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31.
Intumescent coatings are increasingly used as a method of passive fire protection on steel constructions. By forming a carbon network and releasing a blowing agent, the thin intumescent film swells 100‐fold at elevated temperatures. The highly insulating foam effectively prevents the load bearing steel from reaching its critical temperature at which it looses its mechanical properties and collapses. The role of the carbon donor in intumescent coatings has been studied. Comparison in temperature development, foaming ratios, and rheological behavior has been performed between formulations containing pentaerythritol (penta), di–penta, and tri–penta. A simulated fire test, in which the temperature development during intumescence was studied, showed that the formulations containing penta were considerably more efficient in keeping a low temperature throughout the process. A more rapid temperature development was displayed when using di–penta and tri–penta as the carbon donor. Rheometer tests indicate that penta formulations enter the intumescent process at a lower temperature and stays in it for a longer time than di–penta and tri–penta formulations. Furthermore, the crossover temperature and maximum phase angle are shifted towards higher temperatures by replacing penta with di–penta and with tri–penta in the formulations, respectively. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 748–753, 2007 相似文献
32.
Pt/Al2O3 catalysts with platinum contents of 0.1, 1.0 and 3.0 wt% were used for the low temperature combustion of methanol in the absence and the respective presence of a trace amount of ammonia. It is observed that ammonia inhibits the combustion of methanol, which is due to competition between methanol and ammonia for the same sites. For a fixed space velocity and without ammonia in the gas, the performances of the catalysts increase up to a Pt loading of 1.0 wt%. In the presence of ammonia, however, no upper limit of performance is observed with increased Pt content. The results are discussed in terms of both Pt–support interface and the Pt surface being active. 相似文献
33.
EVALUATION OF A METHOD FOR MEASURING MIXING TIME USING NUMERICAL SIMULATION AND EXPERIMENTAL DATA 总被引:10,自引:0,他引:10
Martin Lund n Olle Stenberg Bengt Andersson 《Chemical Engineering Communications》1995,139(1):115-136
A method for measuring mixing performance in large-scale vessels is investigated. The method is evaluated experimentally in a pilotscale reactor and by using a model based on the three-dimensional calculation of the flow field. The method is based on injection of a tracer and measuring the concentration with several detectors at different locations. The mixing performance is measured as the decay rate of the difference between the concentration at the detectors and the final concentration.
The model predicts a strong dependence on injection point. The assumption of a first-order decay rate of the concentration deviation is more appropriate for some injection points. 相似文献
The model predicts a strong dependence on injection point. The assumption of a first-order decay rate of the concentration deviation is more appropriate for some injection points. 相似文献
34.
Monolayer vanadium species are mainly in the V(V) valence state, but with XPS a small fraction of V4+ species are identified. Prolonged analysis treatment increases the V4+ concentration. With increasing vanadium concentration, a monolayer coverage corresponding to 1 mg V2O5 per m2 develops, and it contains additional layers with a thickness of about 250 Å at 4 mg V2O5 per m2, covering 3% of its surface area. 相似文献
35.
Ammoxidation of toluene over the perovskites YBa2Cu3O6.1, YBa2Cu2CoO6.7 and YBaCuCoO4.9 was investigated at 400 °C. At low partial pressures of O2 benzonitrile was selectively formed, while CO2 was the main product at high pressures of O2. Systematic differences in activity were observed for the three phases and are related to the crystal contents of Cu and Co. At low O2 pressures, Cu-sites are active for nitrile formation, while Co-sites give CO2. At high O2 pressures, the activity for CO2 of Cu-sites increases more than that of Co-sites due to filling of near-surface oxygen vacancies. 相似文献
36.
The gas-liquid mass transfer in two-phase flow through a capillary has been measured for water-air, ethanol-air and ethylene glycol-air systems. A semi-theoretical model has been developed and compared with experimental results. and a full computer simulations of the flow pattern and mass transfer using a flow simulation program have been made. The measured values are about 30% less than the calculated values. 相似文献
37.
The main biochemical function of the tocopherols is believed to be the protection of polyunsaturated fatty acids (PUFA) against
peroxidation. A critical question that must be asked in reference to this is whether there is a biochemical link between the
tocopherol levels and the degree of unsaturation in vegetable oils, the main source of dietary PUFA and vitamin E. We used
a mathematical approach in an effort to highlight some facts that might help address this question. Literature data on the
relative composition of fatty acids (16:0, 16:1, 18:0, 18:1, 18:2, and 18:3) and the contents of tocopherols (α-, β-, δ-,
and γ-tocopherol) in 101 oil samples, including 14 different botanical species, were analyzed by principal-component analysis
and linear regression. There was a negative correlation between α- and γ-tocopherols (r=0.633, P<0.05). Results also showed a positive correlation between linoleic acid (18:2) and α-tocopherol (r=0.549, P<0.05) and suggested a positive correlation between linolenic acid (18:3) and γ-tocopherol. 相似文献
38.
The purpose of this investigation was to study the origin of the differences in paper‐to‐paper friction of linerboards based on old corrugated containers (OCC). The sheets were subjected to two extraction stages and analyzed with respect to, surface roughness, and their content of low‐molecular‐mass lipophilic compounds (LLC). Friction was measured using a friction tester based on the horizontal plane principle. The surface roughness was measured using a Perthometer profiler and the low molecular mass lipophilic constituent of the paper sheets was determined by gas chromatography‐mass spectroscopy. The sheets were imaged using environmental scanning electron microscopy (ESEM), and the relative compositions of inorganic ions on the paper surfaces were determined by energy dispersive X‐ray spectroscopy (EDS). The results showed that a high amount of LLC in the sheets lead to low friction, due to lubrication. It was also observed that large CaCO3 particles on the surface had a friction‐increasing effect, and that there was no relationship between the surface roughness and the friction. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1511–1520, 2002 相似文献
39.
Natural rubber vulcanizates of two formulations, with sulfur/N-cyclohexyl-2-benzothiazolesulfenamide (CBS) and tetramethylthiuram disulfide (TMTD), respectively, were analyzed by pyrolysis gas chromatography. A sulfur-selective flame-photometric detector was utilized. The main pyrolysis products were identified as CS2 and some thiophenes. The yields of the pyrolysis products from the two types of rubber were very different. The yields also varied with the curing time of the rubbers. 相似文献
40.
3,7-Dimethyl-2-undecanol, 3,7,9-trimethyl-2-tridecanol, and 3,7, 11-trimethyl-2-tridecanol were synthesized as racemic mixtures in moderate yields. The alcohols are known precursors of the female sex pheromones of the pine sawfly species Diprion nipponica, Macrodiprion nemoralis, and Microdiprion pallipes, respectively. Stereoisomeric mixtures of 3,8,12-trimethyl-2-tridecanol, erythro-(2R,3R,11R/S)-3,11-dimethyl-2-tetradecanol, 3,5-dimethyl-2-tetradecanol, and 5,7-dimethyl-2-tetradecanol, structurally related to sex pheromone alcohol precursors of pine sawfly species, were also synthesized in moderate yields. The key reaction in the syntheses was the ring opening of -butyrolactones by using different alkyl lithiums as nucleophiles. 相似文献