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941.
Feifei Li Haoqiang Ai Changmin Shi Kin Ho Lo Hui Pan 《International Journal of Hydrogen Energy》2021,46(24):12886-12896
Electrochemical CO2 reduction reaction (CO2RR) is an efficient way in the utilization of CO2. In this work, single transition-metal (TM) atom (TM = Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn) anchored on two-dimensional (2D) Ti2CN2 are designed for CO2RR using density-functional-theory (DFT) calculation. We show that Ti2CN2 serves as an excellent substrate to support single atom catalysts (SACs), compared to Ti2CO2 and Ti2CF2. We find that the Sc, Ti and V supported on Ti2CN2 show high catalytic activities to produce CO with a low overpotential of 0.37, 0.27, and 0.23 eV, respectively. Differently, the Mn and Fe on Ti2CN2 are catalytically active for the production of HCOOH with a low overpotential of 0.32 and 0.43 eV, respectively. We further show that the negatively charged TM-Ti2CN2 can capture and activate CO2 more effectively, and the catalytic activity and selectivity can be significantly tuned by injecting extra electrons. 相似文献
942.
Lu Yang Dr. Mingwei Liang Dr. Cheng Cui Xiaowei Li Long Li Xiaoshu Pan Hoda Safari Yazd Dr. Min Hong Prof. Jianrong Lu Prof. Y. Charles Cao Prof. Weihong Tan 《Chembiochem : a European journal of chemical biology》2021,22(4):754-759
Functional nucleic acids (FNAs) are garnering tremendous interest owing to their high modularity and unique bioactivity. Three-dimensional FNAs have been developed to overcome the issues of nuclease degradation and limited cell uptake. We have developed a new facile approach to the synthesis of multiple three-dimensional FNA nanostructures by harnessing photo-polymerization-induced self-assembly. Sgc8 aptamer and CpG oligonucleotide were modified as macro chain-transfer reagents to mediate in situ polymerization and self-assembly. Diverse structures, including micelles, rods, and short worms, afford these two FNAs afford these two FNAs with higher nuclease resistance in serum serum, greater cellular uptake efficiency, and increased bioactivity. 相似文献
943.
Jin'ao Yu Xiaogang Tang Shibing Zhu Haopeng Sun Lunxin Zhong Guangyu Yang 《北京理工大学学报(英文版)》2021,30(1):82-90
This paper investigated a QoS-aware power allocation for relay satellite networks. For the given QoS requirements, we analyzed the signal model of relay transmission and formulated the power minimization problem which is non-convex and difficult to solve. To find the optimal solution to the considered problem, we first analyzed the optimization problem and equivalently turn it into a convex optimization problem. Then, we provided a Lagrangian dual-based method to obtain the closed-form of the power allocation and provided an iterative algorithm to the optimal solution.Moreover, we also extended the results to the cooperative transmission mode. Finally, simulation results were provided to verify the superiority of the proposed algorithm. 相似文献
944.
Fei-Fei Cui Ying-Ying Pan Hao-Huang Xie Xiao-Hui Wang Hong-Xue Shi Jian Xiao Hong-Yu Zhang Hao-Teng Chang Li-Ping Jiang 《International journal of molecular sciences》2016,17(3)
Pressure ulcer is a complex and significant health problem in long-term bedridden patients, and there is currently no effective treatment or efficient prevention method. Furthermore, the molecular mechanisms and pathogenesis contributing to the deep injury of pressure ulcers are unclear. The aim of the study was to explore the role of endoplasmic reticulum (ER) stress and Akt/GSK3β signaling in pressure ulcers. A model of pressure-induced deep tissue injury in adult Sprague-Dawley rats was established. Rats were treated with 2-h compression and subsequent 0.5-h release for various cycles. After recovery, the tissue in the compressed regions was collected for further analysis. The compressed muscle tissues showed clear cellular degenerative features. First, the expression levels of ER stress proteins GRP78, CHOP, and caspase-12 were generally increased compared to those in the control. Phosphorylated Akt and phosphorylated GSK3β were upregulated in the beginning of muscle compression, and immediately significantly decreased at the initiation of ischemia-reperfusion injury in compressed muscles tissue. These data show that ER stress may be involved in the underlying mechanisms of cell degeneration after pressure ulcers and that the Akt/GSK3β signal pathway may play an important role in deep tissue injury induced by pressure and ischemia/reperfusion. 相似文献
945.
