SAPO-34 supported Pt–Sn-based novel catalyst for propane dehydrogenation to propylene

The Pt–Sn-based catalyst was intensified using SAPO-34 as support for direct propane dehydrogenation to propylene. The catalyst was prepared by sequential impregnation method and characterized by XRF, BET, XRD, NH₃-IR, NH₃-TPD, H₂-TPR, HR-TEM and O₂-pulse coke analysis. NH₃-TPD, IR spectra and XRD results suggested that the doping of metals on SAPO-34 did not affect its acidic strength and structural topology of support, respectively. Propylene selectivity of 94% and total olefins selectivity greater than 97% was achieved using Pt–Sn/SAPO-34. The results were compared with Pt–Sn/ZSM-5 under identical conditions. The possible reasons for improvement were the larger surface area, shape selectivity and particular by suitable acidity of SAPO-34.     

Exploring Regional Profile of Drought History- a New Procedure to Characterize and Evaluate Multi-Scaler Drought Indices Under Spatial Poisson Log-Normal Model

Water Resources Management - Drought is recurrently occurring in many parts of the globe. In contrast to other natural hazards, drought has complex climatic characteristics. Several environmental...     

Attrition behavior of fine particles in a fluidized bed with bimodal particles: Influence of particle density and size ratio

To process the solid particulates in fluidized bed and slurry phase reactors, attrition is an inevitable consequence and is therefore one of the preliminary parameters for the catalyst design. In this paper, the mechanical degradation propensity of the zeolite catalysts (particles) was investigated in a bimodal distribution environment using a Gas Jet Attrition — ASTM standard fluidized bed test (D-5757). The experimentation was conducted in order to explore parameters affecting attrition phenomena in a bimodal fluidization. In a bimodal fluidization system, two different types of particles are co-fluidized isothermally. The air jet attrition index (AJI) showed distinct increases in the attrition rate of small particles in a bimodal fluidization environment under standard operating conditions, in comparison with single particle. A series of experiments were conducted using particles of various sizes, with large particles of different densities and sizes. Experimental results suggest that the relative density and particle size ratio have a significant influence on attrition behavior during co-fluidization. Therefore a generalized relationship has been drawn using Gwyn constants; those defined material properties of small particles. Moreover, distinct attrition incremental phenomenon was observed during co-fluidization owing to the change in collision pattern and impact, which was associated with relative particle density and size ratios.     

SER and throughput analysis of space–time analog network coded relaying system over shadowed Rician fading channels

Wireless Networks - This research article presents an innovative approach based on analog network coding (ANC) in conjunction with space time block coding (STBC) which is termed as space time...     

A decade of in-text citation analysis based on natural language processing and machine learning techniques: an overview of empirical studies

Scientometrics - In-text citation analysis is one of the most frequently used methods in research evaluation. We are seeing significant growth in citation analysis through bibliometric metadata,...     

Evaluation of peanut husk as a novel,low cost biosorbent for the removal of Indosol Orange RSN dye from aqueous solutions: batch and fixed bed studies

The feasibility of using peanut husk biomass for the removal of Indosol Orange RSN dye was explored during this study. Batch experiments were conducted with native, polyethyleneimine (PEI) treated and Na-alginate immobilized biomass. Different important process parameters like pH, contact time, biosorbent dose, initial dye concentration, and temperature were optimized during batch study. Low pH and low biosorbent dose were found to be the feasible conditions for the maximum biosorption of dye. PEI-treated biomass exhibited maximum biosorption capacity (79.5 mg g^?1) for Indosol Orange RSN dye. Pseudo-second-order equation generated the best agreement with experimental data. Different equilibrium isotherm models were applied to the experimental data. Langmuir adsorption isotherm model showed better fitness to the experimental results. Biosorption process was found to be exothermic in nature and thermodynamic study was carried out to check out the feasibility of process. Continuous mode study was performed with native peanut husk biomass to optimize the bed height, flow rate, and initial dye concentration for maximum dye removal. The results indicate that maximum dye removal (8.8 mg L^?1) was obtained with 3 cm bed height and 1.8 mL min^?1 flow rate by using 70 mg L^?1 initial dye concentration. Characterization of biosorbent was carried out by determination of point of zero charge, scanning electron microscopy, and Fourier transform infrared spectroscopy. The findings revealed that peanut husk biomass has a high biosorption potential, and it can be exploited for the treatment of dye containing waste water.