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991.
Eun Jeong Kim Ha Ram Kim Seung Jun Choi Cheon-Seok Park Tae Wha Moon 《Food science and biotechnology》2016,25(2):457-460
Structural and digestion properties of amylosucrase-modified waxy adlay starch were investigated. The unique reaction of amylosucrase caused a decrease and an increase in the proportion of short chains and long chains, respectively, via attachment of glucosyl units to the non-reducing ends of branch chains. The in vitro digestion profile of amylosucrase-modified starch revealed that elongated branch chains were the main reason for high contents of slowly digestible and resistant starches due to formation of a more perfect crystalline structure via easy association between elongated branch chains. The glucose response in mice after consumption of amylosucrase-modified starch was similar to the response for commercial resistant starch with a gradual increase followed by a gradual decrease in blood glucose concentrations over a prolonged time. Both in vitro and in vivo tests were used to verify increased resistance to digestive enzymes caused by amylosucrase modification. 相似文献
992.
Light Harvesting: Enhanced Light Harvesting in Mesoscopic Solar Cells by Multilevel Multiscale Patterned Photoelectrodes with Superpositioned Optical Properties (Adv. Funct. Mater. 36/2016)
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993.
Non‐Volatile Polymer Electroluminescence Programmable with Ferroelectric Field‐Induced Charge Injection Gate
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Ju Han Lee Beomjin Jeong Sung Hwan Cho Eui Hyuk Kim Cheolmin Park 《Advanced functional materials》2016,26(30):5391-5399
Electroluminescence (EL) of organic and polymeric fluorescent materials programmable in the luminance is extremely useful as a non‐volatile EL memory with the great potential in the variety of emerging information storage applications for imaging and motion sensors. In this work, a novel non‐volatile EL memory in which arbitrarily chosen EL states are programmed and erased repetitively with long EL retention is demonstrated. The memory is based on utilizing the built‐in electric field arising from the remnant polarization of a ferroelectric polymer which in turn controls the carrier injection of an EL device. A device with vertically stacked components of a transparent bottom electrode/a ferroelectric polymer/a hole injection layer/a light emitting layer/a top electrode successfully emits light upon alternating current (AC) operation. Interestingly, the device exhibits two distinctive non‐volatile EL intensities at constant reading AC voltage, depending upon the programmed direct current (DC) voltage on the ferroelectric layer. DC programmed and AC read EL memories are also realized with different EL colors of red, green and blue. Furthermore, more than four distinguishable EL states are precisely addressed upon the programmed voltage input each of which shows excellent EL retention and multiple cycle endurance of more than 105 s and 102 cycles, respectively. 相似文献
994.
Ki Dong Yang Yoonhoo Ha Uk Sim Junghyun An Chan Woo Lee Kyoungsuk Jin Younghye Kim Jimin Park Jung Sug Hong Jun Ho Lee Hye‐Eun Lee Hui‐Yun Jeong Hyungjun Kim Ki Tae Nam 《Advanced functional materials》2016,26(2):233-242
The reduction of carbon dioxide (CO2) into chemical feedstock is drawing increasing attention as a prominent method of recycling atmospheric CO2. Although many studies have been devoted in designing an efficient catalyst for CO2 conversion with noble metals, low selectivity and high energy input still remain major hurdles. One possible solution is to use the combination of an earth‐abundant electrocatalyst with a photoelectrode powered by solar energy. Herein, for the first time, a p‐type silicon nanowire with nitrogen‐doped graphene quantum sheets (N‐GQSs) as heterogeneous electrocatalyst for selective CO production is demonstrated. The photoreduction of CO2 into CO is achieved at a potential of ?1.53 V versus Ag/Ag+, providing 0.15 mA cm?2 of current density, which is 130 mV higher than that of a p‐type Si nanowire decorated with well‐known Cu catalyst. The faradaic efficiency for CO is 95%, demonstrating significantly improved selectivity compared with that of bare planar Si. The density functional theory (DFT) calculations are performed, which suggest that pyridinic N acts as the active site and band alignment can be achieved for N‐GQSs larger than 3 nm. The demonstrated high efficiency of the catalytic system provides new insights for the development of nonprecious, environmentally benign CO2 utilization. 相似文献
995.
Dae‐Yoon Kim Sang‐A Lee Minwook Park Yu‐Jin Choi Won‐Jin Yoon Jin Soo Kim Yeon‐Tae Yu Kwang‐Un Jeong 《Advanced functional materials》2016,26(24):4242-4251
A programed light‐responsive chiral liquid crystal (LC) containing four photochromic azobenzene moieties covalently connected to a central bicyclic chiral core (abbreviated as AZ4ICD) is newly designed, precisely synthesized, and efficiently applied as a remote‐controllable molecular knob for the optically tunable thin film. First of all, phase evolutions and ordered structures of AZ4ICD are systematically investigated by a combination of thermal, microscopic, scattering, and simulation techniques. Wide‐angle X‐ray diffractions of oriented AZ4ICD samples indicate that the AZ4ICD molecule itself basically forms layer structures: one is a low‐ordered chiral smectic A LC phase (SmA*) with 5.61 nm layer periodicity at high temperatures, and two highly ordered smectic crystal (SmCr1 and SmCr2) phases are subsequently formed at lower temperatures with the anticlinically tilted molecular packing structures. The helical superstructures of chiral nematic LC phase (N*) can be spontaneously constructed by doping AZ4ICD chiral agents into the achiral nematic molecules. Due to the bent conformational geometry of AZ4ICD, the thermal window of blue LC phase (BP) is expanded by stabilizing the double twisted cylindrical building blocks. Remote‐controllable phase transformations in the mesomorphic helical superstructures are demonstrated by tuning the wavelength of light. 相似文献
996.
