Influence of the microstructure of gums on the mechanical properties of silicone high consistency rubbers

This paper is devoted to the characterization and processing of high molar mass vinyl‐bearing polysiloxanes in high consistency silicone rubber (HCR) formulations. The molar masses of five different polydimethylsiloxane gums, bearing vinyl groups at the ends and along their chains, were evaluated by size exclusion chromatography and rheometry. ²⁹Si and ¹H NMR spectroscopy allowed the precise determination of the vinyl content and of the distribution in the different polymers. Typical HCRs formulated from these gums were heat‐cured to process silicone rubber materials that were then tested mechanically. The macromolecular properties were correlated to the final material network structure. The amount of reactive vinyl moieties, rather than their distribution along or at the end of chains, is a key parameter to tailor the material mechanical properties. © 2016 Society of Chemical Industry     

Interpersonal victimization patterns and psychopathology among Latino women: Results from the SALAS study.

[Correction Notice: An erratum for this article was reported in Vol 3(1) of Psychological Trauma: Theory, Research, Practice, and Policy (see record 2010-26899-001). There were citation errors in the last sentence of the first column of text on page 9, and a reference was omitted from the reference list. The sentence should have read: “This result is consistent with other work that has found support for the anxious and dissociative reaction associated with trauma among Latinos and how it may relate to “ataque de nervios” (Hinton, Chong, Pollack, Barlow, & McNally, 2008; Lewis-Fernandez et al., 2002; Schechter et al., 2000; Tolin, Robinson, Gaztambide, Horowitz, & Blank, 2007).] [Correction Notice: An erratum for this article was reported in of Psychological Trauma: Theory, Research, Practice, and Policy (see record 2010-26899-001). In the original article there were citation errors in the last sentence of the first column of text on page 9, and a reference was omitted from the reference list. The sentence should have read: “This result is consistent with other work that has found support for the anxious and dissociative reaction associated with trauma among Latinos and how it may relate to “ataque de nervios” (Hinton, Chong, Pollack, Barlow, & McNally, 2008; Lewis-Fernandez et al., 2002; Schechter et al., 2000; Tolin, Robinson, Gaztambide, Horowitz, & Blank, 2007).] Research on the victimization of Latino women and the subsequent psychological impact has been limited by focusing on individual forms of victimization, primarily partner violence or sexual assault. Another deficiency includes mainly using convenience and/or geographically restricted samples, which impacts the generalizability of the results. To overcome these research limitations, the Sexual Assault Among Latinas (SALAS) study aimed to evaluate the broader scope of victimization among Latino women. The study surveyed a national sample of 2,000 Latino women using random digit dial methodology. Women were asked about various forms of victimization in childhood and adulthood including physical assaults, sexual assaults, stalking, threats, and witnessed violence, as well as psychological symptomatology including depression, anxiety, anger, and dissociation. This analysis found that victimized women were more likely to experience some form of polyvictimization and/or revictimization throughout their lives, with only 36% of victimized women experiencing one form of victimization in childhood or adulthood alone. Furthermore, multiple victimization experiences significantly increased the proportion of women who experienced psychological distress symptoms in the clinical range. For almost all evaluated symptoms, the multiple forms of victimization or varying victimization patterns significantly predicted clinical levels of psychological distress over any specific form or single incident of victimization. The results suggest that victimized Latino women experience multiple forms of victimization and that the evaluation of a broader spectrum of victimization better accounts for pathological symptomatology. Clinical implications for Latino women and future research directions are discussed. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

On the use of masking models for image and audio watermarking

In most watermarking systems, masking models, inherited from data compression algorithms, are used to preserve fidelity by controlling the perceived distortion resulting from adding the watermark to the original signal. So far, little attention has been paid to the consequences of using such models on a key design parameter: the robustness of the watermark to intentional attacks. The goal of this paper is to demonstrate that by considering fidelity alone, key information on the location and strength of the watermark may become available to an attacker; the latter can exploit such knowledge to build an effective mask attack. First, defining a theoretical framework in which analytical expressions for masking and watermarking are laid, a relation between the decrease of the detection statistic and the introduced perceptual distortion is found for the mask attack. The latter is compared to the Wiener filter attack. Then, considering masking models widely used in watermarking, experiments on both simulated and real data (audio and images) demonstrate how knowledge on the mask enables to greatly reduce the detection statistic, even for small perceptual distortion costs. The critical tradeoff between robustness and distortion is further discussed, and conclusions on the use of masking models in watermarking drawn.     

