Covalent triazine framework with efficient photocatalytic activity in aqueous and solid media

Covalent triazine frameworks (CTFs) have been recently employed for visible light-driven photocatalysis due to their unique optical and electronic properties. However, the usually highly hydrophobic nature of CTFs, which originates from their overall aromatic backbone, leads to limitations of CTFs for applications in aqueous media. In this study, we aim to extend the range of the application media of CTFs and design hybrid material of a CTF and mesoporous silica (SBA-15) for efficient photocatalysis in aqueous medium. A thiophene-containing CTF was directly synthesized in mesopores of SBA-15. Due to the high surface area and the added hydrophilic properties by silica, the hybrid material demonstrated excellent adsorption of organic molecules in water. This leads not only to high photocatalytic performance of the hybrid material for the degradation of organic dyes in water, but also for efficient photocatalysis in solvent-free and solid state. Furthermore, the reusability, stability and easy recovery of the hybrid material offers promising metal-free heterogeneous photocatalyst for broader applications in different reaction media.     

为孩子营造美好城市

正毫无疑问,21世纪是城市化的世纪。与此同时,人们越来越认识到,城市化进程不但没有使与经济发展相关的个体生态足迹最小化,反而加剧了这种增长。由于不可持续的城市化进程,地球正处于崩塌的边缘。此外,"人口增长是主要问题,计划生育是拯救我们所居住星球的一剂良方",这一观点的全球语境正在缩小。在城市化的世界背景和老龄化社会的实情之下,呼吁建设儿童友好型的城市很有难度。2018年笔者为联合国儿童基金会撰写了《儿童友好型城市规划手册》(下文简称《手册》)~([1]),这篇文章是基于手册中提出的原则、概念和建议发展     

法国国家图书馆,巴黎,法国

正一个为巴黎而建的广场,一座为法国而建的图书馆这座图书馆是一座缘起之地,而不是一半寺庙一半超市的庞然巨物——请参考巴黎东区。图书馆的所在地位于塞纳河沿岸,是协和广场、战神广场和荣誉军人院等一系列连续场地中的一块。塞纳河沿岸的场地,是区域活化的决定性因素。第十三区的山岗朝向塞纳河,身后是Porte de Choisy和Porte d'Ivry大厦。法国国家图书馆无私地用自己的影响力和光彩推动了区域性保护与复兴。为了对     

蓝色鸣鸟的承诺

当我们驾车向西穿过宾西法尼亚州时，大地披着一层冬装。虽然这不是想念蓝色鸣鸟的季节，但我却无法将它从头脑中驱赶。     

High Power Fiber Bundle Array Coupled LDA Module

1 Introduction High power laser diode arrays (LDA) have many advan- tages such as small volume, long working life, high slope efficiency and high optical density, so they have many applications in medical treatment, material pro- cessing, and for the pumping source of solid laser and etc. But unfortunately, the LDA can not be easy to use directly in these fields because of their poor beam quality and extremely asymmetric divergent beams (!x≈ 5°～10°and !y≈20°～35°, for example), so it …     

用动态规划神经网络模型研究多水库系统的水量分配(下)

为了分析多水库系统中两座水库之间灌溉用水的分配问题，建立了基到动态规划的神经网络模型。为了研究从一座上游水库取水在下游两座之库之间进行水量分配的问题，提出了3个状态变量和4个决策变量的改进的动态规划算法。采用神经网络模型，用3个状态变量动态规划算法得出调度原则，就所研究的多水库系统实例来说，新的动态规划神经网络模型的性能很好，将该模型的性能与临时凑合的标准调度原则和以前推荐使用的约束动态规划神经网络模型进行了比较。     

High Temperature Property Development of Bauxite Based Bricks

Physical properties and microstructural evolution on firing of 3 types of bauxite based refractory bricks were carried out using techniques such as porosimetry,XRD and SEM.The groups differed from each other by progressive refining of the matrix or bond phase.It is revealed that such a refinement of the matrix can improve the high temperature properties of the bricks made from poor grade materials.     

带上DC去踏青——春游DC选购专题

寒冷的冬季已经渐渐远去,而温暖的春天脚步则是越来越急促。俗话讲的好,一年之计在于春,踏青出游成为最佳选择,呼吸清馨泥土的气息让人心情舒畅,邀上三五好友,拿起相机,记录游玩的点滴记忆。如果你还未成为数码E时代的成员,正在打算购买数码相机,那么本期将是一套数码相机装备的饕餮大餐,希望对你的选购有所帮助。     

伊朗卡尔黑水利枢纽

伊朗卡尔黑多目标水利枢纽，首台机组于2002年9月投运。介绍了工程历史，并从导流系统遂洪道、渗漏控制和惟幕灌浆等方面介绍了工程的技术要求。