全文获取类型
收费全文 | 550篇 |
免费 | 12篇 |
专业分类
电工技术 | 4篇 |
化学工业 | 108篇 |
金属工艺 | 3篇 |
机械仪表 | 7篇 |
建筑科学 | 25篇 |
矿业工程 | 2篇 |
能源动力 | 4篇 |
轻工业 | 134篇 |
水利工程 | 3篇 |
无线电 | 26篇 |
一般工业技术 | 95篇 |
冶金工业 | 105篇 |
原子能技术 | 2篇 |
自动化技术 | 44篇 |
出版年
2023年 | 8篇 |
2022年 | 17篇 |
2021年 | 17篇 |
2020年 | 8篇 |
2019年 | 5篇 |
2018年 | 6篇 |
2017年 | 4篇 |
2016年 | 6篇 |
2015年 | 6篇 |
2014年 | 19篇 |
2013年 | 41篇 |
2012年 | 25篇 |
2011年 | 35篇 |
2010年 | 18篇 |
2009年 | 20篇 |
2008年 | 67篇 |
2007年 | 58篇 |
2006年 | 42篇 |
2005年 | 13篇 |
2004年 | 12篇 |
2003年 | 10篇 |
2002年 | 9篇 |
2001年 | 14篇 |
2000年 | 7篇 |
1999年 | 9篇 |
1998年 | 11篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 4篇 |
1992年 | 8篇 |
1991年 | 4篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 6篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1976年 | 3篇 |
1969年 | 1篇 |
1965年 | 1篇 |
1962年 | 1篇 |
排序方式: 共有562条查询结果,搜索用时 15 毫秒
81.
82.
83.
The enhanced local optical fields at the surface of illuminated metallic nanoparticles and nanostructures are of intense fundamental and technological interest. Here we report a self-consistent measurement of the spatial extent of the fringing field above a plasmonic nanoparticle surface. Bifunctional DNA-based adsorbate molecules are used as nanoscale optical rulers, providing two distinct surface enhanced Raman scattering signals that vary independently in intensity as a function of distance from the nanoparticle surface. While the measurement technique is calibrated on gold nanoshell surfaces with controlled and predictable electromagnetic nanoenvironments, this approach is broadly adaptable to a wide range of plasmonic geometries. 相似文献
84.
Koyama S Haniu H Osaka K Koyama H Kuroiwa N Endo M Kim YA Hayashi T 《Small (Weinheim an der Bergstrasse, Germany)》2006,2(12):1406-1411
Carbon nanotubes hold great promise for use in biomedical fields. Among numerous potential applications, including DNA and protein sensors, bioseparators, biocatalysts, and tissue scaffolds, this article emphasizes the use of carbon-nanotube-filled polymer composites as medical devices, namely, microcatheters. The currently hot topic of the biocompatibility (e.g., toxic properties) of carbon nanotubes is discussed. In addition, critical issues that must be clarified for the full utilization of current carbon-nanotube science and technology in biomedical fields are discussed. 相似文献
85.
Lubick N 《Environmental science & technology》2006,40(19):5827-5828
86.
Lubick N 《Environmental science & technology》2006,40(17):5166-5167
87.
Planar clusters of coupled plasmonic nanoparticles support nanoscale electromagnetic "hot spots" and coherent effects, such as Fano resonances, with unique near and far field signatures, currently of prime interest for sensing applications. Here we show that plasmonic cluster properties can be substantially modified by the addition of individual, discrete dielectric nanoparticles at specific locations on the cluster, introducing new plasmon modes, or transmuting existing plasmon modes to new ones, in the resulting metallodielectric nanocomplex. Depositing a single carbon nanoparticle in the junction between a pair of adjacent nanodisks induces a metal-dielectric-metal quadrupolar plasmon mode. In a ten-membered cluster, placement of several carbon nanoparticles in junctions between multiple adjacent nanoparticles introduces a collective magnetic plasmon mode into the Fano dip, giving rise to an additional subradiant mode in the metallodielectric nanocluster response. These examples illustrate that adding dielectric nanoparticles to metallic nanoclusters expands the number and types of plasmon modes supported by these new mixed-media nanoscale assemblies. 相似文献
88.
