggests male-killing is associated with a member of the genus Spiroplasma. We discuss this conclusion in relation to the evolutionary genetics of male-killing bacteria, and the evolution of male-killing behaviour in the eubacteria.     

Coagulation of bentonite suspension by polyelectrolytes or ferric chloride: Floc breakage and reformation

Coagulation process usually involves different hydrodynamic conditions, in particular when it is followed by a filtration step. In this study, coagulation performance was investigated under a wide range of shear stress. Floc behaviour was followed in-line by laser granulometry to determine size distribution and structure. Synthetic suspension of bentonite in tap water was used as a reference for mineral solids in surface water. Three cationic polymers (polyamine based and polyDADMAC) and ferric chloride were tested using different coagulation reactor geometries. Jar-test indicated coagulation performance under mild hydrodynamic conditions and Taylor–Couette reactors were used to create shear stresses up to 8 Pa. Flocs formed with ferric chloride are not able to grow under middle shear stress like 1.5 Pa. On the contrary, polyelectrolytes lead to large flocs, dense (D_f = 2.6) and resistant to shear stress. A qualitative comparison of floc resistance to shear depending on hydrodynamic conditions and coagulant type is given through the calculation of the strength factor. Fractal dimension measurements indicate a mechanism of particle erosion when flocs are subjected to a higher shear stress in Taylor–Couette reactor. Floc re-growth is also investigated, and breakage appears to be non-reversible regardless of coagulant and conditions experimented.     

A Neyman–Pearson Approach to Universal Erasure and List Decoding

When information is to be transmitted over an unknown, possibly unreliable channel, an erasure option at the decoder is desirable. Using constant-composition random codes, we propose a generalization of Csiszar and Korner's maximum mutual information (MMI) decoder with an erasure option for discrete memoryless channels. The new decoder is parameterized by a weighting function that is designed to optimize the fundamental tradeoff between undetected-error and erasure exponents for a compound class of channels. The class of weighting functions may be further enlarged to optimize a similar tradeoff for list decodersin that case, undetected-error probability is replaced with average number of incorrect messages in the list. Explicit solutions are identified. The optimal exponents admit simple expressions in terms of the sphere-packing exponent, at all rates below capacity. For small erasure exponents, these expressions coincide with those derived by Forney (1968) for symmetric channels, using maximum a posteriori decoding. Thus, for those channels at least, ignorance of the channel law is inconsequential. Conditions for optimality of the Csiszar-Korner rule and of the simpler empirical-mutual-information thresholding rule are identified. The error exponents are evaluated numerically for the binary symmetric channel.     

Effects of input level and crop diversity on soil nitrate-N,extractable P,aggregation, organic C and N,and nutrient balance in the Canadian Prairie

A field experiment was conducted from 1995 to 2006 on a Dark Brown Chernozem (Typic Boroll) loam soil at Scott, Saskatchewan, Canada to determine the influence of input level and crop diversity on accumulation and distribution of nitrate-N and extractable P in the soil profile, and soil pH, dry aggregation, organic C and N, and nutrient balance sheets in the second 6-year rotation cycle (2001–2006). Treatments were combinations of three input levels (organic input under conventional tillage—ORG; reduced input under no-till—RED; and high input under conventional tillage—HIGH), three crop diversities (fallow-based rotations with low crop diversity—LOW; diversified rotations using annual cereal, oilseed and pulse grain crops—DAG; and diversified rotations using annual grain and perennial forage crops—DAP), and six crop phases including green manure (GM), chem-fallow or tilled-fallow (F). Amount of nitrate-N in 0-240 cm soil was usually highest under the HIGH input-LOW crop diversity treatment and lowest under the ORG input-DAP crop diversity treatment. The distribution of nitrate-N in various soil depths suggested downward movement of nitrate-N up to 240 cm depth, especially with LOW crop diversity compared to DAP crop diversity, and with HIGH input. In some years, the ORG input systems had higher nitrate-N than the RED or HIGH input systems, which was attributed to low extractable P in soil for optimum crop growth and reduced nutrient uptake with ORG input management. Extractable P in soil was higher by a small margin for HIGH or RED input relative to ORG input in the 0–15 cm layer, suggesting little downward movement of P. Crop diversity did not affect extractable soil P due to the low baseline levels of P in this soil. The proportion of fine dry aggregates (<1.3 mm, erodible fraction) in 0–5 cm soil was highest with LOW crop diversity-HIGH input system, and lowest with DAG diversity-RED input system. The opposite was true for large aggregates (>12.7 mm). Wet aggregate stability was higher for RED input compared to ORG and HIGH input, which was attributed to the increase in the concentration of organic C in aggregates in the RED input system. Amount of light fraction organic matter (LFOM), light fraction organic C (LFOC) and light fraction organic N (LFON) in 0–15 cm soil was higher for RED input compared to ORG and HIGH inputs, and higher for DAG and DAP crop diversities than for LOW crop diversity. Soil N and P were usually deficient under ORG input management, but large amounts of N and P were unaccounted for, or in surplus, under RED and HIGH inputs, despite a marked increase in plant N and P uptake and crop yield compared to ORG input. Overall, our findings suggest that soil quality can be improved and nutrient accumulation in the soil profile can be minimized by increasing cropping frequency, reducing/eliminating tillage, and using appropriate combinations of fertilizer input and diversified cropping.     

