憎水性栀子蓝色素制备的研究

以浓盐酸为催化剂,采用乙酸酐酯化处理水溶性栀子蓝色素,制备了憎水性栀子蓝色素.探讨了栀子蓝色素与乙酸酐料液比、反应时间和反应温度等因素对憎水性栀子蓝色素色价的影响.结果表明:采用料液比1:20,在常温下反应4 h,为制备憎水性栀子蓝色素的最优条件.同时,通过红外光谱、可见吸收光谱及溶解性对栀子蓝色素的酯化改性进行了初步的探讨.     

Local residence time,residence revolution,and residence volume distributions in twin‐screw extruders

This work was aimed at studying the overall, partial, and local residence time distributions (RTD); overall, partial and local residence revolution distributions (RRD) and overall, partial and local residence volume distributions (RVD) in a co‐rotating twin screw extruder, on the one hand; and establishing the relationships among them, on the other hand. Emphasis was placed on the effects of the type and geometry of mixing elements (a gear block and various types of kneading elements differing in staggering angle) and process parameters on the RTD, RRD and RVD. The overall and partial RTD were directly measured in‐line during the extrusion process and the local ones were calculated by deconvolution based on a statistical theory. The local RTD allowed comparing the mixing performance of mixing elements. Also it was confirmed both experimentally and theoretically that specific throughput, defined as a ratio of throughput (Q) over screw speed (N), controlled all the above three types of residence distributions, be they local, partial or overall. The RRD and RVD do not provide more information on an extrusion process than the corresponding RTD. Rather they are different ways of representing the same phenomena. POLYM. ENG. SCI., 48:19–28, 2008. © 2007 Society of Plastics Engineers     

土卡河水电站施工导截流设计

针对土卡河水电站枢纽布置、河道的水文气象条件及坝址区河谷地形等综合因素,介绍土卡河水电站施工导流方案、导流标准以及导流程序设计。根据现场交通条件和实际情况,进行截流设计,并将实际截流发生情况与设计进行比较。     

Global practical stabilization of planar linear systems in the presence of actuator saturation and input additive disturbance

In this note, we revisit the problem of global practical stabilization for planar linear systems subject to actuator saturation and input additive disturbances. A parameterized linear state feedback law is designed such that, by tuning the value of the parameter, all trajectories of the closed-loop system converge to an arbitrarily small neighborhood of the origin in a finite time and remain in there.     

Cr-Mo solid solutions forced by high-energy ball milling

Mixtures of Cr and Mo elemental powders, with the nominal compositions Cr₂₅Mo₇₅, Cr₅₀Mo₅₀, and Cr₇₅Mo₂₅, are processed by high-energy ball milling at ambient temperature. Milling is observed to force the mixing of the immiscible bcc elements Cr and Mo into solid solutions. The lattice parameter of these solid solutions, measured by X-ray diffraction (XRD), displays the expected positive deviation from Vegard’s law. These deviations are compared to the ones predicted by Eshelby’s inclusion model for dilute alloys. The conventional Williamson-Hall approach is shown to fail to determine the grain size in as-milled samples, probably due to the high density of dislocations. Annealing at 700 °C for 10 hours under argon leads to a large reduction in structural defect density, without inducing any significant decomposition. The mixing measured in Cr-Mo is discussed in the broader context of the mechanical mixing forced by ball milling in moderately immiscible systems.     

基于光敏自组装多层膜的液晶光控取向膜

采用layer-by-layer(LBL)的方法，将基板依次在具有光敏双键的季铵盐水溶液和聚乙烯基苯磺酸钠水溶液中浸泡，石英基板表面形成了自组装多层沉积膜。经线性偏振紫外光辐照后，LBL多层膜表现出明显的紫外吸收各向异性。将两片带有各向异性薄膜的基板做成平行液晶器件。在正交的偏光显微镜下观察，发现取得均一、稳定的取向效果。该种光控取向膜有望用作LCoS微显示的取向层。     

关于本地传输网网络优化的探讨

根据长期工作经验,对现有网络存在的问题进行分析,提出对本地传输网网络优化的有关建议。     

Parallel multilevel fast multipole method for solving large-scale problems

The Multilevel Fast Multipole Method (FMM) is a well-established method and can be applied to solve electromagnetic (EM) scattering problems. Compared with other traditional methods, it requires less computational time and memory. However, constrained by a single processor's speed and memory limitations, the problem size that can be solved by serial implementation is still relatively small. For a million-unknown target, the computational time on a single processor is intolerable, and memory could be easily exhausted. Parallel-computing technology, which can utilize multiprocessors, provides an efficient way to solve electrically large-scale EM problems. This paper will focus on discussing the parallel methodologies applied to a multilevel FMM code, as well as demonstrating the computational efficiency of the parallel approach.     

Al-Zn-Ce非晶合金的相选择与组织结构演化

本文研究了具有典型分解特征的Al-Zn-Ce非晶合金的形成和晶化过程，探讨了各种相的生成顺序。XRD和DSC测试结果表明强烈的化合物短程序有利于Al-Zn-Ce非晶合金的形成。在Al-Zn-Ce非晶合金的晶化过程中存在复杂的相选择行为，多种相的竞争形核和有限生长使其具有复杂的结构特点。同时，结果也表明冷速对该体系非晶的形成有很大影响。