All-organic PANI–DBSA/PVDF dielectric composites with unique electrical properties

Novel all-organic polymer high-dielectric permittivity composites of polyaniline (PANI)/poly (vinylidene fluoride) (PVDF) were prepared by solution method and their dielectric and electric properties were studied over the wide ranges of temperatures and frequencies. To improve the interface bonding between two polymers, dodecylbenzenesulfonic acid (DBSA), a bulky molecule containing a polar head and a long non-polar chain was used both as a surfactant and as dopant in polyaniline (PANI) synthesis. Synthesized conducting PANI–DBSA particles were dispersed in poly(vinylidene fluoride) (PVDF) matrix to form an all-organic composite with different PANI–DBSA concentrations. Near the percolation threshold, the dielectric permittivity of the composites at 100 Hz frequency and room temperature was as high as 170, while the dielectric loss tangent value was as low as 0.9. Like typical percolation system, composites experienced high dielectric permittivity at low filler concentrations. However, their dielectric loss tangent was low enough to match with non-percolative ceramic filler-based polymer composites. Maximum electrical conductivity at 24 wt% of PANI–DBSA was mere 10^?6 S/cm, a remarkably low value for percolative-type composites. Increase in the dielectric permittivity of the composites with increase in temperature from 25 to 115 °C for different PANI–DBSA concentrations was always in the same range of 50–60 %. However, the degree of increase in the electrical conductivity with the temperature was more prominent at low filler concentrations compared with high filler concentrations. Distinct electrical and their unique thermal dependence were attributed to an improved interface between the filler and the polymer matrix.     

Production, purification and thermal characterisation of invertase from a newly isolated Fusarium sp. under solid-state fermentation

Production of invertase employing a newly isolated Fusarium sp. under solid-state fermentation was optimised. Different process parameters were optimised. The maximum enzyme activity under optimum conditions was 47.23 ± 2.12 U gds⁻¹ with nitrogen additives. The enzyme was purified by ammonium sulphate precipitation, diethylaminoethyl cellulose ion-exchange chromatography and Sephadex gel filtration. This protocol gave 20.25-fold purification and 5.53% recovery. The optimum pH and temperature for activity were 5.0 and 50 °C. The K _m and V _max values for the enzyme were 8.33 m m and 21.48 μmol min⁻¹, respectively. A detailed kinetic study of thermal inactivation has been carried out. Enthalpy of activation (Δ H *) decreased when entropy (Δ S *) of activation increased at higher temperatures. Moreover, free energy of denaturation (Δ G *) increased at higher temperature making the enzyme thermally stable. A possible explanation for the thermal inactivation of invertase at higher temperatures is also discussed.     

Experimental study on heat transfer and pressure drop of in-house synthesized graphene oxide nanofluids

Abstract

In this article, first, graphene oxide nanosheets were synthesized in-house according to the modified Hummers method, and these nanosheets were used to prepare graphene oxide nanofluids at two concentrations. Then the thermophysical properties of nanofluids were characterized using X-ray diffraction analysis, a scanning electron microscope, and UV–Vis spectrophotometry. The particle size distribution was investigated using dynamic light scattering. Then, a fundamental study was conducted on the thermal-hydraulic characteristics of graphene oxide nanofluids flowing through a straight copper tube. An experimental setup was developed to find the heat transfer characteristics and pressure drop of nanofluids in the test section consisting of a copper tube with constant heat flux. The flow regimes and associated pressure drop and heat transfer characteristics at varying flow rate were investigated at three different heat flux conditions of 7.4, 9.1, and 12.6?kW/m². Due to the increase in viscosity, flowrate and Reynolds number decreased from 0.01 to 0.1?wt% of graphene oxide nanofluids at constant pump frequency. Experimental data obtained for water were validated with the findings from the literature, and the correlations were formulated for the Nusselt number and Reynolds number by considering the multiple regression analysis. The convective heat transfer coefficient for graphene oxide at 0.01?wt% was higher when compared to graphene oxide at 0.1?wt% and water. The variation of Nusselt number with the heat flux and velocity was insignificant.