Fusion Generated Fast Particles by Laser Impact on Ultra-Dense Deuterium: Rapid Variation with Laser Intensity

Nuclear fusion D+D processes are studied by nanosecond pulsed laser interaction with ultra-dense deuterium. This material has a density of 10²⁹ cm^?3 as shown in several previous publications. Laser power is <2 W (0.2 J pulses) and laser intensity is <10¹⁴ W cm^?2 in the 5–10 μm wide beam waist. Particle detection by time-of-flight energy analysis with plastic scintillators is used. Metal foils in the particle flux to the detector remove slow ions, and make it possible to convert and count particles with energy well above 1 MeV. The variation of the signal of MeV particles from D+D fusion is measured as a function of laser power. At relatively weak laser-emitter interaction, the particle signal from the laser focus varies as the square of the laser power. This indicates collisions in the ultra-dense deuterium of two fast deuterons released by Coulomb explosions. During experiments with stronger laser-emitter interaction, the signal varies approximately as the sixth power of the laser power, indicating a plasma process. At least 2 × 10⁶ particles are created by each laser pulse at the maximum intensity used. Our results indicate break-even in fusion at a laser pulse energy of 1 J with the same focusing, in approximate agreement with theoretical results for ignition conditions in ultra-dense deuterium. Radiation loss at high temperature will however require higher laser energy at break-even.     

Offshore wind power policy and planning in Sweden

The main objective of this paper is to analyze the role of policy support schemes and planning systems for inducing offshore wind power development in Sweden. Specifically, it highlights the different types of economic, political and planning-related conditions that face offshore wind power investors in Sweden, and provides brief comparisons to the corresponding investment conditions in Denmark, Norway and the UK. The analysis shows that in Sweden existing policy incentives are generally too weak to promote a significant development of offshore wind power, and the paper provides a discussion about a number of political and economic aspects on the choice between different support schemes for offshore wind in the country. Swedish permitting and planning procedures, though, appear favorable to such a development, not the least in comparison to the corresponding processes in the other major offshore wind countries in Europe (e.g., the UK). On a general level the paper illustrates that the success and failure stories of national offshore wind policies and institutions cannot be easily transferred across country borders, and the analysis shows that both the political and the legal frameworks governing the investment situation for offshore wind farms in Denmark, Norway, Sweden and the UK differ significantly.     

Oxygen Activity Calculations of Molten Steel: Comparison With Measured Results

This study sets out to find some model/s that could calculate the closest oxygen activity of molten steel to the measured oxygen activity in an ASEA‐SKF ladle furnace. Ten steel heats grade SAE 52100 were chosen, the oxygen activities of the molten steel after vacuum degassing process were measured, then by means of two different equations and one computer programs the theoretical oxygen activities were calculated and compared to the measured results. In order to calculate the activities of Al₂O₃ in the top slag four different models and two different constants were applied. Both Wagner and Turkdogan's equations were found to be useful. It was seen that increasing the wt% Al from 0 up to 0.05 in molten steel, increasing CaO/Al₂O₃ ratio in top slag, and reducing equilibrium temperature of slag‐steel could contribute to reduction of oxygen activity of molten steel. The scanning electron microscope observations revealed that the main types of observed non‐metallic inclusions in these samples were spinels and calcium aluminates and by increasing the CaO content of the inclusions their equivalent circle diameters grew.     

A physical modelling study to determine the influence of slag on the fluid flow in the AOD converter process

A 1:4.6 scale physical model of a production argon oxygen decarburisation (AOD) converter was used to study the influence of top slag on the AOD process. Specifically, the gas penetration depth, fluid flow and slag behaviour under different nozzle diameters, nozzle numbers and gas flow rates were studied. The results show that the relative gas penetration depth generally increases linearly with an increased gas flow rate and a decreased nozzle size. Furthermore, the slag thickness increases linearly with an increased gas flow rate. In addition, the open-eye size was found to increase exponentially with an increased gas flow rate. Overall, three kinds of fluid flow patterns were found in the experiments: (i) a counter-clockwise rotation, (ii) a clockwise rotation and (iii) a double circulation with the plume in the middle of the converter. A counter-clockwise rotation was most common for the current experimental conditions.     

