Assessment of Capillary Rise from Shallow Groundwater by the Simulation Model SIMWASER Using Either Estimated Pedotransfer Functions or Measured Hydraulic Parameters

The performance of the water balance and crop growth model SIMWASER to estimate the water supply of a lawn by capillary rise from shallow ground water was investigated by using lysimeter measurements with a sandy and a clayey soil. Moreover the robustness of the model was evaluated by running it either with measured hydraulic soil parameters or with estimated pedotransfer functions (PTFs) derived from texture and bulk density. Simulations were performed for the years 1996–1998 with input data from the lysimeter station Berlin-Dahlem (Germany) for lysimeters containing undisturbed sandy or clayey soil monoliths, with groundwater at 135 cm depth. Simulated evapotranspiration and percolation/capillary rise were in good agreement with the measured data for all variants, while simulated soil water storage was acceptable only for the variants using hydraulic soil data based on laboratory measurements or using PTFs derived from known soil class and bulk density. PTFs based on mean total pore volume of the respective soil classes yielded soil water storages which were evidently too high; therefore they should be used with care and must be avoided at all in simulating the soil water balance of arid sites with shallow groundwater.     

Scaled model measurements of embedding impedances for SIS waveguide mixers

Several scaled models have been used to determine the contributions of various waveguide mount parameters to the embedding impedance of a mm-wave SIS mixer. Measured effects of waveguide height, substrate orientation and width, junction location, lead inductance and RF-filter impedance are presented and discussed.     

Radiation chemical reactions of poly-p-chlorphenylmethacrylate by ESCA

Summary ESCA is used to characterize ion beam irradiated P(p-ClPhMA)-samples. The results show a chlorine abstraction. The experimental findings are in accordance with a recently proposed model for a crosslinking mechanism of halogenated aromatic polymers.     

Video tape manufacture by high vacuum evaporation—aspects of machine technology

The next generation of video tapes will use evaporated thin films with their superior properties such as recording density, output level, frequency characteristics and signal-to-noise ratio. This paper describes the metal layer formation by a simple model for the growth of microcolumns at oblique incidence deposition. The most relevant process parameters are discussed. The layout of a production coater is described.     

Damage and strain in pseudomorphic vs relaxed GexSi1−x layers on Si(100) generated by Si ion irradiation

We compare both the strain and damage that 100 keV Si irradiation at room temperature introduces in pseudomorphic and relaxed Ge_xSi_1−x films grown on Si(100) substrates. The ion range is such that the Si/Ge_xSi_1−x interface is not significantly damaged. The amount of damage produced in pseudomorphic and relaxed Ge_xSi_1−x layers of similar x for irradiation doses up to 2.5 × 10¹⁴ Si/cm² is the same, which proves that a pre-existing uniform strain does not noticeably affect the irradiation-induced damage. However, the irradiation-induced strain does depend on the pre-existing strain of the samples. Possible interpretations are discussed. On leave from Inst. voor Kern en Stralingsfysika, Catholic University of Leuven, Belgium.     

Towards hybrid Triple Helix indicators: A study of university-related patents and a survey of academic inventors

This paper presents work directed at capturing the entrepreneurial and collaborative activity of university researchers. The Triple Helix points to the emergence of the entrepreneurial university as well as to an increasing overlay of activities in universities, industry and government. This study explores ways in which patent-based metrics could be utilized in a Triple Helix context, and how hybrid indicators could be developed by combining patent with survey data. More specifically, it aims to develop indicators that connect technological inventiveness of university researchers to both funding organizations and users, as well as to entrepreneurial activities by academics. The paper develops a simplified model of the innovation process to benchmark the relevance of the indicators to the Triple Helix. An analysis of Finnish academic patents illustrates that patent data can already provide useful indicators but, on its own, cannot provide information about how academic patents are interconnected with government or industry through funding or utilization links. An exclusive analysis of patents can point to patent concentrations on certain universities, to inventors and assignees, or to potential gaps in translating applied science into industrial technology. However, the patent data had to be combined with an inventor survey in order to relate academic patents more to their Triple Helix environment. The survey indicated that most patented academic inventions are connected to (often publicly funded) scientific research by the inventors and tend to be utilized in large firms rather than in start-up companies founded by academic entrepreneurs.     

Modeling of microwave-excited gas discharges

Content This paper is dealing with the power density versus electric field characteristic of microwave-excited discharges on the example of typical CO₂ laser gas discharges.The fundamentals of the method are a simple electric equivalent circuit for the excitation structure and the assumption of a fixed reduced electric field intensity within the plasma. This operating field is enforced by the plasma under stationary conditions and can be calculated using an electron balance under consideration of the non-Maxwellian electron energy distribution function. The calculations turn out that c.w. excitation with microwaves is involved with considerable plasma power densities. In the case of the CO₂ laser this requires special discharge channel designs for effective gas cooling. Besides a discussion of the plasma characteristic, measurements taken from a microwave applicator are presented and compared to the calculations.

