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Nanostructuring Lipophilic Dyes in Water Using Stable Vesicles,Quatsomes, as Scaffolds and Their Use as Probes for Bioimaging 下载免费PDF全文
Antonio Ardizzone Siarhei Kurhuzenkau Sílvia Illa‐Tuset Jordi Faraudo Mykhailo Bondar David Hagan Eric W. Van Stryland Anna Painelli Cristina Sissa Natalia Feiner Lorenzo Albertazzi Jaume Veciana Nora Ventosa 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(16)
A new kind of fluorescent organic nanoparticles (FONs) is obtained using quatsomes (QSs), a family of nanovesicles proposed as scaffolds for the nanostructuration of commercial lipophilic carbocyanines (1,1′‐dioctadecyl‐3,3,3′,3′‐tetramethyl‐indocarbocyanine perchlorate (DiI), 1,1′‐dioctadecyl‐3,3,3′,3′‐tetramethyl‐indodicarbocyanine perchlorate (DiD), and 1,1′‐dioctadecyl‐3,3,3′,3′‐tetramethyl‐indotricarbocyanine iodide (DiR)) in aqueous media. The obtained FONs, prepared by a CO2‐based technology, show excellent colloidal‐ and photostability, outperforming other nanoformulations of the dyes, and improve the optical properties of the fluorophores in water. Molecular dynamics simulations provide an atomistic picture of the disposition of the dyes within the membrane. The potential of QSs for biological imaging is demonstrated by performing superresolution microscopy of the DiI‐loaded vesicles in vitro and in cells. Therefore, fluorescent QSs constitute an appealing nanomaterial for bioimaging applications. 相似文献
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Siyuan Dai Mykhailo Tymchenko Yafang Yang Qiong Ma Marta Pita‐Vidal Kenji Watanabe Takashi Taniguchi Pablo Jarillo‐Herrero Michael M. Fogler Andrea Alù Dimitri N. Basov 《Advanced materials (Deerfield Beach, Fla.)》2018,30(16)
Hexagonal boron nitride (hBN) is a natural hyperbolic material that supports both volume‐confined hyperbolic polaritons and sidewall‐confined hyperbolic surface polaritons (HSPs). In this work, efficient excitation, control, and steering of HSPs are demonstrated in hBN through engineering the geometry and orientation of hBN sidewalls. By combining infrared nanoimaging and numerical simulations, the reflection, transmission, and scattering of HSPs are investigated at the hBN corners with various apex angles. It is also shown that the sidewall‐confined nature of HSPs enables a high degree of control over their propagation by designing the geometry of hBN nanostructures. 相似文献
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Niall Killilea Mingjian Wu Mykhailo Sytnyk Amir Abbas Yousefi Amin Oleksandr Mashkov Erdmann Spiecker Wolfgang Heiss 《Advanced functional materials》2019,29(14)
PbS nanocrystals have been proven to be highly suitable for photodetector fabrication by facile solution processing, and have been successfully tested as photosensitive material in imaging devices. So far, their spectral response has been blue‐shifted with respect to that of commercial bulk PbS detectors, due to quantum confinement in nanostructures smaller than the exciton Bohr radius. Here, a PbS nanocrystal synthesis approach is introduced, allowing to surpass this limit, and thus to push the cut‐off wavelength to the value of the bulk material. To avoid self‐absorbance from ligands within the spectral range of the photoconducting signal, an all inorganic metal‐halide‐perovskite is applied to form a semiconducting ligand shell. The photoconductors, which are provided from a single drop, do not only show a record in long wavelength operation for PbS nanocrystal detectors but also a room temperature detectivity > 1010 Jones, which is on par with that of commercial bulk PbS detectors. Combining these properties might find application in future low‐cost infrared imagers, which are currently still elusive due to their high prices. 相似文献
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Manuel Daum Sarah Deumel Mykhailo Sytnyk Hany A. Afify Rainer Hock Andreas Eigen Baolin Zhao Marus Halik Albert These Gebhard J. Matt Christoph J. Brabec Sandro F. Tedde Wolfgang Heiss 《Advanced functional materials》2021,31(47):2102713
Self-healing of defects imposed by external stimuli such as high energy radiation is a possibility to sustain the operational lifetime of electronic devices such as radiation detectors. Cs3Bi2Br3I6 polycrystalline wafers are introduced here as novel X-ray detector material, which not only guarantees a high X-ray stopping power due to its composition with elements with high atomic numbers, but also outperforms other Bi-based semiconductors in respect to detector parameters such as detection limit, transient behavior, or dark current. The polycrystalline wafers represent a size scalable technology suitable for future integration in imager devices for medical applications. Most astonishingly, aging of these wafer-based devices results in an overall improvement of the detector performance—dark currents are reduced, photocurrents are increased, and one of the most problematic properties of X-ray detectors, the base line drift is reduced by orders of magnitude. These aging induced improvements indicate self-healing effects which are shown to result from recrystallization. Optimized synthetic conditions also improve the as prepared X-ray detectors; however, the aged device outperforms all others. Thus, self-healing acts in Cs3Bi2Br3I6 as an optimization tool, which is certainly not restricted to this single compound, it is expected to be beneficial also for many further polycrystalline ionic semiconductors. 相似文献
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V. I. Yakerson T. V. Vasina L. I. Lafer V. P. Sytnyk G. L. Dykh A. V. Mokhov O. V. Bragin Kh. M. Minachev 《Catalysis Letters》1989,3(4):339-345
The state of additives (zinc, gallium) in pentasils and their role in the aromatization of ethane and propane have been studied by IR-spectroscopy, analytical electron microscopy and catalytic techniques. The different distribution of additives in the pentasil matrix have been found. Positive effect in aromatization of ethane and propane depends on zinc and gallium content.Presented at the Royal Society — USSR Academy of Sciences Meeting on Surfaces and Catalysts, Oxford, 8–10 April 1989. 相似文献
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Philipp Stadler Shaimaa A. Mohamed Jacek Gasiorowski Mykhailo Sytnyk Sergii Yakunin Markus C. Scharber Christina Enengl Sandra Enengl Daniel A. M. Egbe Mabrouk K. El‐Mansy Salah S. A. Obayya N. Serdar Sariciftci Kurt Hingerl Wolfgang Heiss 《Advanced materials (Deerfield Beach, Fla.)》2015,27(9):1533-1539
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Belfield KD Bondar MV Hernandez FE Morales AR Przhonska OV Schafer KJ 《Applied optics》2004,43(34):6339-6343
The nonlinear transmission and the excited-state absorption spectra of three fluorene derivatives exhibiting large two-photon absorptivity were measured by the third harmonic of a picosecond Nd:YAG laser. We analyzed their capability for exhibiting stimulated emission in polar solvents and found that asymmetrical fluorene compounds with a diphenylamino substituent exhibited large Stokes shifts (approximately 8000 cm(-1)), high quantum yields (approximately 0.9-1.0), and no optical gain over their entire fluorescence spectral region. In contrast, a symmetrical fluorene derivative with vinylphenylbenzothiazole substituents in positions 2 and 7 underwent lasing under one-photon excitation by use of picosecond pulsed irradiation. 相似文献