Growth and characterization of barium copper oxalate single crystals in gels

Barium copper oxalate was grown in silica hydrogel at ambient temperature. The effect of various parameters like gel pH, gel density, gel aging and concentrations of reactants on the growth of these crystals was studied. The crystals grown were characterized by chemical analysis, X-ray powder diffractometry, infrared spectroscopy, thermogravimetric and differential thermal analysis. The results of these observations are described and discussed.     

Application of the method of moments to acoustic scattering from fluid-filled cylinders using three different formulations

In this work, we present three different formulations, namely the pressure field integral equation formulation (PFIE), the velocity field integral equation formulation (VFIE), and the combined field integral equation formulation (CFIE) for solving acoustic scattering problems associated with two-dimensional fluid-filled bodies of arbitrary cross-section. In particular using the boundary conditions on the surface of the body, two equivalent problems, each valid for the outside and inside regions of the scatterer, are derived. By properly selecting the associated equations for these equivalent problems, the three different formulations are derived. The PFIE, VFIE, and CFIE are then solved by approximating the cylindrical cross-section by linear segments and employing the method of moments. Further, it is shown that the moment matrices generated by the PFIE and VFIE are ill-conditioned at resonant frequencies of the cylinder, whereas the CFIE generates a well-conditioned matrix at all frequencies. The solution techniques presented in this work are simple, efficient and applicable to truly arbitrary geometries. Numerical results are presented for certain canonical shapes and compared with other available data.     

Characterization of poly(vinyl alcohol)/sodium bromide polymer electrolytes for electrochemical cell applications

Sodium‐ion conducting polymer electrolytes based on poly(vinyl alcohol) complexed with sodium bromide were prepared with a solution‐casting technique. The structure of these films was determined with X‐ray diffraction, and the complexation of the salt with the polymer was confirmed with Fourier transform infrared spectroscopy studies. Electrical conductivity was measured with an alternating‐current impedance analyzer in the frequency range of 100 Hz to 1 MHz and in the temperature range of 303–373 K. It was observed that the magnitude of conductivity increased with the increase in the salt concentration as well as the temperature. The nature of the charge transport in these polymer electrolyte films was determined with both Wagner's polarization technique and the Watanabe technique. The dominant conducting species were found to be ions, particularly anions. Optical absorption studies were performed in the wavelength range of 200–600 nm, and the absorption edge, direct band gap, and indirect band gap values were evaluated. Electrochemical cells were fabricated, and their discharge characteristics were studied. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Synthesis and characterization of acidic properties of Al-SBA-15 materials with varying Si/Al ratios

Al-SBA-15 of varying Si/Al ratios in the range 11.4–78.4 was synthesized using tri-block copolymer P123. The calcined materials were examined by XRD, pore size distribution, surface area, ²⁷Al NMR spectroscopy. The acidity and acid strength distribution were studied using microcalorimetric adsorption of NH₃. The acidic properties were also examined by cumene cracking reaction as a function of Si/Al ratios. Systematic variation of acidity and activity was observed as a function of Si/Al ratio. The initial heats of NH₃ adsorption correlated well with activity indicate that acid sites with ΔH > 100 kJ/mole is responsible for cumene cracking activity. Linear correlations were obtained with total acidity and cumene cracking activities. The tetrahedral aluminum was found to be responsible for the observed acidities and catalytic activities.     

利用串行RapidIO连接功能增强DSP协处理能力

SRIO IP解决方案提供真实双向数据流,大大增强连接功能。目前,对高速通信与超快计算的需求正与日俱增。有线和无线通信标准的应用随处可见,数据处理架构每天都在扩展。较为普遍的有线通信方式是以太网(LAN、WAN和MAN网络)。手机通信是最为常见的无线通信方式,由应用了DSP的     

Chrestenson函数序列的生成方法及其数学分析

本文提出了适于三种序号的Ｃｈｒｅｓｔｅｎｓｏｎ函数序列的复制方法，对其复制过程进行了数学分析，并指出当Ｃｈｒｅｓｔｅｎｓｏｎ函数退化为Ｗａｌｓｈ函数时，此方法即为复制理论中的平移复制方法。