Effect of alloying elements on the solidification characteristics and microstructure of Al- Si- Cu- Mg- Fe 380 alloy

The effect of varying the major alloying elements within the limits of specification on the solidification behavior, fluidity, and microstructure of a 380 alloy has been studied at two cooling rates. The thermal analysis technique has been used to study the solidification behavior. The alloying elements investigated ranged from 3.22 to 4.09 pct copper, 1.01 to 1.70 pct iron, 0.06 to 0.50 pct magnesium, 1.69 to 3.00 pct zinc, and 0.16 to 0.46 pct manganese. The results show that the solidification behavior of the 380 alloys is complicated, and the cooling curve at 0.4 ‡C/s indicates six reactions taking place during the process of solidification. Cooling curves obtained for each of the alloying element additions, their analysis, and the resultant microstructures are discussed.     

Spectral and laser studies on energy transfer binary dye-doped polymer laser rods

The energy transfer mechanism of two different dyes, C450 as donor and C535 as acceptor incorporated into polymeric matrices, is investigated. The absorption and fluorescence characteristics of C450 and C535 dye-doped polymer modified with ethanol are studied. The results are compared with their respective liquid mixtures. The spectral parameters of C450 and C535 in polymer and the corresponding monomer compositions are obtained. We study the variation of gain for different acceptor concentrations whilst keeping the donor concentration fixed. The gain of acceptor with donor increased and then decreased as the acceptor concentration was increased. Both solid and liquid media showed similar trends. We also study the photobleaching of the dye-doped polymer rod under nitrogen laser excitation.     

Quantum shell game: Finding the hidden pea in a single attempt

Abstract

A quantum search of a database of four elements can be carried out in a single run with unit success probability. The classical analogy is to finding a pea hidden under one of four nut shells in a single attempt. We consider the algorithm in a system composed of two qubits, and show how the one and two-qubit search transforms are related to Pauli spin operators. The key search operation, the inversion about the mean, appears as a spatially rotated two-qubit phase shift, which provides some physical intuition for how it is implemented.     

Tailoring C60 for Efficient Inorganic CsPbI2Br Perovskite Solar Cells and Modules

Although inorganic perovskite solar cells (PSCs) are promising in thermal stability, their large open-circuit voltage (V_OC) deficit and difficulty in large-area preparation still limit their development toward commercialization. The present work tailors C₆₀ via a codoping strategy to construct an efficient electron-transporting layer (ETL), leading to a significant improvement in V_OC of the inverted inorganic CsPbI₂Br PSC. Specifically, tris(pentafluorophenyl)borane (TPFPB) is introduced as a dopant to lower the lowest unoccupied molecular orbital (LUMO) level of the C₆₀ layer by forming a Lewis acidic adduct. The enlarged free energy difference provides a favorable enhancement in electron injection and thereby reduces charge recombination. Subsequently, a nonhygroscopic lithium salt (LiClO₄) is added to increase electron mobility and conductivity of the film, leading to a reduction in the device hysteresis and facilitating the fabrication of a large-area device. Finally, the as-optimized inorganic CsPbI₂Br PSCs gain a champion power conversion efficiency (PCE) of 15.19%, with a stabilized power output (SPO) of 14.21% (0.09 cm²). More importantly, this work also demonstrates a record PCE of 14.44% for large-area inorganic CsPbI₂Br PSCs (1.0 cm²) and reports the first inorganic perovskite solar module with the excellent efficiency exceeding 12% (10.92 cm²) by a self-developed quasi-curved heating method.     

Investigation of multiple process parameters in abrasive water jet machining of tiles

This paper discusses the optimization of an abrasive water jet machining process with multiple characteristics, using the Taguchi orthogonal array and grey relational analysis (GRA). The machining process variables, such as mesh size, nozzle diameter, abrasive flow rate, water pressure, stand-off distance, and feed rate, were optimized with respect to multiple performance characteristics, namely, the surface roughness and the kerf angle. Experiments were performed using an L₁₈ orthogonal array, and the optimum machining process variables were determined, using GRA. Analysis of variance was used to identify the most significant factor in the machining performance. A confirmatory test was performed to verify the improvement of the performance characteristics. The microstructure of the machined surfaces was also examined by scanning electron microscopy and atomic force microscopy. The results showed that the surface roughness and kerf angle were minimized under optimal machining conditions.     

Quantum fast Fourier transform using multilevel atoms

We propose an implementation of the quantum fast Fourier transform algorithm in an entangled system of multilevel atoms. The Fourier transform occurs naturally in the unitary time evolution of energy eigenstates and is used to define an alternative wave-packet basis for quantum information in the atom. A change of basis from energy levels to wave packets amounts to a discrete quantum Fourier transform within each atom. The algorithm then reduces to a series of conditional phase transforms between two entangled atoms in mixed energy and wave-packet bases. We show how to implement such transforms using wave-packet control of the internal states of the ions in the linear ion-trap scheme for quantum computing.     

Insect chitinases: molecular biology and potential use as biopesticides

Chitin, an insoluble structural polysaccharide that occurs in the exoskeletal and gut linings of insects, is a metabolic target of selective pest control agents. One potential biopesticide is the insect molting enzyme, chitinase, which degrades chitin to low molecular weight, soluble and insoluble oligosaccharides. For several years, our laboratories have been characterizing this enzyme and its gene. Most recently, we have been developing chitinase for use as a biopesticide to control insect and also fungal pests. Chitinases have been isolated from the tobacco hornworm, Manduca sexta, and several other insect species, and some of their chemical, physical, and kinetic properties have been determined. Also, cDNA and genomic clones for the chitinase from the hornworm have been isolated and characterized. Transgenic plants that express hornworm chitinase constitutively have been generated and found to exhibit host plant resistance. A transformed entomopathogenic virus that produces the enzyme displayed enhanced insecticidal activity. Chitinase also potentiated the efficacy of the toxin from the microbial insecticide, Bacillus thuringiensis. Insect chitinase and its gene are now available for biopesticidal applications in integrated pest management programs. Current knowledge regarding the molecular biology and biopesticidal action of insect and several other types of chitinases is described in this mini-review.     

Effect of cooling rate on the solidification behavior of Al-7 Pct Si-SiCp metal-matrix composites

The solidification behavior of two composites based on Al-Si alloy has been investigated as a function of cooling rate. Thermal analysis techniques have been used to establish the relationship between solidification history and the microstructure developed. The results of thermal analysis show that the characteristic parameters are influenced by the cooling rate. A marked difference in these parameters is observed between the reinforced and the unreinforced materials at all cooling rates studied. The cooling rates used in the present study range from 0.3 to 20 K/s. Increasing the cooling rate is shown to affect the undercooling parameters both in the liquidus and eutectic solidification region. The eutectic growth temperature of the composites is observed to be higher than that of the base alloy at all cooling rates. The depression in eutectic temperature ΔT is found to decrease by 27 K for the unreinforced alloy (A356) and by 17 K for the composites (A356 + 10, 20 vol pct SiC) at a higher cooling rate of ≃16 K/s. The presence of SiC reinforcement is observed to suppress the Mg₂Si precipitate formation and decrease the amount of heat liberated during both primary and eutectic phase formation. Dendrite arm spacing (DAS) is correlated to the cooling rate by a relationship of the form DAS =AT ^-n, wheren is found to be of the order of 0.33.