Biocompatible electrospun tactic poly(methyl methacrylate) blend fibers

Uniform and beads free fibers of pristine syndiotactic PMMA (s-PMMA), isotactic PMMA (i-PMMA), and their blends in the ratio of s:i = 3:1, 1:1 and 1:3 were successfully prepared using the electrospinning technique. The tactic PMMA blend fibers showed unique thermal stability and glass transition temperatures compared to their pristine counterparts. An interesting endotherm peak was observed for the s:i = 1:3 electrospun fibers, which might indicate a complex formation between the two tactic PMMAs. Systematic surface functionalities study by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) revealed the interactions between these two tactic PMMAs. Biocompatibility of tactic PMMA and their blend fibers was first time comparably investigated using HeLa as the model mammalian cell line; an intriguing observance was first revealed that the blend fibers showed better biocompatibility than both pristine ones, though the behind mechanism is not well understood yet.     

Preparation and characterization of porous PDMS beads for oil and organic solvent sorption

In this article, poly (dimethyl siloxane) (PDMS) porous beads were prepared by suspension polymerization method using n‐octane and carbon tetrachloride (CCl₄) as diluents and pore formation agents. The apparent density, porosity and other characteristics were characterized. The absorption experiments showed that the porous PDMS beads exhibited more absorption capacity and faster absorption rate toward oils than the nonporous or oligoporous PDMS beads did, moreover they are of remarkable stability and recyclability, which could provide a path to absorb the oils floating on water. POLYM. ENG. SCI., 54:2965–2969, 2014. © 2014 Society of Plastics Engineers     

TiB2 Powders Synthesis by Borothermal Reduction in TiO2 Under Vacuum

TiB₂ powders were synthesized by borothermal reduction in nanoscale TiO₂ with boron under vacuum. Reaction processes were investigated, and the effect of by‐product B₂O₃ was evaluated. Results showed that TiO₂ was firstly reduced by boron to form TiBO₃ and Ti₂O₃, and then to produce TiB₂ and B₂O₃ with increasing temperature. The reaction processes of TiB₂ powders synthesis included two‐step reduction in TiO₂ by boron and the removal of B₂O₃. The presence of B₂O₃, which was previously reported as the most important factor in promoting the coarsening of ZrB₂ and HfB₂ powders by borothermal reduction, did not lead to significant coarsening of TiB₂ powders. Due to the minor effect of B₂O₃, TiB₂ powders with small particle size and low oxygen content could be prepared by direct heat treatment of TiO₂ and boron at 1550°C under vacuum for 1 h. The particle size and oxygen content of synthesized TiB₂ powders were ~0.9 μm and ~1.7 wt%, respectively.     

Sintering Behavior and Dielectric Properties of Ultra‐Low Temperature Fired Silver Molybdate Ceramics

Ag₂MoO₄ ceramic was prepared by using the solid‐state reaction method, which could be sintered at 450°C for 2 h, having a relative permittivity of 8.08, a Qf value of 17 000 GHz, and a temperature coefficient of resonance frequency about ?133 ppm/°C. Ag₂MoO₄ ceramic was chemically compatible with silver but reacted seriously with aluminum to form (Ag_0.5Al_0.5)MoO₄ during the sintering. The fitting of infrared spectra and the Shannon's additive rule were employed to study intrinsic dielectric behaviors of the ceramics at microwave region. Ionic displacive polarization and the electronic polarization contributed almost equally to the dielectric permittivity of the ceramic at microwave region. The Ag₂MoO₄ ceramics could be a good candidate for ultra‐low temperature co‐fired microwave devices.     

A New Ferroelectric Phase of YMnO3 Induced by Oxygen‐Vacancy Ordering

Manganese oxides are good candidates of strongly correlated electron materials due to the uniqueness of electronic structure of manganese and the mobility of oxygen among lattice sites under external impacts. Here, we used electron beam as the excitation source to explore the structural evolution of YMnO₃ and identified a new phase under the radiation of electron beam in the transmission electron microscope. Analyses of the electron energy‐loss spectra reveal that this phase originates from ordered oxygen vacancy. We applied the first principles calculation to pick out the optimized stable structure with a lower polarization, and verified its correctness by electron diffraction and image simulations. Analyses of density of states indicate that weak Y–O covalence is favorable for the existence of ferroelectricity, supporting the electrostatic nature of ferroelectricity in the YMnO₃.     

