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11.
Sujith Vijayan Rajaram Narasimman Kuttan Prabhakaran 《Journal of the American Ceramic Society》2013,96(9):2779-2784
Highly concentrated alumina powder suspensions have been prepared in aqueous urea solutions of concentrations in the range 200–360 g/100 mL using an ammonium poly(acrylate) dispersant at 80°C. The dispersant concentration for the suspension viscosity minimum in the urea solutions is higher than that in water due to the higher processing temperature. The urea solutions having higher dielectric constant than that of water offer higher interparticle potential that resulted in better dispersion of the powder as evidenced from the lower viscosity and yield stress of the suspensions. The decrease in temperature increased the suspension viscosity and the suspension formed a strong gel when cooled to room temperature due to the crystallization of urea. The minimum urea solution concentration for a 55 vol% alumina suspension to form a dimensionally stable gel is 240 g/100 mL. The compressive strength and Young's modulus of the gels increased with the increase in urea solution concentration. The alumina ceramics prepared by the urea removal followed by sintering at 1500°C had porosity in the range 28–36 vol% with the rectangular rod‐shaped aligned pores. 相似文献
12.
Silicon - Metal Matrix Nano Composites (MMNCs) are progressive alternatives of formal metal materials, are presently accomplishing a growing inclination of research and engineering approaches for... 相似文献
13.
Mayurkumar S. Gandhi Mayur J. Sathe Jyeshtharaj B. Joshi Pallippattu K. Vijayan 《Chemical engineering science》2011,66(14):3152
Buoyancy induced flow and heat transfer are important phenomena in a wide range of engineering systems e.g. electronics and photovoltaics cooling, thermosiphon heat exchangers, solar-thermal heat absorbers, passive decay heat removal systems, etc. Such systems are subject to thermal stratification. The objective of the present work is to study the single phase and two phase (boiling) natural convection accompanied by thermal stratification. We carried out velocity and temperature measurements in a rectangular tank (0.8×0.6×0.6 m3) fitted with (a) a central tube, and (b) a 10 tube assembly; which form the heat transfer surface. Flows were measured using Particle Image Velocimetry (PIV). Additionally, computational fluid dynamic (CFD) simulations of these systems were performed: first with an assumption of no-boiling (i.e. no phase change) near the heat transfer surfaces; for which we used the open source CFD code OpenFOAM-1.6. For two phase simulations, we used the boiling model of Ganguli et al. (2010) and carried out simulations using the commercial software FLUENT 6.3. The extent of stratification and mixing has been investigated for a range of Rayleigh numbers from 4.34×1011 to 2.59×1014. The flow information obtained from PIV was analyzed for insights into the dynamics of turbulent flow structures. We used the signal processing technique of discrete wavelet transform (DWT) for this purpose. From the analysis, we were able to estimate the size, velocity and energy distribution of turbulent structures in our flows. This information was used to estimate wall heat transfer coefficients. A good agreement was observed between the predicted and the experimental values of heat transfer coefficients. 相似文献
14.
First time in the literature, we report that polyaniline‐EB can be doped by SnCl2 to give conducting SnO2 doped polyaniline novel material. The composite is characterized by Fourier transform infrared, ultraviolet‐visible, X‐ray diffraction, scanning electron micrograph, transmission electron microscopy, and electrochemical methods. The new composite exhibited improved electrochemical properties compared with the virgin polymer. The composite is also expected for its high sensitivity for recognizing volatile organic compounds. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
15.
Sujith Vijayan Praveen Wilson Remani Sreeja Kuttan Prabhakaran 《Journal of the American Ceramic Society》2016,99(12):3866-3873
Open cellular SiC foams with low densities were prepared by thermo‐foaming and setting (130°C–150°C) of silicon powder dispersions in molten sucrose followed by pyrolysis and reaction sintering at 1500°C. The bubbles generated in the dispersion by water vapor produced by the –OH condensation was stabilized by the adsorption of silicon particles on the air‐molten sucrose interface. The composition of a sucrose‐silicon powder mixture for producing SiC foam without considerable unreacted carbon was optimized. The sucrose in the thermo‐foamed silicon powder dispersion leaves 24 wt% carbon during the pyrolysis. The sintering additives such as alumina and yttria promoted the silicon‐carbon reaction. SiC nanowires with diameters in the range of 35–55 nm and length >10 μm observed on the cell walls as well as in the fractured strut region were grown by both vapor–liquid–solid and vapor–solid mechanisms. Large SiC foam bodies without crack could be prepared as the total shrinkage during pyrolysis and reaction sintering was only ~30 vol%. The relatively low compressive strength (0.06–0.41 MPa) and Young's modulus (14.9–24.2 MPa) observed was due to the large cell size (1.1–1.6 mm) and high porosity (93%–96%). 相似文献
16.