In this paper, primary attention is paid to the mechanical instability of superelastic NiTi shape memory alloy (SMA) during localized forward transformation at different temperatures. By inhibiting the localized phase transformation, we can obtain the up-down-up mechanical response of NiTi SMA, which is closely related to the intrinsic material softening during localized martensitic transformation. Furthermore, the material parameters of the up-down-up stress-strain curve are extracted, in such a way that this database can be utilized for simulation and validation of the theoretical analysis. It is found that during forward transformation, the upper yield stress, lower yield stress, Maxwell stress, and nucleation stress of NiTi SMA exhibit linear dependence on temperature. The relation between nucleation stress and temperature can be explained by the famous Clausius-Clapeyron equation, while the relation between upper/lower yield stress and temperature lacks theoretical study, which needs further investigation. 相似文献
946.
The networks-on-chip (NoC) communication has an increasingly larger impact on the system power consumption and performance. Emerging technologies, like surface wave, are believed to have lower transmission latency and power consumption over the conventional wireless NoC. Therefore, this paper studies how to optimize the network performance and power consumption by giving the packet-switching fabric and traffic pattern of each application. Compared with the conventional method of wire-linked, which adds wireless transceivers by using the genetic algorithm (GA), the proposed maximal declining sorting algorithm (MDSA) can effectively reduce time consumption by as much as 20.4% to 35.6%. We also evaluate the power consumption and configuration time to prove the effective of the proposed algorithm. 相似文献
947.
建筑的节能设计已经成为了当前建筑设计的一个潮流和趋势。本文在分析民用建筑电气工程节能设计原则的基础上,对民用建筑电气工程节能设计的方法做出了一定的研究。 相似文献
948.
Effect of nitrogen–phosphorus fire retardant blended with Mg(OH)2/Al(OH)3 and nano‐SiO2 on fire‐retardant behavior and hygroscopicity of poplar
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The aim of the study was to screen any possible synergistic effects related to the combination of nitrogen–phosphorus fire retardant and Mg(OH)2/Al(OH)3. This combination is used to improve fire performance, especially smoke suppression of poplar through ultrasonic wave impregnation after microwave treatment. In this study, nano‐SiO2 was used to impregnate poplar treated with nitrogen–phosphorus fire retardant and form a hydrophobic layer on wood cells in order to improve hygroscopicity and reduce water uptake. Cone tests and thermal analysis showed that poplar treated with blended fire retardant had improved behavior. Results show that a 20% and 25% nitrogen–phosphorus fire‐retardant solution (blended by adding 10% Mg(OH)2/Al(OH)3 based on the dry weight of nitrogen–phosphorus fire retardant) was more effective for smoke suppression. The heat release rate, total heat release, and total smoke production of a 25% nitrogen–phosphorus fire‐retardant solution blended by adding 10% Mg(OH)2/Al(OH)3 showed significant reduction. The char residual yield showed a marked increase to 35.5%. Fourier transform infrared analysis suggested a –CH2–Si–CH2– and Si–O–C stretching vibration in nano‐SiO2 treated poplar, which greatly decreased the hygroscopicity of fire‐retardant‐treated poplar. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
949.
Yunyan Liu Shanying Yang Gongxiang Wei Jiaoqing Pan Yuzhen Yuan Chuanfu Cheng 《材料科学技术学报》2013,29(12):1134-1138
Znl_xCoxO (x = 0.05) thin films are deposited on sapphire (0001) substrates by laser-molecular beam epitaxy technique at different substrate temperatures. The structural, stress and morphology evolution features are investigated by means of X-ray diffraction and atomic force microscopy. The surface parameters of roughness exponent α, root mean square (RMS) roughness w and autocorrelation length ~ are calculated and the surface parameters are preliminarily analyzed. The values of ~ vary from 0.7 to 0.9. The RMS roughness w is less than 2.2 nm, and it increases with increasing Ts from 300 to 400 °C, and then decreases when Ts is 500 °C. The autocorrelation length ~ decreases monotonously with the increase in Ts from 300 to 500 °C, which indicates that the increase in Ts restrains the spread of the surface fluctuations until Ts is higher than 400 °C. 相似文献
950.
Shaoxue Jing Tianhong Pan Quanmin Zhu 《International Journal of Adaptive Control and Signal Processing》2021,35(12):2537-2549
The identification of Wiener systems is very difficult because of the output nonlinearity and the parameter product term. To identify the Wiener system, a novel stochastic gradient algorithm based on the multierror and the key term separation is proposed. Firstly, the Wiener system is parameterized as a pseudo-linear model to avoid the products of the parameters. Secondly, a parzen window is used to estimate the probability density function of the error. Thirdly, a stochastic information gradient algorithm with the multierror is adopted to estimate the parameters. The multierror takes the place of the scalar error by the stacked error, which accelerates the algorithm greatly. Fourthly, a variable forgetting factor considering errors is integrated to further speed the algorithm up. Finally, the proposed algorithm is validated by a numerical example and an industrial case. The estimation results indicate that the proposed algorithm can obtain accurate estimates with fast convergence speed. 相似文献