北京南中轴南延段城市设计

北京市在提出建设"世界城市"和"加快南城发展"的新背景下,以新机场和临空都市区(新航城)建设为契机,拉动北京城市建设中轴线继续向南延展。北京南中轴南延段城市设计通过大项目的植入,为区域经济发展、城市建设提供发展引擎,通过延伸发展城市优先发展轴完善城市功能,提升南城形象和公共配套水平,缩小与北城的差距,引导城市均衡发展。     

Synthesis and glutathione S-transferase structure-affinity relationships of nonpeptide and peptidase-stable glutathione analogues

A series of nonpeptidic glutathione analogues where the peptide bonds were replaced by simple carbon-carbon bonds or isosteric E double bonds were prepared. The optimal length for the two alkyl chains on either side of the mercaptomethyl group was evaluated using structure-affinity relationships. Affinities of the analogues 14a-f, 23, and 25 were evaluated for a recombinant GST enzyme using a new affinity chromatography method previously developed in our laboratory. Analysis of these analogues gives an additional understanding for GST affinity requirements: (a) the carbon skeleton must conserve that of glutathione since analogue 14a showed the best affinity (IC50 = 5.2 microM); (b) the GST G site is not able to accommodate a chain length elongation of one methylene group (no affinity for analogues 14c,f); (c) a one-methylene group chain length reduction is tolerated, much more for the "Glu side" (14d, IC50 = 10.1 microM) than for the "Gly side" (14b, IC50 = 1800 microM); (d) the mercaptomethyl group must remain at position 5 as shown from the null affinity of the 6-mercaptomethyl analogue 14e; (e) the additional peptide isosteric E double bond (25) or hydroxyl derivative (23) in 14e did not help to retrieve affinity. This work reveals useful information for the design of new selective nonpeptidic and peptidase-stable glutathione analogues.     

包覆CaF2对稀土铝酸锶长余辉发光材料耐水性能的影响

为了提高稀土铝酸锶—SrAl2O4∶Eu2+,Dy3+ (SAOED)的耐水性能,通过液相沉积法制备了不同CaF2包覆量的SAOED.对包覆前后样品的微观形貌、物相结构、发光性能以及耐水性进行了研究.结果 表明:经由CaF2包覆后的SAOED表面粗糙,有颗粒沉积的现象,包覆工艺及CaF2包覆层未改变SAOED的物相结构...     

Cu2O催化甲醛乙炔化反应助剂效应

在液相还原法制备的纯Cu2O样品中,采用浸渍法分别引入Mg、Al、Fe助剂制备Cu2O-MgO、Cu2O-Al2O3、Cu2O-Fe2O3催化剂。采用XRD、FT-IR、TEM和H2-TPR等对催化剂进行表征,研究不同助剂的加入对甲醛乙炔化反应的影响。结果表明,不同助剂对催化剂的结晶度和可还原性能有较大影响,进而使甲醛乙炔化表现出不同的催化活性。相比MgO与Al2O3,Fe2O3的引入,使Cu2O结晶度明显下降,主要是由于Fe2O3与Cu2O之间产生强的相互作用,有利于乙炔亚铜活性物种的形成,从而表现出最优的催化性能。     

Effect of the thermal treatment mode on the composition and structure of ZrB2-SiC system composites

The composite materials and coatings for graphite based on a ZrB₂-SiC system were obtained by the formation of a glass-forming melt in air. The effect of the heating mode on the structure and properties of the materials synthesized was shown. The coatings can be used for protecting graphite from oxidation for several hours at temperatures up to 1400°C.     

Segregation Behavior of Metal Impurities During Al-Si Melt Directional Solidification with an Open Ended Crucible

The distribution characteristic and segregation behavior of metal impurities during directional solidification of Al-20Si, Al-30Si and Al-40Si alloys have been investigated. The morphologies of the alloys and impurity phases were observed by optical microscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy. The concentration profiles of representative metal impurities Al, Fe and Ti were measured by inductively coupled plasma optical emission spectrometry. The results indicate that the metal impurities segregate into the eutectic Al-Si melt during the growth of primary Si flakes and gradually segregate towards the top of each ingot during directional solidification. A concept of apparent segregation coefficient is proposed to characterize the segregation behavior of impurity elements. The apparent segregation coefficients of metal impurities decrease with increase in solidification temperature of the Al-Si alloys.     

Directional Growth of Tin Crystals Controlled by Combined Solute Concentration Gradient Field and Static Magnetic Field

A new method was introduced to achieve directional growth of Sn crystals. Microstructures in liquid(Pb)/liquid(Sn) diffusion couples were investigated under various static magnetic fields. Results show that the β-Sn crystals mainly reveal an irregular dendritic morphology without or with a relatively low static magnetic field(B0.3 T). When the magnetic field is increased to 0.5 T, the β-Sn dendrites close to the final stage of growth begin to show some directional character. With a further increase in the magnetic field to a higher level(0.8–5 T), the β-Sn dendrites have an enhanced directional growth character, but the dendrites show a certain deflection. As the magnetic field is increased to 12 T, the directional growth of the β-Sn dendrites in the center of the couple is severely destroyed. The mechanism of the directional growth of the β-Sn crystals and the deflection of the β-Sn crystals with the application of static magnetic field was tentatively discussed.     

一种基于占有率反馈的虚拟网络映射算法

网络虚拟化技术通过对物理资源的抽象,可以有效解决现有互联网架构中存在的网络结构僵化、可扩展性差等问题.虚拟网络映射问题是指将用户发送的所有虚网请求映射到底层物理网络中,同时还要满足虚网请求中对各个资源的限制要求(如节点计算能力、链路带宽等).从节点负载平衡的角度出发,在基于就近原则的虚网映射算法基础上,引入节点负载平衡的反馈机制,引导各个虚网请求更均匀地映射到底层物理网络中.另外,在k短路径算法机制中引入了当前链路资源占有率作为评价参考标准,这样可以尽可能均匀地分散链路压力.同时,在检验链路资源是否满足虚网请求的过程中,由于优先选中的链路资源占有率低,所以算法映射成功率高,映射耗时更短,虚拟网络映射效率得到了有效提高.     

Application of Poly(acetic Acid)–Based Graft Copolymer as a Compatibilizer for Poly(L-lactic Acid)/Poly(butylenesuccinate) Blend System

Poly(L-lactic acid) (PLLA) was blended with poly(butylenesuccinate) (PBS) using a single-screw extruder to modify the poor characteristics of these polymers. Furthermore, when both polymers were blended, the graft copolymer that was synthesized by partially saponified poly(vinyl alcohol) (PSPVA) and ?-caprolactone (?-CL) was used as a novel compatibilizer. The structure of the synthesized compatibilizer was determined by ¹H or ¹³C NMR. From this result, the ring-opening polymerization of the ?-CL occurred at the hydroxyl group of PSPVA. The structures of the PLLA/PBS solvent-cast blended films could be observed via an optical microscope. From the optical microscopic observation, the structures of the solvent-cast blended films with the synthesized compatibilizer were more homogeneous than those of the solvent-cast blended films without the compatibilizer. The mechanical properties of the PLLA/PBS extruded blended films were determined by a tensile test. The result showed the tensile strength of the blended films with the synthesized compatibilizer was greater than that of the blended films without the compatibilizer.