Char barrier effect of graphene nanoplatelets on the flame retardancy and thermal stability of high‐density polyethylene flame‐retarded by brominated polystyrene

Graphene nanoplatelets (GNPs) with the char barrier effect were combined with brominated polystyrene (BPS) and antimony trioxide (Sb₂O₃) to improve the flame retardancy and thermal stability of high‐density polyethylene. Thermogravimetric analysis, limited oxygen index (LOI) testing, and vertical burning testing (UL‐94) showed that the presence of GNPs led to enhanced thermal oxidation stability and significantly reduced the flammability. The addition of 1 wt % GNPs to polyethylene/BPS–Sb (mass ratio = 92/6/2) led to UL‐94 grades from NG (first burning time > 30 s) to V‐2 (total burning time = 14 s), and the LOI value increased from 23.4 to 24.1%. The results of the pyrolysis products provided evidence that the GNPs restricted volatilization. The morphology of the chars also proved the formation of the char layer, which could act as a barrier to isolate the material from the flame and retard the vaporization of flammable gases via a tortuous pathway. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40520.     

Fast accessing Web3D contents using lightweight progressive meshes

Accessing Web3D contents is relatively slow through Internet under limited bandwidth. Preprocessing of 3D models can certainly alleviate the problem, such as 3D compression and progressive meshes (PM). But none of them considers the similarity between components of a 3D model, so that we could take advantage of this to further improve the efficiency. This paper proposes a similarity‐aware data reduction method together with PM, called lightweight progressive meshes (LPM). LPM aims to excavate similar components in a 3D model, generates PM representation of each component left after removing redundant components, and organizes all the processed data using a structure called lightweight scene graph. The proposed LPM possesses four significant advantages. First, it can minimize the file size of 3D model dramatically without almost any precision loss. Because of this, minimal data is delivered. Second, PM enables the delivery to be progressive, so called streaming. Third, when rendering at client side, due to lightweight scene graph, decompression is not necessary and instanced rendering is fully exerted. Fourth, it is extremely efficient and effective under very limited bandwidth, especially when delivering large 3D scenes. Performance on real data justifies the effectiveness of our LPM, which improves the state‐of‐the‐art in accessing Web3D contents. Copyright © 2015 John Wiley & Sons, Ltd.     

Pipelining image compositing in heterogeneous networking environments

Because of intensive inter‐node communications, image compositing has always been a bottleneck in parallel visualization systems. In a heterogeneous networking environment, the variation of link bandwidth and latency adds more uncertainty to the system performance. In this paper, we present a pipelining image compositing algorithm in heterogeneous networking environments, which is able to rearrange the direction of data flow of a compositing pipeline under strict ordering constraint. We introduce a novel directional image compositing operator that specifies not only the color and α channels of the output but also the direction of data flow when performing compositing. Based on this new operator, we thoroughly study the properties of image compositing pipelines in heterogeneous environments. We develop an optimization algorithm that could find the optimal pipeline from an exponentially large searching space in polynomial time. We conducted a comprehensive evaluation on the ns‐3 network simulator. Experimental results demonstrate the efficiency of our method. Copyright © 2016 John Wiley & Sons, Ltd.     

离线低辐射镀膜玻璃

对离线低辐射镀膜玻璃的发展进行了介绍,指出单银、双银和三银离线低辐射镀膜玻璃因为膜系结构的不同而在生产和运营成本上产生了很大差异,进一步分析了3种不同产品的性能及对建筑节能性的影响。     

工业磷化废水处理的实验研究及应用

文章介绍了目前工业磷化废水处理过程中常用的化学沉淀除磷法,研究了pH、PAM投加量的变化对除磷效率的影响。确定了除磷的最佳工艺条件为:pH为7.5~9之间,PAM投加量为300 mg/L。