Fine grain nanocomposites of (100 ? x) PbZr0.52Ti0.48O3 ? (x) CeO2 with x = 0.5, 1 and 2 wt%, were prepared and characterized for structural and microstructural changes. Addition of ceria nanoparticles resulted into a fine grain microstructure with average grain size ranging from 600 nm to 440 nm and a significant decrease in sintering temperature (~200 °C). Size distribution profile, as analyzed by lognormal distribution function suggests a very narrow size distribution. X-ray diffraction analyses of sintered samples reveal that fine grain PZT/CeO2 nanocomposite could retain distorted tetragonal structure even with grain size as low as 440 nm. Further, complex impedance spectroscopy studies were performed to illustrate the electrical properties of bulk and grain boundary phases in fine grain ceramics. Two electrical processes in the impedance spectra at temperatures above 350 °C were attributed to bulk and grain boundary phase. Magnitude of grain boundary capacitance and corresponding transition was found to be strongly dependent on grain size of the system. Both bulk and grain boundary relaxation processes follows Arrhenius law. 相似文献
17.
Effect of thermal ageing on Nylon 6,6 fibres 总被引:1,自引:0,他引:1
The residual effects of thermal ageing at various temperatures on fibres of the aliphatic polyamide Nylon 6,6 have been studied. Both crystal and macro structural characteristics manifest the residual effects. The former category includes changes in intensity, 2 values and half width. The macro changes include introduction of surface damages in the form of holes, material deposits etc. The fibre also undergoes reduction in weight. The structural changes suggest deterioration in the initial tensile characteristics which has been verified experimentally. A direct correlation between the tensile strength and the angular separation of the equatorial reflections has also been observed. 相似文献
18.
Amino acid - carboxylic acid complexes provide useful information in relation to molecular interactions in present day biological systems and to prebiotic self-organisation. The crystal structures of the complexes of maleic acid with DL- arginine (orthorhombic; Pca2(1); a=15.9829, b=5.4127, c=16.1885; R=0.0522 for 956 reflections) and L- arginine (triclinic; P1; a=5.2641, b=8.0388, c=9.7860, alpha=106.197, beta=97.275, gamma=101.64; R=0.039 for 1749 reflections) have been determined. The complexes are made up of positively charged zwitterionic arginine molecules and negatively charged semi-maleate ions which contain an intramolecular symmetric O-H-O hydrogen bond. In both the structures, the amino acid molecules aggregate into layers. In each layer, S2 head-to-tail sequences are interconnected through specific intermolecular interactions between alpha-carboxylate and guanidyl groups, an arrangement observed for the first time in crystal structures involving arginine. The carboxylate-guanidyl interactions are of different types in the two complexes and consequently aggregation patterns in them exhibit substantial differences. Interactions between the amino acid layers involve the semi-maleate ions in both the complexes. In addition, water-bridges also exist in the L complex. The full potential of the guanidyl group for specific interactions is realized in both the structures. The L complex contains an array of water-mediated salt bridges. The structures demonstrate that the effect of chirality on molecular aggregation can span a wide range. 相似文献
19.
Meta-nitroaniline (m-NA) doped gold/polyvinyl alcohol (Au/PVA) nano-composites are prepared via in-situ reduction of gold salt by employing hydrazine hydrate (HH). Effect of the NLO (non-linear optical) active m-nitroaniline (m-NA) on the photo-physical properties of nano-particles of gold is studied in the colloidal as well as self-supported film form. The UV-Visible absorption bands between 530 and 555 nm due to surface plasmon resonance in Au nano-particles are observed. The absorption values show a shift in the position due to variation in m-NA with respect to the gold concentration. Additional absorption bands are observed after m-NA doping that influences the original position of gold absorption bands. The solutions and the films are further characterized by photoluminescence (PL), FTIR spectroscopy, XRD, TEM and thermal analysis. The particle size as shown by TEM is found to be less than 10 nm. Spin cast nano-composite films show single mode waveguide properties. 相似文献
20.
A new fast adaptive high-performance filter (FAHPF) has been proposed to remove salt-and-pepper noise in images. ‘Maximize the speed without compromising denoising performance’ is the fundamental intention to build up the FAHPF algorithm. Among diverse phases of filtering employed in the FAHPF, overlapping medians (OM) is our newly proposed frame-based filtering concept which is the basis for speed of FAHPF and running averages embedded with OM is an idea behind excellent denoising performance of FAHPF at the same pace. Simulation experiments have been conducted and denoising results of FAHPF has been investigated against very recently developed filtering methods. It is proved that the FAHPF excellently outperforms many of state-of-the-art filters considered for comparison, in terms of peak signal to noise ratio, structural similarity index, and visual representation and requires the extremely shortest execution time among all, which could make it as a real time filter. 相似文献