Fabrication of basalt embedded composite fiber membrane using electrospinning method and response surface methodology

In this study, a novel basalt embedded fiber membranes was prepared by the electrospinning method. The effects of the feed rate, voltage, tip to collector distance, and the basalt content on the prepared composite fiber membranes were investigated and optimized using the response surface method. Four models were built to compare the fibers in terms of deionized water flux (DWF), activated sludge flux, chemical oxygen demand (COD) removal, and porosity of fiber membranes. All the developed models were significant and adequately precise. The maximum flux of DWF was obtained when the voltage was 17.25 kV, the tip to collector distance of 19 cm, and a basalt content in polymer of 1.25%. COD removal decreased at higher voltage values as the feed rate increased. The porosity, pore size, and the contact angle values decreased for basalt embedded fiber membrane. The increases in the basalt percentage in polymer increased the hydrophilicity of the fiber. The flux decline for the basalt embedded fiber membrane was compared with the pristine fiber membrane. The permeate fluxes of pristine and basalt embedded fiber membranes were 42.3 and 59.6 L/m²/h, respectively. The biofouling performances of pristine and basalt embedded fiber membranes were also examined. Irreversible fouling decreased from 42.9% to 8.0%, and reversible fouling increased from 56.5% to 91.1% after modification of the membrane with basalt powder. Scanning electron microscopy with energy dispersive X-ray analysis (SEM–EDX) analysis showed that basalt powder was successfully embedded into polyether sulfone polymer.     

Surface characteristics and overlaying properties of flat-pressed wood plastic composites

This study evaluated surface characteristics and overlaying properties of wood plastic composite (WPC) panels made from dry-blended rubber wood fiber-polypropylene (PP) powder formulations using a conventional flat-press process under laboratory conditions. Three levels of rubberwood fibers (Hevea brasiliensis), 40%, 50%, and 60%, based on the composition by weight, were mixed with the PP powder without and with 3% (based on weight) maleic anhydride grafted PP (MAPP) as a coupling agent. Contact angle measurements on the WPC samples were performed using a goniometer connected with a digital camera which collected one image per second. Roughness measurements, average roughness (R _a), mean peak-to-valley height (R _z), and maximum roughness (R _y), were taken from the sanded samples along and across the sandmarks using a fine stylus tracing technique. With increasing polymer content, surface roughness of the WPC panels improved while their wettability and adhesive bonding strength decreased. The formulations without MAPP were found to have higher surface roughness but they also had better wettability. Wettability and surface roughness of the WPC panels can provide good information on their ability to bond.     

Structural and Thermo-Physical Properties of 3C-SiC: High-Temperature and High-Pressure Effects

Silicon - Based on the density functional theory (DFT), a systematic theoretical investigation on the structural parameters and finite temperature thermo-physical properties of cubic silicon...     

Mechanical and Thermal Properties of 3D-Printed Biocomposites of Polylactic Acid and Thermally Modified Wood Flour with Silver Nanoparticles

This study investigates the effects of thermal treatment and silver nanoparticles on the mechanical and thermal properties of additively manufactured wood/polylactic acid (PLA) specimens. The 5 and 10 wt% additions of the wood flour into the PLA matrix are done in the twin screw extruder. The test specimens are produced from the filaments with a diameter of 1.75 mm using 3D printer. The mechanical properties of the 3D-printed wood/PLA specimens are affected by the wood flour content, thermal treatment of wood, and silver nanoparticles. The 3D-printed neat PLA specimens have better mechanical properties than the wood flour-filled PLA specimens. The bending strength of the specimens enhances with increasing wood flour content while the tensile strength decreases. The increases in the mechanical properties reveal that the thermal treatment of the wood improves the compatibility between wood and PLA matrix, which hereby improves the interfacial adhesion. The addition of the silver nanoparticles positively affects the mechanical properties and it is more compatible with thermally modified wood particles as compared to the untreated wood particles.     

The Lodgepole × Jack Pine Hybrid Zone in Alberta, Canada: A Stepping Stone for the Mountain Pine Beetle on its Journey East Across the Boreal Forest?

Historical data show that outbreaks of the tree killing mountain pine beetle are often preceded by periods of drought. Global climate change impacts drought frequency and severity and is implicated in the range expansion of the mountain pine beetle into formerly unsuitable habitats. Its expanded range has recently reached the lodgepole × jack pine hybrid zone in central Alberta, Canada, which could act as a transition from its historical lodgepole pine host to a jack pine host present in the boreal forest. This field study tested the effects of water limitation on chemical defenses of mature trees against mountain pine beetle-associated microorganisms and on beetle brood success in lodgepole × jack pine hybrid trees. Tree chemical defenses as measured by monoterpene emission from tree boles and monoterpene concentration in needles were greater in trees that experienced water deficit compared to well-watered trees. Myrcene was identified as specific defensive compound, since it significantly increased upon inoculation with dead mountain pine beetles. Beetles reared in bolts from trees that experienced water deficit emerged with a higher fat content, demonstrating for the first time experimentally that drought conditions benefit mountain pine beetles. Further, our study demonstrated that volatile chemical emission from tree boles and phloem chemistry place the hybrid tree chemotype in-between lodgepole pine and jack pine, which might facilitate the host shift from lodgepole pine to jack pine.     