Sorption of Aldrich humic acid onto hematite: insights into fractionation phenomena by electrospray ionization with quadrupole time-of-flight mass spectrometry

Sorption induced fractionation of purified Aldrich humic acid (PAHA) on hematite is studied through the modification of electrospray ionization (ESI) quadrupole time-of-flight (QToF) mass spectra of supernatants from retention experiments. The ESI mass spectra show an increase of the "mean molecular masses" of the molecules that constitutes humic aggregates. The low molecular weight fraction (LMWF; m/z < or = 600 Da) is preferentially sorbed compared to two other fractions. The resolution provided by ESI-QToF mass spectrometer in the low-mass range provided evidence of further fractionation induced by sorption within the LMWF. Among the two latter fractions, the high molecular weight fraction (HMWF; m/z approximately 1700 Da) seems to be more prone to sorption compared to the intermediate molecular weight fraction (IMWF; m/z approximately 900 Da). The IMWF seems to be more hydrophilic as it should be richer in O, N, and alkyl C from the proportion of even mass, and poorer in aromatic structures from mass defect analysis in ESI mass spectra.     

Hereditary amyloid cardiomyopathy caused by a variant apolipoprotein A1

Autosomal dominant hereditary amyloidosis with a unique cutaneous and cardiac presentation and death from heart failure by the sixth or seventh decade was found to be associated with a previously unreported point mutation (thymine to cytosine, nt 1389) in exon 4 of the apolipoprotein A1 (apoA1) gene. The predicted substitution of proline for leucine at amino acid position 90 was confirmed by structural analysis of amyloid protein isolated from cardiac deposits of amyloid. The subunit protein is composed exclusively of NH2-terminal fragments of the variant apoA1 with the longest ending at residue 94 in the wild-type sequence. Amyloid fibrils derived from four previously described apoA1 variants are composed of similar fragments with carboxyl-terminal heterogeneity, but contrary to those variants, which all carry one extra positive charge, the substitution Leu90Pro does not result in any charge modification. It is unlikely, therefore, that amyloid fibril formation is related to change of charge for a specific residue of the precursor protein. This is in agreement with studies on transthyretin amyloidosis in which no unifying factor such as change of charge for amino acid residues has been noted.     

New software to model energy dispersive X-ray diffraction in polycrystalline materials

Detection of illicit materials, such as explosives or drugs, within mixed samples is a major issue, both for general security and as part of forensic analyses. In this paper, we describe a new code simulating energy dispersive X-ray diffraction patterns in polycrystalline materials. This program, SinFullscat, models diffraction of any object in any diffractometer system taking all physical phenomena, including amorphous background, into account. Many system parameters can be tuned: geometry, collimators (slit and cylindrical), sample properties, X-ray source and detector energy resolution. Good agreement between simulations and experimental data was obtained. Simulations using explosive materials indicated that parameters such as the diffraction angle or the energy resolution of the detector have a significant impact on the diffraction signature of the material inspected. This software will be a convenient tool to test many diffractometer configurations, providing information on the one that best restores the spectral diffraction signature of the materials of interest.