Naomi B. Klinghoffer Federico Barrai Marco J. Castaldi 《Journal of power sources》2011,196(15):6374-6381
Autothermal reforming (ATR) of commercial grade JP8 was performed on a Pt/Rh catalyst deposited on a monolith. This study investigated catalyst performance under three test conditions: (i) 120 startup and shutdown cycles, (ii) 80 h of continuous operation with sulfur-free fuel, and (iii) 370 h of testing with JP8 containing 125 ppm of sulfur. Axial reactor temperature profiles and gas composition data showed that startup and shutdown cycling had no impact on catalyst performance. When durability testing was done with fuel containing 125 ppm of sulfur, the catalyst deactivated initially, which was reflected by a decrease in H2 concentration and decrease in fuel conversion. However, after 250 h of operation the activity stabilized at 66% fuel conversion and product concentrations were constant for the remaining 120 h of testing. The presence of sulfur resulted in higher CO selectivity, lower H2 concentrations, and lower fuel conversions compared to data with sulfur-free fuel. The data suggests that the presence of sulfur primarily affects steam reforming reactions, and CO oxidation. Regeneration was attempted with air and with fuel-lean combustion but initial H2 yields and carbon selectivity were not achieved. 相似文献
89.
Analysis of the effects of thermal protein denaturation on the quality attributes of sous‐vide cooked tuna
下载免费PDF全文
![点击此处可从《Journal of Food Processing and Preservation》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Yvan Llave Naomi Shibata‐Ishiwatari Mai Watanabe Mika Fukuoka Naoko Hamada‐Sato Noboru Sakai 《Journal of Food Processing and Preservation》2018,42(1)
Traditional (low temperature, long time) and novel (low temperature, short time) sous‐vide cooking of lean tuna were characterized by analyzing the effects of thermal protein denaturation (TPD) on quality attributes, such as color, appearance, shrinkage, drip loss, and texture. TPD was analyzed by differential scanning calorimetry and estimated for several thermal schedules by kinetic analysis, following the dynamic method. When heated at a rate of 10 °C/min, myosin began to denature at around 35 °C. Actin did not denature, even when the temperature rose to approximately 51 °C, until the denaturation of myosin was complete. However, actin began to denature at approximately 58 °C and was completely denatured at 76 °C. Actin denaturation had a stronger effect than myosin denaturation on texture changes, whereas myosin denaturation was responsible for changes in color and appearance. A better preservation of tuna quality was obtained by novel sous‐vide cooking over the traditional sous‐vide method.
Practical applications
The results of this study are useful to both the research community and industry because they provide quantitative characterization of the consequences of sous‐vide cooking method on food quality explained by estimating TPD. Moreover, the kinetic parameters of the denaturation rate collected for kinetic modeling of the TPD of tuna, not only have application to simulate denaturation of actin and myosin under different thermal schedules of sous‐vide cooking, but also they can be used for the analysis of additional thermal treatments. 相似文献90.
Bovine serum albumin (BSA) was employed as a model protein emulsifier to conjugate with aldohexose (D-glucose (Glc) or D-allose (All)) and sugar fatty acid ester (6-O-octanoyl-D-glucose (GlcC8)) through the Maillard reaction. It was found during the reaction that rate of decrease of free amino groups in BSA was almost the same for the BSA-sugar mixtures whereas browning and protein aggregation developed in the following order: Glc < All < GlcC8. It was thought that the rate of degradation of the Amadori compound could have been influenced by the OH-group stereochemistry at the C3 position of aldohexose, while denaturation of BSA by GlcC8 enhanced the browning and protein aggregation. To understand the emulsifying ability of the BSA-sugar conjugates, hexadecane-water interfacial tension and the oil droplet size of emulsions prepared by homogenizing hexadecane and aqueous solution of the conjugates were examined. BSA-GlcC8 showed greater improvement in interfacial and emulsifying activity than did BSA-Glc and -All. However, no improvement in emulsion stability was observed for any of the BSA-sugar conjugates, suggesting the weakness of the film formed at the oil droplet interface. 相似文献