Utilization of the Antiferromagnetic IrMn Electrode in Spin Thermoelectric Devices and Their Beneficial Hybrid for Thermopiles
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Dong‐Jun Kim Kyeong‐Dong Lee Srivathsava Surabhi Soon‐Gil Yoon Jong‐Ryul Jeong Byong‐Guk Park 《Advanced functional materials》2016,26(30):5507-5514
The thermoelectric effect in various magnetic systems, in which electric voltage is generated by a spin current, has attracted much interest owing to its potential applications in energy harvesting, but its power generation capability has to be improved further for actual applications. In this study, the first instance of the formation of a spin thermopile via a simplified and straightforward method which utilizes two distinct characteristics of antiferromagnetic IrMn is reported: the inverse spin Hall effect and the exchange bias. The former allows the IrMn efficiently to convert the thermally induced spin current into a measurable voltage, and the latter can be used to control the spin direction of adjacent ferromagnetic materials. It is observed that a thermoelectric signal is successfully amplified in spin thermopiles with exchange‐biased IrMn/CoFeB structures, where an alternating magnetic alignment is formed using the IrMn thickness dependence of the exchange bias. The scalable signal on a number of thermopiles allowing a large‐area application paves the way toward the development of practical spin thermoelectric devices. A detailed model analysis is also provided for a quantitative understanding of the thermoelectric voltages, which consist of the spin Seebeck and anomalous Nernst contributions. 相似文献
997.
For the blind calculation of the International Collaborative Standard Problem (ICSP) experiment on heavy water reactor moderator subcooling requirements, the COMSOL Multiphysics code is used to simulate plastic deformation of a pressure tube (PT) as a result of the interaction of stress and temperature. It is shown that the thermal stress model of COMSOL is compatible to simulate the multiple heat transfers (including the radiation heat transfer and heat conduction) and stress strain in the simplified two-dimensional problem. The benchmark test result for radiation heat transfer is in good agreement with the analytical solution for the concentric configuration of PT and calandria tube (CT). Since the original strain model of COMSOL only considers an elastic deformation with thermal expansion coefficient, the PT/CT contact cannot be predicted in the ICSP. Therefore, the plastic deformation model by the Shewfelt and Godin, widely used in the fuel channel analysis of CANadian Deuterium Uranium (CANDU) reactor, is implemented to the strain equation of COMSOL. The heat-up of PT, the strain rate, and the contact time of the PT/CT are calculated with the boundary conditions (BCs) given for blind calculation of the ICSP experiment.
The result shows a sudden expansion of the inner concentric PT within a few milliseconds. This unsteady simulation should be helpful for the conceptual design of experiment as well as for the understanding of multiphysics inside the fuel channels of the CANDU reactor. 相似文献
998.
Uiju Jeong Tae-Joon Kim Yun Ho Kim Hong Hyun Son Gwang Hyeok Seo 《Journal of Nuclear Science and Technology》2016,53(2):173-183
One of the several key subsystems in the test facility of Korean sodium-cooled fast reactor is a plugging meter system, which measures the impurities in the sodium using an indirect online technique. To measure the low flow rate, a permanent magnet flowmeter was developed owing to its inherent fast response time, non-invasive characteristic, relatively accurate flow rate measurements, and excellent linearity between the flow rate and flowmeter signal. However, several limitations have been reported in the experimental evaluation of the flowmeter under low flow rate conditions given the measurement capability of the current experimental facility. Thus, the performance of the flowmeter was evaluated numerically using a commercial computational fluid dynamics tool, a FLUENT/MHD module, based on the finite volume method with the help of electromagnetic analysis software, ANSYS MAXWELL. The FLUENT/MHD module was validated by comparing the simulation results with the experimental results. The relative error of the FLUENT simulation was estimated to be approximately 0.24% compared with the experimental results. After the validation process, MHD simulations were conducted to calculate the flowmeter voltage signals versus flow rates, especially in a low flow rate regime, where the linearity between the flow rate and flowmeter signal was carefully analyzed. 相似文献
999.
1000.
The Gupta–Kumar’s nearest-neighbor multihop routing with/without infrastructure support achieves the optimal capacity scaling in a large erasure network in which n wireless nodes and m relay stations are regularly placed. In this paper, a capacity scaling law is completely characterized for an infrastructure-supported erasure network where n wireless nodes are randomly distributed, which is a more feasible scenario. We use two fundamental path-loss attenuation models (i.e., exponential and polynomial power-laws) to suitably model an erasure probability. To show our achievability result, the multihop routing via percolation highway is used and the corresponding lower bounds on the total capacity scaling are derived. Cut-set upper bounds on the capacity scaling are also derived. Our result indicates that, under the random erasure network model with infrastructure support, the achievable scheme based on the percolation highway routing is order-optimal within a polylogarithmic factor of n for all values of m. 相似文献