Autoclave manufacturing of thick composites

Autoclave manufacturing of thermoset composites is determined mainly by heat transfer phenomena. As a matter of fact, the consolidation of composite laminates takes place by the progress of the polymerization, which is activated thermally. The design and control of the autoclave process relies on the capability to manage the relationship between the temperature-pressure cycle of the heat carrier fluid and the temperature distribution through the manufacturing part. In particular, in industrial cases, the main limitations reside in the correct evaluation of the local convective heat transfer conditions through the autoclave and in the evaluation of the local thermal inertia arising from the bagging-tooling system. In this study, the autoclave manufacturing of thick laminates has been addressed by modeling the heat transport phenomena occurring through the composite, the bagging and the tooling system. A new methodology for the evaluation of the energy transfer regimes has been proposed accounting for the heat fluxes from the bag and the tool side, the temperature through-the-thickness gradients and the heat generated by the resin polymerization reaction. The proposed approach enables the prediction of the temperature history of the autoclave assembly without knowledge of the effective thermal inertia of the two external layers, which could be difficult to evaluate owing to possible deformations of the bag during the manufacturing cycle and nonuniform shape of the metallic tool along the part. Experimental data from industrial autoclave runs have been collected and analyzed to validate the method.     

A Hybrid Magneto-Optic Capacitive Memory with Picosecond Writing Time

The long-term future of information storage requires the use of sustainable nanomaterials in architectures operating at high frequencies. Interfaces can play a key role in this pursuit via emergent functionalities that break out from conventional operation methods. Here, spin-filtering effects and photocurrents are combined at metal-molecular-oxide junctions in a hybrid magneto-capacitive memory. Light exposure of metal-fullerene-metal oxide devices results in spin-polarized charge trapping and the formation of a magnetic interface. Because the magnetism is generated by a photocurrent, the writing time is determined by exciton formation and splitting, electron hopping, and spin-dependent trapping. Transient absorption spectroscopy measurements show changes in the electronic states as a function of the magnetic history of the device within picoseconds of the optical pumping. The stored information is read using time-resolved scanning magneto optic Kerr effect measurements during microwave irradiation. The emergence of a magnetic interface in the picosecond timescale opens new paths of research to design hybrid magneto-optic structures operating at high frequencies for sensing, computing, and information storage.     

Analysis of heat transfer in autoclave technology

In autoclave technology, polymer based composites are manufactured under the application of pressure and heat. The heat transferred between the energy carrying fluid and the bag‐composite‐tool element activates exothermic curing reactions, leading to composite consolidation. The convective heat transfer mechanism is the most relevant aspect controlling the rate of chemical and physical transformations associated with composite curing. Moreover, the fluidodynamic regime that results from the interactions between the autoclave and the tool geometry, even if totally predictable in theory, is unattainable in practice. In this study, the heat transfer phenomena occurring during the autoclave manufacturing cycle have been analyzed. The assumption of a negligible through‐the‐thickness thermal gradient led to simplified energy balance equations. In this case, the thermal evolution of the manufacturing elements has been completely determined by two parameters: the global convective heat exchange coefficient, setting the rate of the heat transfer between the autoclave environment and the bag‐composite‐tool element, and the adiabatic temperature rise, establishing the relevance of the polymerization exotherm. A scaling analysis has been performed in order to identify the dimensionless parameters controlling the autoclave process. The developed semitheoretical methodology has been extensively tested by comparison with experimental data from an industrial autoclave.     

DMFCs: From Fundamental Aspects to Technology Development

This review paper describes recent developments in both the fundamental and technological aspects of direct methanol fuel cells (DMFCs). Most previous studies in this field have dealt with fundamental aspects, whereas in recent years, the technology of these devices has become the object of significant interest. This is mainly due to the fact that a probable application of DMFCs in portable power sources and in hybrid electrical vehicles has only recently been envisaged. The section on fundamentals is particularly focused on the electrocatalysis of the methanol oxidation reaction and oxygen electroreduction. In this regard, particular relevance is given to the interpretation of the promoting effect on Pt of additional elements and some aspects of the electrocatalysis of oxygen reduction in the presence of methanol crossover have been treated. The technology section deals with the development of both components and devices. Particular emphasis is given to the development of high surface area electrocatalysts and alternative electrolyte membranes to Nafion, also the fabrication methodologies for the M&E assembly have been discussed. The last part of the paper describes the recent efforts in developing DMFC stacks for both portable and electro‐traction applications. The current status of the technology in this field is presented and some important technical and economical challenges are been discussed.