The capture of carbon dioxide by transition metal aluminates,calcium aluminate,calcium zirconate,calcium silicate and lithium zirconate

The capture of CO₂ by transition metal (Mn, Ni, Co and Zn) aluminates, calcium aluminate, calcium zirconate, calcium silicate and lithium zirconate was carried out at pre- and post-combustion temperatures. The prepared metal adsorbents were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), surface area analysis and acidity/alkalinity measurements. The different experimental variables affecting the adsorbents ability to capture CO₂, such as the mol ratio of metal ions, the pressure of CO₂, the exposure time and the temperature of the adsorbent were also investigated. Calcium zirconate captured 13.85 wt-% CO₂ at 650°C and 2.5 atm and calcium silicate captured 14.31 wt-% at 650°C. Molecular sieves (13X) and carbon can only capture a negligible amount of CO₂ at high temperatures (300°C–650°C). However, the mixed metal oxides captured reasonable amount of CO₂ at these higher temperatures. In addition, calcium aluminate, calcium zirconate, calcium silicate and lithium zirconate adsorbents captured CO₂ at both pre and post-combustion temperatures. The trend for the amount of captured carbon dioxide over the adsorbents was calcium aluminate相似文献   

8 MeV electron irradiation effect on the dielectric and optical properties of iminodiacetic acid doped ferroelectric triglycine sulphate crystals

Single crystal of iminodiacetic acid (5 mol%) doped Tri Glycine Sulphate (IDATGS) was grown by slow evaporation from its aqueous solution at constant temperature, using solution growth method. The dielectric constant (ε′) and pyroelectric current (I_P) were measured over the temperature range of 30-60 °C in the ferroelectric direction. The measured values of ε′ and I_P were found to be smaller compared to pure triglycine sulphate (TGS) crystal parameters. But increased transition temperature was observed for doped crystals. Curie Weiss constants C_P and C_f in the paraelectric and ferroelectric phases were also determined. The doped crystal was irradiated with graded dosages from 5 to 80 kGy of electron beam from 8 MeV Microtron at room temperature and radiation effects on optical and dielectric properties were studied. The UV-Vis absorption spectrum indicates that the UV lower cutoff shifts towards the higher wavelength region (red shift) and the optical band gap is found to be decreasing with the increase of electron dose. It is also observed that the electron irradiation effects in pure and doped TGS were found to be long lasting. The dielectric study shows that there is a gradual reduction in dielectric constant at T_C and shifting of Curie temperature towards lower temperature region with the increase in electron radiation dose. The material figures of merit were found increased after the crystal was irradiated. Induced changes in the physical and optical properties due to irradiation may help one to tailor the device quality and characteristics.     

Fretting wear behaviour of plasma nitrided Ti-6Al-4V fretted against unnitrided Ti-6Al-4V and alumina counterbodies

Ti-6Al-4V samples were plasma nitrided at 520°C in two environments (nitrogen and a mixture of nitrogen and hydrogen in the ratio of 3:1) for two different time periods (4 h and 18 h). Fretting wear tests were conducted on unnitrided and nitrided samples for 50,000 cycles using two counterbody materials (unnitrided Ti-6Al-4V and alumina). Gross slip prevailed at a normal load of 4.9 N while mixed stick-slip prevailed at 9.8 N. Tangential force coefficient values of plasma nitrided samples were lower than those of unnitrided samples. The tangential force coefficient nearly stabilised after thousand cycles in case of samples tested against Ti-6Al-4V counterbody. On the other hand, it showed a continuously increasing trend in case of specimens tested against alumina counterbody. The samples nitrided for 4 h exhibited higher hardness and lower tangential force coefficient compared to the specimens nitrided for 18 h. The samples nitrided in nitrogen-hydrogen mixture environment exhibited higher hardness and lower tangential force coefficient compared to the specimens nitrided in nitrogen. The samples plasma nitrided in nitrogen-hydrogen mixture for 4 h exhibited the highest hardness and the lowest tangential force coefficient. The wear volume of the plasma nitrided samples was lower than that of the unnitrided samples. Owing to tribochemical reactions, the wear volume of unnitrided and nitrided samples fretted against alumina ball was higher than that of the samples fretted against Ti-6Al-4V. A consistent trend was not observed regarding which nitriding condition would result in lower wear volume at different loads.     

Advancement and characterization of Al-Mg-Si alloy using reinforcing materials of Fe2O3 and B4C composite produced by stir casting method

The modifications of Al6061-T6 metal matrix composites is an extraordinary enthusiasm of recent pertinence for lesser weight materials with high value of tensile strength, hardness and wear protection, which can be widely used in automotive and aircraft design. In this paper, we investigate the impacts of the reinforced Al6061 composite with 5 wt% of Fe₂O₃ in addition to 2 %, 4 %, 6 % weight of B₄C being made-up by stir casting technique. In this research, Al6061 composites have analyzed by its physical and mechanical properties like as density, hardness, impact strength, ultimate tensile and compressive strength, and an optical microscope is utilized to assess the metallurgical properties such as microstructure with different wt% of reinforcement of Al6061 composite. The microstructure of newly prepared composites was shown a regular spreading of reinforcements in the matrix by an optical microscope and also the muscular bonding between the matrix and reinforcements were demonstrated by SEM analysis. It is further identifying that, microstructure uniformity and therefore the tensile strength of the metal composites was enhanced with increasing the fraction of Fe₂O₃ and B₄C particles without any decrement in elongation.

