HIx system thermodynamic model for hydrogen production by the Sulfur–Iodine cycle

The HI_x ternary system (H₂O–HI–I₂) is the latent source of hydrogen for the Sulfur–Iodine thermo-chemical cycle. After analysis of the literature data and models, a homogeneous approach with the Peng–Robinson equation of state used for both the vapor and liquid phase fugacity calculations is proposed for the first time to describe the phase equilibrium of this system. The MHV2 mixing rule is used, with UNIQUAC activity coefficient model combined with of hydrogen iodide solvation by water. This approach is theoretically consistent for HI_x separation processes operating above HI critical temperature. Model estimation is done on selected literature vapor–liquid, liquid–liquid, vapor–liquid–liquid and solid–liquid equilibrium data for the ternary system and the three binaries subsystems. Validation is done on the remaining literature data. Results agree well with the published data, but more experimental effort is needed to improve modeling of the HI_x system.     

Bunsen section thermodynamic model for hydrogen production by the sulfur–iodine cycle

A model for the Bunsen section of the Sulfur–Iodine thermo-chemical cycle is proposed, where sulfur dioxide reacts with excess water and iodine to produce two demixing liquid aqueous phases (H₂SO₄ rich and HI rich) in equilibrium. Considering the mild temperature and pressure conditions, the UNIQUAC activity coefficient model combined with Engels' solvation model is used. The complete model is discussed, with HI solvation by water and by iodine as well as H₂SO₄ solvation by water, leading to a very high complexity with almost hundred parameters to be estimated from experimental data. Taking into account the water excess, a successful reduced model with only 15 parameters is proposed after defining new apparent species. Acids total dissociation and total H⁺ solvation by water are the main assumptions. Results show a good agreement with published experimental data between 25 °C and 120 °C.     

Effect of Cr additions on the electrical properties of Ni–BaTiO3 ultra-thin multilayer capacitors

Multilayer ceramic capacitors based on BaTiO₃ dielectric compositions and Ni inner electrodes have complex interfacial reactions that impact the continuity of the inner electrode microstructure. Previously we demonstrated that through the addition of Cr to Ni, a significant improvement in the continuity of ultra-thin Ni electrodes in Ni–BaTiO₃ multilayer capacitors could be achieved. Here, the effect of the Cr addition to the nickel electrode pastes is studied with regard to the electrical properties. Low-field electrical measurements demonstrate no major differences between Cr doped Ni and undoped Ni. However, high-field measurements show a significant decrease to the total capacitor resistance. Under a critical electrical bias the conductivity significantly increases due to a Fowler–Nordheim tunneling conduction though the interfacial Schottky barrier at the dielectric–electrode interface; the onset voltage of this conduction is much lower than with the undoped nickel. Based on these results, we evaluate criteria for the selection of an appropriate refractory metal in order to improve the Ni electrode continuity.     

Optimal Hydropower Generation Under Climate Change Conditions for a Northern Water Resources System

This paper examines climate change impacts on the water resources system of the Manicouagan River (Québec, Canada). The objective is to evaluate the performance of existing infrastructures under future climate projections and the associated uncertainties. The main purpose of the water resources system is hydropower production. A reservoir optimization algorithm, Sampling Stochastic Dynamic Programming (SSDP), was used to derive weekly operating decisions for the existing system subject to reservoir inflows reflecting future climate, for optimum hydropower production. These projections are simulations from the SWAT hydrologic model for climate change scenarios for the period from 2010 to 2099. Results show that the climate change will alter the hydrological regime of the study area: earlier timing of the spring flood, reduced spring peak flow, and increased annual inflows volume in the future compared to the historical climate. The SSDP optimization algorithm adapted the operating policy to the future hydrological regime by adjusting water reservoir levels in the winter and spring, and increasing the release through turbines, which in the end increased power generation. However, there could be more unproductive spills for some power plants, which would decrease the overall efficiency of the existing water resources system.     