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Modellierung mikrowellenangeregter Gasentladungen

Übersicht Der Artikel behandelt die Berechnung der Feldstärke-Leistungsdichte-Kennlinie mikrowellenangeregter Gasentladungen am Beispiel von Entladungen in typischen CO₂-Lasergasgemischen. Das Berechnungsverfahren beruht auf einem einfachen, auf die meisten Anregungsstrukturen anwendbaren elektrischen Ersatzschaltbild und der Tatsache einer vom Plasma erzwungenen stationären Brennfeldstärke. Letztere wird über eine Elektronenbilanz unter Berücksichtigung der nicht Maxwell'schen Elektronen-Energieverteilung ermittelt. Es zeigt sich, daß bei einer CW-Anregung mit Mikrowellen hohe Mindestleistungsdichten im Plasma auftreten, wodurch beispielsweise im Fall des CO₂-Lasers kein Laserbetrieb ohne sehr effektive Maßnahmen zur Gaskühlung möglich ist.Neben einer Diskussion der Plasmakennlinie werden Vergleichsmessungen an einer konkreten Anregungsstruktur vorgestellt.

     

Formation of droplets on Si surfaces bombarded by In from a capillary type liquid metal ion source

Droplet formation on Si surfaces bombarded by 10 keV beams from a liquid metal indium ion source has been observed. It has been verified that excess indium is transported in the ion beam, probably in the form of charged droplets. SIMS, SEM and RBS techniques have been used to study the distribution of droplets at the surface. At the specified ion source operating conditions, equilibrium droplet coverage is of the order of 25%. Individual droplets have an average diameter of 0.35 ωm and an average height of 2.2 nm. At a bombardment current density of 0.1 mA cm^?2, equilibrium coverage is reached in about 1 s.     

On the Mechanism of Palladium(0)-Catalyzed Reactions of Allylic Substrates with Nucleophiles. Origin of the Loss of Stereospecificity

The mechanism of the loss of stereospecificity in palladium-catalyzed nucleophilic substitution of allylic substrates has been investigated. Eight substrates (cis and trans isomers of 1a-d) and two nucleophiles (Et₂NH and NaCH(SO₂Ph)₂) were studied. In the animation reactions two pathways are responsible for the formation of anomalous inversion product, viz., isomerization of the starting material (path B, Scheme 2) and isomerization of the π-allyl intermediate via displacement of palladium by Pd(0) (path C, Scheme 2), the latter of which predominates. In the alkylation the results indicate that loss of stereospecificity is caused only by path C. The use of a more reactive substrate increased the stereospecificity of the reaction and suppressed the isomerization pathway. An analysis of the kinetics is consistent with the hypothesis that path C is the major pathway for the stereochemical loss.     

Simulation des dichteabhängigen Stofftransportes im Grundwasser und Verifizierung am Beispiel der Saltpool-Experimente

Kurzfassung Die Saltpool-Experimente von OSWALD (1998) und OSWALD & KINZELBACH (2004), im Jahre 1998 an der ETH Zürich ausgeführt, sind exzellente Benchmark-Tests für numerische Simulationsprogramme der dichtevariablen Strömung. Zahlreiche Autoren haben Ergebnisse dazu veröffentlicht. Die kritischen Probleme hierbei sind sowohl die zu dicke Übergangszone von hoher Konzentration an der Sohle der Versuchsbox zum Süßwasser am Top der Box in der Injektionsphase und in der Ruhephase als auch die extrem langen Rechenzeiten.Die Untersuchungen von HÄFNER & BOY (2003a) wurden fortgeführt mit dem erweiterten Code MODCALIF-MST (MODular Flow and CALIbration with Front Limitation algorithm—Multi Species and Temperature). Insbesondere werden Methoden zur Rechenzeitbeschleunigung diskutiert und verifiziert. Durch Nutzung eines algebraischen Multigrid- Gleichungslösers konnte die Rechenzeit um den Faktor 4 verringert werden. Zur Prüfung der Leistungsfähigkeit von MODCALIF-MST wurden die Saltpool Experimente, case 1 und case 2, nachsimuliert und Gitterkonvergenzstudien sowie eine Modellkalibrierung durchgeführt.

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Simulation of density-dependent solute transport in groundwater and verification with saltpool experiments

Abstract The Saltpool experiments by OSWALD (1998) and OSWALD & KINZELBACH (2004), carried out in 1998 at the ETH Zurich, are an excellent benchmark test for numerical simulation programmes of the variable-density flow. Numerous authors published results on this subject. Here, critical problems are the thick transition zones from high concentration at the bottom to fresh water at the top of the box in the injection phase and the rest phase (phases 1–2) as well as the extremely long computing time.We have continued the investigations by HÄFNER & BOY (2003a) with the extended code MODCALIF-MST (MODular Flow and CALIbration with Front Limitation algorithm—Multi Species and Temperature) in double porosity porous media. Especially, the methods for code acceleration are discussed and verified. By incorporating the algebraic multigrid package as linear equation solver, computing times could be reduced by a factor of about 4. Simulations, a grid convergence study and a model calibration were carried out for the experiments case 1 and case 2 with MODCALIF.