Hydride formation during cathodic polarization of Ti—II. Effect of temperature and pH of solution on hydride growth

The effect of temperature on the kinetics of hydrogen absorption in α-Ti during galvanostatic cathodic polarization in 0·05M H₂SO₄ at c.d. 1·0 mA/cm² has been studied by direct estimation of the hydrogen content and by determination of the thickness of the surface hydride layer. For the temperature range 25°–100°C the rate of hydrogen absorption is parabolic and increases with temperature. The following equation has been determined for the diffusion of hydrogen occurring during the growth of surface hydride layers on α-Ti:

$D_{\alpha }=6\times {10}^{?2}\exp ?(?14,400\pm 800/RT)c{m}^2{s}^{?1}.$

For vacuum annealed Ti the rate of hydrogen absorption decreases as the pH value of the charging solution increases, and for solutions of pH 10·3 and 14·0 no hydrogen absorption was detected. Surface condition affects hydrogen absorption over the entire pH range 0·3–13·0, hydrogen absorption being greatest for abraded specimens and least for pickled and vacuum annealed specimens.     

Investigation of Heaving at Holloman Air Force Base, New Mexico

Heaving of pavements and a building foundation became progressively worse on a project at Holloman Air Force Base (AFB), N.M. The cause of the heaving was identified as sulfate attack on recycled concrete used as fill and base course below the buildings and pavements. This recycled concrete came from sulfate-resistant airfield Portland concrete pavement that had existed for decades at Holloman AFB without distress. However, severe sulfate exposure conditions, ready availability of water, the more permeable nature of the crushed recycled concrete, less common thaumasite attack, possible soil contamination as a secondary source of alumina, or some combination of these factors allowed sulfate attack to develop in the recycled material even though it had not in the original concrete pavement.     

Rheumatoid-like joint lesions in rabbits injected intravenously with bovine serum

Rheumatoid-like synovial lesions have been produced experimentally in 21% of rabbits receiving intravenous injections of bovine serum by various regimens. They were characterized by lining cell hyperplasia, accumulations, often follicular, of lymphocytes and plasma cells just under the lining layer, sometimes with extensive fibroplasia and pannus formation with cartilage erosion.     

Effect of heart failure on muscle capillary geometry: implications for 02 exchange

There is strong evidence that chronic heart chronic heart failure (CHF) impairs skeletal muscle function independent of blood flow and bulk O2 delivery. Purpose: This investigation sought to determine whether alterations in muscle capillary geometry and surface area that are thought to be primary determinants of the efficacy for blood-tissue 02 exchange might be altered in CHF and contribute to these changes. Methods: Plantaris (fast twitch) and soleus (slow twitch) muscles from control (C) and 6- to 7-wk post myocardial infarcted (CHF) rates were perfusion-fixed in situ. These muscles were analyzed using morphometric techniques that facilitated determination of muscle sarcomere length fiber cross-sectional area, capillary tortuosity and branching coefficient (c(K,0)), capillary length, volume, and surface area. Results: Normalized to a sarcomere length of 2.1 microns, plantaris fiber cross-sectional area decreased by 21% (P < 0.05), and capillary-to-fiber ratio decreased from 2.05 +2- 0.07 in C to 1.79 +2- 0.04 (P < 0.05) in CHF, but these variables were unchanged in soleus. These was no change in c(K,0) or capillary diameter in either muscle, and thus capillary length and surface area per fiber volume remained unchanged. From the measured fiber atrophy and capillary involution in plantaris reductions of total muscle capillary length, volume, and surface area of 11%, 9% and 17%, respectively, are estimated. Conclusion: These changes, coupled with reduced blood flow may impair the effective matching of muscle fiber 02 delivery to 02 requirement during repeated muscle contractions (i.e. exercise). The scenario is expected to reduce intramyocyte 02 partial pressure and thereby contribute to the greater fatigability characteristic of the CHF condition.     

The effects of temperature,chlorine and acids on the survival of Listeria and Salmonella strains associated with uncooked shrimp carapace and cooked shrimp flesh

The purpose of this study was to assess the influence of the association of Listeria and Salmonella with shrimp surfaces on the effects of temperature, chlorine and acids on their survival. Planktonic, attached and colonized cells of Listeria monocytogenes Scott A, L. monocytogenes V7, Salmonella Senftenberg 1734b and S. Typhimurium ATCC 14028 were challenged with high (50°, 60° and 70 °C) and low (4 °C) temperature, 100 ppm sodium hypochlorite solution, and acetic, hydrochloric and lactic acids (pH 4.0). Attached and colonized Listeria and Salmonella showed significantly greater (p < 0.05) resistance to heat (∼1.3–2.6 fold increase in D-values), hypochlorite (∼6.6 ≥ 40.0 fold) and acids (∼4.0–9.0 fold) than their planktonic counterparts. There were no significant differences (p > 0.05) in the survival of planktonic, attached or colonized cells of Listeria and Salmonella stored under refrigerated conditions. The association of Listeria and Salmonella with shrimp surfaces enhances their resistance to heat, chlorine and acids. Both attachment to, and subsequent colonization of, shrimp surfaces by pathogens may reduce the efficacy of methods used in their control. Strategies to reduce attachment of these pathogens to shrimp are required to assure safety of this product.