     

n-MOSFET With Silicon–Carbon Source/Drain for Enhancement of Carrier Transport

A novel strained-silicon (Si) n-MOSFET with 50-nm gate length is reported. The strained n-MOSFET features silicon-carbon (Si_1-yC_y) source and drain (S/D) regions formed by a Si recess etch and a selective epitaxy of Si_1-yC_y in the S/D regions. The carbon mole fraction incorporated is 0.013. Lattice mismatch of ~0.56% between Si _0.987C_0.013 and Si results in lateral tensile strain and vertical compressive strain in the Si channel region, both contributing to substantial electron-mobility enhancement. The conduction-band offset DeltaE_c between the Si_0.987 C_0.013 source and the strained Si channel could also contribute to an increased electron injection velocity nu_inj from the source. Implementation of the Si_0.987 C_0.013 S/D regions for n-MOSFET provides significant drive current I_Dsat enhancement of up to 50% at a gate length of 50 nm     

Impact of cell size on capacity and handoff in deployed CDMAnetworks

A study into the impact of cell size parameter on the performance of a CDMA network is presented. The findings suggest optimum cell sizes for maximum CDMA capacity and reduced handoff overhead     

An Artificial Intelligence Approach for Solving Stochastic Transportation Problems

Recent years witness a great deal of interest in artificial intelligence (AI) tools in the area of optimization. AI has developed a large number of tools to solve the most difficult search-and-optimization problems in computer science and operations research. Indeed, metaheuristic-based algorithms are a sub-field of AI. This study presents the use of the metaheuristic algorithm, that is, water cycle algorithm (WCA), in the transportation problem. A stochastic transportation problem is considered in which the parameters supply and demand are considered as random variables that follow the Weibull distribution. Since the parameters are stochastic, the corresponding constraints are probabilistic. They are converted into deterministic constraints using the stochastic programming approach. In this study, we propose evolutionary algorithms to handle the difficulties of the complex high-dimensional optimization problems. WCA is influenced by the water cycle process of how streams and rivers flow toward the sea (optimal solution). WCA is applied to the stochastic transportation problem, and obtained results are compared with that of the new metaheuristic optimization algorithm, namely the neural network algorithm which is inspired by the biological nervous system. It is concluded that WCA presents better results when compared with the neural network algorithm.     

Nickel hydroxide deposited indium tin oxide electrodes as electrocatalysts for direct oxidation of carbohydrates in alkaline medium

In this work, the direct electrochemical oxidation of carbohydrates using nickel hydroxide modified indium tin oxide (ITO) electrodes in alkaline medium is demonstrated; suggesting the feasibility of using carbohydrates as a novel fuel in alkaline fuel cells applications. The chosen monosaccharides are namely glucose and fructose; disaccharides such as sucrose and lactose; and sugar acid like ascorbic acid for this study. ITO electrodes are chemically modified using a hexagonal lyotropic liquid crystalline phase template electrodeposition of nickel. Structural morphology, growth, orientation and electrochemical behaviour of Ni deposits are characterized using SEM, XRD, XPS and cyclic voltammetry (CV), respectively. Further electrochemical potential cycling process in alkaline medium is employed to convert these Ni deposits into corresponding nickel hydroxide modified electrodes. These electrodes are used as novel platform to perform the electrocatalytic oxidation of various carbohydrates in alkaline medium. It was found that bare and Ni coated ITO electrodes are inactive towards carbohydrates oxidation. The heterogeneous rate constant values are determined and calculated to be two orders of magnitude higher in the case of template method when compared to non-template technique. The observed effect is attributed to the synergistic effect of higher surface area of these deposits and catalytic ability of Ni(II)/Ni(III) redox couple.     

Benchmarking to the Gold Standard: Hyaluronan‐Oxime Hydrogels Recapitulate Xenograft Models with In Vitro Breast Cancer Spheroid Culture

Many 3D in vitro models induce breast cancer spheroid formation; however, this alone does not recapitulate the complex in vivo phenotype. To effectively screen therapeutics, it is urgently needed to validate in vitro cancer spheroid models against the gold standard of xenografts. A new oxime‐crosslinked hyaluronan (HA) hydrogel is designed, manipulating gelation rate and mechanical properties to grow breast cancer spheroids in 3D. This HA‐oxime breast cancer model maintains the gene expression profile most similar to that of tumor xenografts based on a pan‐cancer gene expression profile (comprising 730 genes) of three different human breast cancer subtypes compared to Matrigel or conventional 2D culture. Differences in gene expression between breast cancer cultures in HA‐oxime versus Matrigel or 2D are confirmed for 12 canonical pathways by gene set variation analysis. Importantly, drug response is dependent on the culture method. Breast cancer cells respond better to the Rac inhibitor (EHT‐1864) and the PI3K inhibitor (AZD6482) when cultured in HA‐oxime versus Matrigel. This study demonstrates the superiority of an HA‐based hydrogel as a platform for in vitro breast cancer culture of both primary, patient‐derived cells and cell lines, and provides a hydrogel culture model that closely matches that in vivo.     

Numerical illustrations of 3D tangent hyperbolic liquid flow past a bidirectional moving sheet with convective heat transfer at the boundary

Convective heat transfer plays a central role in the numerous industrial devices because it perturbs the mechanical behavior of a system along with its thermodynamics. Keeping such applications in mind, analysis of heat transportation in three‐dimensional tangent hyperbolic fluid flow is investigated here. Convective heat transportation at the boundaries is considered. Rosseland's approximation has been used for the radiation effects. Closed form analytical solutions for the governing equations are difficult to obtain even after the use of similarity transformations. Therefore, the numerical solutions are presented through the Runge‐Kutta‐Fehlberg forth‐fifth method. Graphical analysis of the numerical results has been carried out. Roles of sundry constraints on flow are studied. It is also noted that the rates of heat transportation and skin‐friction are higher in the presence of convective heat transfer near the boundary.