Specificity of different anti-myosin heavy chain antibodies in bovine muscle

Muscle fibre types play an important role in bovine meat tenderness, and conditions the speed of ageing. Two generations of myotubes appear during foetal life. Their differentiation results in several types of fibres differing in their contractile and metabolic properties, namely type I fibres and type II fibres (IIA and IIB). Fibre types were identified using antibodies by immunohistochemistry and western-blotting techniques. The aim was to test different antibodies on foetal and adult muscles by these two techniques. Ten monoclonal antibodies reported to be specific to different myosin heavy chain (MHC) isoforms in other species were tested. Only three antibodies were selected: BF.35, specific for I and IIa MHCs, F1.652 specific for foetal MHC and SC.71 an anti II MHCs (IIa and IIb) antibody. The use of these antibodies will enable a more precise characterisation of muscle fibres and will have applications in the study of bovine muscle ontogenesis.     

Light emission from sources located within metallodielectric planar microcavities

A simple, rigorous electromagnetic formula is derived for predicting the electromagnetic power provided by sources located in transparent or dissipative planar microcavities. With this simple approach, we compare numerically and experimentally the electromagnetic power that escapes the microcavity when the source is located in a metallodielectric or in an all-dielectric resonant planar structure. Although a strong light-extraction coefficient might be expected for metallodielectric microcavities, we show that these attractive structures suffer from metal absorption even when thin metallic layers are used. Experiments implemented with europium chelates located in metallodielectric or in all-dielectric microcavities confirm this result.     

Overexpression of the ferritin H subunit in cultured erythroid cells changes the intracellular iron distribution

To test the hypothesis that variations in H- and L-subunit composition in the ferritin shell affect intracellular iron metabolism, we established stable transfectants of mouse erythroleukemia cells overexpressing the H-ferritin subunit. Analyses were performed on individual clones of transfected cells induced to differentiate with hexamethylenbisacetamide (HMBA). The results showed that there was a reduction in the amount of hemoglobin produced, in inverse relationship with the level of H-subunit overexpression. Incorporation of [2-14C]glycine into heme was reduced by 20% t0 30% in the clones overexpressing H-ferritin subunit compared with control clone. However, the reduction in hemoglobin production was not reversed by addition of heme precursors (delta-aminolevulinic acid or iron) or by hemin itself. A reduced accumulation of beta-globin mRNA was also observed, which could account for the impaired hemoglobin synthesis. Furthermore, synthesis of the endogenous L-ferritin subunit was greatly repressed. Gel retardation assays performed on cytoplasmic extracts of transfected cells using an iron-responsive element (IRE) as a probe revealed that in overexpressing cells, the iron-regulatory protein (IRP) had a conformation with a high RNA-binding affinity, thus leading to translational repression of the endogenous L-ferritin synthesis. These data suggest that an increased formation of H-rich isoferritins leads to a rapid chelation of the regulatory iron pool. While the mechanism underlying the reduction in beta-globin mRNA remains to be elucidated, this study provides direct evidence for the role of IRP-mediated regulation of ferritin expression in erythroid cell metabolism.     

Classement des porteurs de charge et conductivite du compose K8Na4Sb12O36 de structure KSbO3 cubique

Two structures have been reported for cubic KSbO₃ type. One has space group Pn3, where K⁺ ions are in an ordered state. The other has Im3 with K⁺ ions in a disordered state. These ions are weakly bound in large tunnels along 〈111〉 and are mobile along them three-dimensionally.The presence of two alkaline cations in these tunnels is in favour of the ordered state. Single-crystals of K₈Na₄Sb₁₂O₃₆ are obtained and crystallize in the space group Pn3, $\text{a}\text{= 9,515(3)}\text{A}\text{?}$. Using 563 independent reflections, the structure has been refined by full-matrix least squares, to factor R = 0,059.The comparison of the ionic conductivity of ordered (Pn3) and disordered (Im3) compounds is studied by the authors.     

Mesure du Débit d’Absorption Spécifique (das) des téléphones mobiles — contribution du projetcomobio à la normalisation internationale

Human exposure to electromagnetic fields emitted by mobile phones is characterised by the Specific Absorption Rate (sar). This value corresponds to therf power absorbed by unitary mass of the equivalent tissue. It represents the basic restriction used to define limit of human exposure torf electromagnetic fields. Academic and industrial labs have contributed through thecomobio project to define international standards for mobile phones certification.