Temperature-dependent viscosity correlations of vegetable oils and biofuel-diesel mixtures

Viscosity correlations of peanut, soy, sunflower, waste vegetable oil and its biofuel mixtures with diesel are presented based on three suggested equations. Calibrated capillary viscometers are used for measurements. Temperature is changed between the range of 20 °C and 120 °C. Correlations show small standard errors based on the method of curve fitting.     

Compression wood as a source of reinforcing filler for thermoplastic composites

Compression wood (CW) is a reaction wood formed in gymnosperms in response to various growth stresses. Many of the anatomical, chemical, physical, and mechanical properties of CW differ distinctly from those of normal wood. Because of different properties, the CW is much less desirable than normal wood. This study was conducted to investigate the suitability of CW flour obtained from black pine (Pinus nigra Arnold) in the manufacture of wood plastic composite (WPC). Polypropylene (PP) and CW flour were compounded into pellets by twin‐screw extrusion, and the test specimens were prepared by injection molding. WPCs were manufactured using various weight percentages of CW flour/PP and maleic anhydride‐grafted PP (MAPP). Water absorption (WA), modulus of rupture (MOR), and modulus of elasticity (MOE) values were measured. The results showed that increasing of the CW percentage in the WPC increased WA, MOR, and MOE values. Using MAPP in the mixture improved water resistance and flexural properties. CW flour of black pine can be used for the manufacturing of WPC as a reinforcing filler. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Improved phenol adsorption from aqueous solution using electrically conducting adsorbents

The electrically conducting and partially porous graphite based adsorbent (called NyexTM 2000) was tested for its adsorption capacity and electrochemical regeneration ability for the removal of phenol from aqueous solution. Nyex? 2000 was tested in comparison with Nyex? 1000, which is currently being used for a number of industrial waste water treatment applications. Nyex? 1000 exhibited small adsorption capacity of 0.1 mg g^?1 for phenol because of having small specific surface area of 1 m² g^?1. In contrast, Nyex? 2000 with specific surface area of 17 m² g^?1 delivered an adsorption capacity of 0.8 mg g^?1, which was eight-fold higher than that of Nyex? 1000. Nyex? 2000 was successfully electrochemically regenerated by passing a current of 0.5 A, charge passed of 31 C g^?1 for a treatment time of 45 minutes. These electrochemical parameters were comparable to Nyex? 1000 for which a current of 0.5 A, charge passed of 5 C g^?1 for a treatment time of 20 minutes were applied for complete oxidation of adsorbed phenol. The comparatively high charge density was found to be required for Nyex? 2000, which is justified with its higher adsorption capacity. The FTIR results validated the mineralization of adsorbed phenol into CO₂ and H₂O except the formation of few by-products, which were in traces when compared with the concentration of phenol removed from aqueous solution. The electrical energy as required for electrochemical oxidation of phenol adsorbed onto Nyex? 1000 & 2000 was found to be 214 and 196 J mg^?1, respectively. The comparatively low energy requirement for electrochemical oxidation using Nyex? 2000 is consistent with its higher bed electrical conductivity, which is twice that of Nyex? 1000.     

Measuring elastic constants of Hevea brasiliensis using compression and Iosipescu shear test

The increasing demand and widespread utility of wood composite products necessitate the knowledge of the orthotropic engineering and strength properties of the raw wood used for its safe design and effective performance. This research study aimed at finding the orthotropic elastic parameters of a sustainable timber in India, namely rubber wood (Hevea brasiliensis) with respect to the material axes longitudinal (L), radial (R) and tangential (T), which is a potential raw material for laminated products as verified. This study evaluated the three Young’s moduli, the three shear moduli and the six Poisson’s ratios of the wood species, unavailable in literature. Compression test in rectangular prism was used for the determination of the Young’s moduli and Poisson’s ratios. Shear characterization in the three material planes was done using the Iosipescu test. The highest value of normal stiffness of the material in compression was obtained in the longitudinal direction followed by radial stiffness and tangential stiffness. The shear stiffness was largest in the LR plane followed by LT and RT planes. RT plane exhibited the highest Poisson’s ratio and TL plane the lowest. Significant difference was noted in the shear strength of LR planes between block shear test and Iosipescu test but not with the LT planes.     

Memory Defect Tolerance Architectures for Nanotechnologies

Memory Built In Self Repair (BISR) is gaining importance since several years. Because defect densities are increasing in future submicron technologies, more advanced solutions may be required for memories to be produced in the upcoming nanometric CMOS process generations. Moreover, this problem will be exacerbated with nanotechnologies, where defect densities are predicted to reach levels of several orders of magnitude higher than in current CMOS technologies. For such defect densities, traditional memory repair is not adequate. This work presents several Built-In Self Repair techniques addressing memories affected by high defect densities as well as an evaluation of the area cost and yield. Statistical fault injection simulations were conducted and the obtained results show that BISR architectures can be used for future high defect technologies, providing close to 100% memory yield, by means of reasonable hardware cost. Thus, the extreme defect densities that many authors predict for nanotechnologies do not represent a show-stopper, at least as concerning memories.