Photochemical formation of polybrominated dibenzo-p-dioxins from environmentally abundant hydroxylated polybrominated diphenyl ethers

High levels of polybrominated dibenzo-p-dioxins (PBDDs) have been found in Baltic Sea biota, where the toxic load owing to, for example, polychlorinated dibenzo-p-dioxins and other organic pollutants is already high. The levels and geographic pattern of PBDDs suggest biogenic rather than anthropogenic origin, and both biotic and abiotic formation pathways have been proposed. Photochemical formation from hydroxylated polybrominated diphenyl ethers (OH-PBDE) is a proposed pathway for PBDDs in marine environments. Ultraviolet radiation-initiated transformations of OH-BDEs 47, 68, 85, 90, 99, and 123, which all are abundant in the environment, were investigated. It was shown that the most abundant PBDDs in the environment (1,3,7-triBDD and 1,3,8-triBDD) can be formed from the most abundant OH-BDEs (OH-BDE 47 and OH-BDE 68) at high rates and with percentage yields. In fact, most of the PBDDs that have been identified in the Baltic Sea environment were formed with high yield from the six studied OH-PBDE, through initial cyclization and subsequent debromination reactions. The high formation yields point to this route as an important source of PBDDs in biota. However, congeners showing relatively high retention in fish, specifically 1,3,6,8- and 1,3,7,9-tetraBDD, were not formed. These are likely formed by enzymatic coupling of brominated phenols.     

Tectonic Articulation: Making Engineering Logics Speak

As much of the responsibility of a building's physical design and fabrication has increasingly shifted to engineers, spatial communication has remained the sole and significant preserve of architects. Patrik Schumacher , Partner at Zaha Hadid Architects (ZHA), explains how tectonic articulation through architectural design – the selection and employment of technically engineered forms and details – enables the legible enunciation of a building's forms in a manner that has the potential to give it social meaning and expression.     

Passivation of Al–Cr–Fe and Al–Cu–Fe–Cr complex metallic alloys in 1 M H2SO4 and 1 M NaOH solutions

The corrosion mechanisms of Al–Cr–Fe and Al–Cu–Fe–Cr complex metallic alloys have been investigated by potentiodynamic and potentiostatic polarization. Very good passivation of the Al–Cr–Fe surface is exhibited from 1 M H₂SO₄ to 1 M NaOH solutions, which was confirmed by ICP-OES analysis over a period of 273 days. Potentiostatically formed passive films analysed by XPS revealed chromium enrichment in the outermost layer of the aluminium oxy-hydroxide film. Although Al–Cu–Fe–Cr showed passivation during potentiodynamic polarization, heavy active corrosion at OCP was revealed by ICP-OES. For the Al–Cu–Fe–Cr alloy, the 10% content of Cr is insufficient to maintain a protective “chemically stable” Cr oxide/hydroxide.     

Electrochemical growth of self-organized TiO2�CWO3 composite nanotube layers: effects of applied voltage and time

The present work demonstrates that morphology of TiO₂?CWO₃ composite nanotubes formed by alloy anodization can be tuned by controlling applied voltages and time. Distinctive tube morphology can be formed by applying a voltage of more than 80?V. Nanotube diameter and length have a linear relationship with the anodization voltage with a current efficiency of almost 100?%. Furthermore, compared to pure TiO₂, the composite nanotubes show a very uniform tube diameter along the tube axis even at the extended anodization time.     

Calculated phase diagrams,iron tolerance limits,and corrosion of Mg-Al alloys

The factors determining corrosion are reviewed in this paper, with an emphasis on iron tolerance limit and the production of high-purity castings. To understand the iron impurity tolerance limit, magnesium phase diagrams were calculated using the Pandat software package. Calculated phase diagrams can explain the iron tolerance limit and the production of high-purity castings by means of control of melt conditions; this is significant for the production of quality castings from recycled magnesium. Based on the new insight, the influence of the microstructure on corrosion of magnesium alloys is reviewed.     

An exploratory study of the corrosion of Mg alloys during interrupted salt spray testing

A first systematic investigation was carried out to understand the corrosion of common Mg alloys (Pure Mg, AZ31, AZ91, AM30, AM60, ZE41) exposed to interrupted salt spray. The corrosion rates were also evaluated for these alloys immersed in 3 wt.% NaCl by measuring hydrogen evolution and an attempt was made to estimate the corrosion rate using Tafel extrapolation of the cathodic branch of the polarisation curve. The corrosion of these alloys immersed in the 3 wt.% NaCl solution was controlled by the following factors: (i) the composition of the alpha-Mg matrix, (ii) the volume fraction of second phase and (iii) the electrochemical properties of the second phase. The Mg(OH)₂ surface film on Mg alloys is probably formed by a precipitation reaction when the Mg²⁺ ion concentration at the corroding surface exceeds the solubility limit. Improvements are suggested to the interrupted salt spray testing; the ideal test cycle would be a salt spray of duration X min followed by a drying period of (120-X) min. Appropriate apparatus changes are suggested to achieve 20% RH rapidly within several minutes after the end of the salt spray and to maintain the RH at this level during the non-spray part of the cycle. The electrochemical measurements of the corrosion rate, based on the “corrosion current” at the free corrosion potential, did not agree with direct measurements evaluated from the evolved hydrogen, in agreement with other observations for Mg.