Photoinduced electron transfer mechanism between green fluorescent protein molecules and metal oxide nanoparticles

Green fluorescent protein (GFP) molecules are attached to titanium dioxide and cadmium oxide nanoparticles via sol–gel method and fluorescence dynamics of such a protein–metal oxide assembly is investigated with a conventional time correlated single photon counting technique. As compared to free fluorescent protein molecules, time-resolved experiments show that the fluorescence lifetime of GFP molecules bound to these metal oxide nanoparticles gets shortened dramatically. Such a decrease in the lifetime is measured to be 22 and 43 percent for cadmium oxide and titanium dioxide respectively, which is due to photoinduced electron transfer mechanism caused by the interaction of GFP molecules (donor) and metal oxide nanoparticles (acceptor). Our results yield electron transfer rates of 3.139×10⁸ s⁻¹ and 1.182×10⁸ s⁻¹ from the GFP molecules to titanium dioxide and cadmium oxide nanoparticles, respectively. The electron transfer rates show a marked decrease with increasing driving force energy. This effect represents a clear example of the Marcus inverted region electron transfer process.     

Optical gain in 1.3-μm electrically driven dilute nitride VCSOAs

We report the observation of room-temperature optical gain at 1.3 μm in electrically driven dilute nitride vertical cavity semiconductor optical amplifiers. The gain is calculated with respect to injected power for samples with and without a confinement aperture. At lower injected powers, a gain of almost 10 dB is observed in both samples. At injection powers over 5 nW, the gain is observed to decrease. For nearly all investigated power levels, the sample with confinement aperture gives slightly higher gain.     

Energy output estimation for small-scale wind power generators using Weibull-representative wind data

Estimation of energy output for small-scale wind power generators is the subject of this article. Monthly wind energy production is estimated using the Weibull-representative wind data for a total of 96 months, from 5 different locations in the world. The Weibull parameters are determined based on the wind distribution statistics calculated from the measured data, using the gamma function. The wind data in relative frequency format is obtained from these calculated Weibull parameters. The wind speed data in time-series format and the Weibull-representative wind speed data are used to calculate the wind energy output of a specific wind turbine. The monthly energy outputs calculated from the time-series and the Weibull-representative data are compared. It is shown that the Weibull-representative data estimate the wind energy output very accurately. The overall error in estimation of monthly energy outputs for the total 96 months is 2.79%.     

IEEE 802.16J relay-based wireless access networks: an overview [recent advances and evolution of WLAN and WMAN standards]

Multihop wireless systems have the potential to offer improved coverage and capacity over single-hop radio access systems. Standards development organizations are considering how to incorporate such techniques into new standards. One such initiative is the IEEE 802.16j standardization activity, adding relay capabilities to IEEE 802.16 systems. This article provides an overview of this relay-based technology, focusing on some of the most pertinent aspects. In particular, the different modes of operation (transparent and non-transparent), framing structures, and network entry procedures are described. Some consideration of the issues in designing such systems is then given, which highlights when different features within the standard are most appropriate. As these systems are very new, many open issues remain to be resolved.     

A statistical analysis of wind power density based on the Weibull and Rayleigh models at the southern region of Turkey

The electric generating capacity of Turkey must be tripled by 2010 to meet Turkey’s electric power consumption, if the annual 8% growth in electric power consumption continues. Turkey has to make use of its renewable energy resources, such as wind and solar, not only to meet the increasing energy demand, but also for environmental reasons. Studies show that Iskenderun (36°35′N; 36°10′E) located on the Mediterranean coast of Turkey is amongst the possible wind energy generation regions. In the present study, the wind energy potential of the region is statistically analyzed based on 1-year measured hourly time-series wind speed data. The probability density distributions are derived from time-series data and distributional parameters are identified. Two probability density functions are fitted to the measured probability distributions on a monthly basis. The wind energy potential of the location is studied based on the Weibull and the Rayleigh models.     

Photoconductivity and photoluminescence under bias in GaInNAs/GaAs MQW p-i-n structures

The low temperature photoluminescence under bias (PLb) and the photoconductivity (PC) of a p-i-n GaInNAs/GaAs multiple quantum well sample have been investigated. Under optical excitation with photons of energy greater than the GaAs bandgap, PC and PLb results show a number of step-like increases when the sample is reverse biased. The nature of these steps, which depends upon the temperature, exciting wavelength and intensity and the number of quantum wells (QWs) in the device, is explained in terms of thermionic emission and negative charge accumulation due to the low confinement of holes in GaInNAs QWs. At high temperature, thermal escape from the wells becomes much more dominant and the steps smear out.     

Gain studies of 1.3-μm dilute nitride HELLISH-VCSOA for optical communications

The hot electron light emitting and lasing in semiconductor heterostructure-vertical-cavity semiconductor optical amplifier (HELLISH-VCSOA) device is based on Ga_0.35In_0.65 N_0.02As_0.08/GaAs material for operation in the 1.3-μm window of the optical communications. The device has undoped distributed Bragg reflectors (DBRs). Therefore, problems such as those associated with refractive index contrast and current injection, which are common with doped DBRs in conventional VCSOAs, are avoided. The gain versus applied electric field curves are measured at different wavelengths using a tunable laser as the source signal. The highest gain is obtained for the 1.3-μm wavelength when an electric field in excess of 2 kV/cm is applied along the layers of the device.     

Negative attitudes to transition in post-communist Albania and acute coronary syndrome.

Objective: The authors assessed the association of acute coronary syndrome (ACS) with attitudes to the socioeconomic aspects of rapid change in transitional Albania. Design: A population-based case–control study conducted in Tirana, Albania, in 2003–2006 included 467 nonfatal ACS patients (370 men, 97 women; 88% response) and a population-sampled control group (469 men, 268 women; 69% response). Main Outcome Measures: Reaction to transition was assessed as a composite score of 3 items capturing attitudes toward socioeconomic aspects of transition in Albania. Results: Using logistic regression, there was a strong linear relationship of the attitude score with ACS. When categorized as negative, intermediate, or positive attitudes, the age- and sex-adjusted odds ratio (OR) for the negative versus positive categories was 3.0; 95% confidence interval (CI) = 2.1, 4.3; p for linear trend