Differences in seasonal distribution of wild and stocked juvenile lake trout by depth and temperature in Lake Champlain

Lake trout (Salvelinus namaycush) reared in hatcheries are exposed to an environment and feeding regime that is different from wild lake trout, and are stocked at substantially larger sizes with higher lipid reserves. In addition to differences in diet and growth, this early experience may alter habitat use compared to the wild cohort. We used seasonal data on the depth and temperature distribution of wild and stocked juvenile lake trout to test for differences in habitat use and inform sampling strategies to evaluate annual recruitment. Bottom trawling was conducted from 2015 to 2019 in the central basin of Lake Champlain every two to four weeks during the ice-free season. Differences in distribution of wild and stocked lake trout were most pronounced during thermal stratification, when wild juveniles were more abundant than stocked juveniles at shallower depths and warmer temperatures and stocked juveniles were more abundant at deeper depths and colder temperatures. Temperature preferences may be a consequence of different early rearing environments; wild lake trout are acclimated to lake temperatures and forage, whereas stocked fish entered the lake with high lipid content and little foraging experience. Unbiased assessment of the proportion of wild lake trout and growth and survival of the entire juvenile lake trout population using bottom trawl sampling should either take place in the pre- and post-stratification seasons when wild and stocked fish are at the same depths, or include the full range of depths and temperatures that wild and stocked fish occupy during the stratified period.     

Model-driven visualizations of constraint-based local search

Visualization is often invaluable to understand the behavior of optimization algorithms, identify their bottlenecks or pathological behaviors, and suggest remedial techniques. Yet developing visualizations is often a tedious activity requiring significant time and expertise. This paper presents a framework for the visualization of constraint-based local search (CBLS) algorithms. Given a high-level model and a declarative visualization specification, the CBLS visualizer systematically produces animations to visualize constraints and objectives, violations, and conflicts, as well as the temporal behavior of these measures. The visualization specification is declarative and typically composed of a triple (what,where,how) indicating what to display, where, and with which graphical objects. The visualizer architecture is compositional and extensible. It provides building blocks which can be assembled freely by the user and focuses almost exclusively on static aspects, the dynamic aspects being automated by the use of invariants. The paper highlights various functionalities of the visualizer and describes a blueprint for its implementation.     

Reproducing ten years of road ageing — Accelerated carbonation and leaching of EAF steel slag

Reuse of industrial aggregates is still hindered by concern for their long-term properties. This paper proposes a laboratory method for accelerated ageing of steel slag, to predict environmental and technical properties, starting from fresh slag. Ageing processes in a 10-year old asphalt road with steel slag of electric arc furnace (EAF) type in the subbase were identified by scanning electron microscopy (SEM) and leaching tests. Samples from the road centre and the pavement edge were compared with each other and with samples of fresh slag. It was found that slag from the pavement edge showed traces of carbonation and leaching processes, whereas the road centre material was nearly identical to fresh slag, in spite of an accessible particle structure. Batches of moisturized road centre material exposed to oxygen, nitrogen or carbon dioxide (CO₂) were used for accelerated ageing. Time (7-14 days), temperature (20-40 °C) and initial slag moisture content (8-20%) were varied to achieve the carbonation (decrease in pH) and leaching that was observed in the pavement edge material. After ageing, water was added to assess leaching of metals and macroelements. 12% moisture, CO₂ and seven days at 40 °C gave the lowest pH value. This also reproduced the observed ageing effect for Ca, Cu, Ba, Fe, Mn, Pb, Ca (decreased leaching) and for V, Si, and Al (increased leaching). However, ageing effects on SO₄, DOC and Cr were not reproduced.     

Design of multimaterial processed by powder metallurgy: Processing of a (steel/cemented carbides) bilayer material

A bimaterial, consisting of tough and hard layers, was designed to be processed by powder metallurgy. A materials selection software lead to choose steel and cemented carbide for the tough and hard components. To insure the interlayer compatibility, Fe was selected as base of the tough part and as binder of the hard part. The compositions and the temperature range enabling the simultaneous consolidation of the Fe base by transient liquid phase sintering and of the WC base by liquid phase sintering were defined from thermodynamics data. Experiments lead to define a treatment in two steps: presintering (1080 °C) for the partial densification of the Fe base then sintering (1280–1320 °C) to achieve densification and cohesion of the bimaterial. The sintering temperature increase provided a higher liquid fraction leading to interface cohesion but coarse porosity development. Bimaterial, with fair mechanical properties, were obtained by presintering at 1080 °C then sintering at 1280 °C.