生物质真空裂解制备磁性活性炭

以生物质杉木屑为原料、四氧化三铁为磁性添加剂、十六烷基三甲基氯化铵和聚氧乙烯月桂醚为复配表面活性剂,采用真空裂解技术,制备了杉木屑基磁性活性炭。考察了体系压力、活化温度、磁性剂质量分数和活化时间对磁性活性炭的碘吸附值、亚甲基蓝吸附值和磁性能的影响。单一因素变量试验结果表明:磁性活性炭对碘和亚甲基蓝的吸附值随着各体系压力、活化温度和活化时间的增加而呈现出先增大后减小的变化规律性,而随着磁性剂添加质量分数的增加而降低。综合考虑各因素,确定其最优制备条件为体系压力10k Pa、活化温度450℃、磁性剂的质量分数10%和保温时间60 min,此条件下制备的磁性活性炭对碘和亚甲基蓝的吸附值分别为935 mg·g~(-1)和315 mg·g~(-1),磁性活性炭的饱和磁化强度为8.24 emu·g~(-1),满足中等强度磁场磁选回收活性炭的要求。     

Sr对Mg-1.7Si合金中初生和共晶Mg_2Si相的变质作用

为了获得性能优良的耐热镁合金,研究了Sr对初生和共晶Mg_2Si相的变质作用,并利用扫描电子显微镜观察了Mg_2Si相的形貌特征与Mg-1.7Si-x Sr合金的微观组织.结果表明,当Sr的质量分数处于1.0%~1.5%范围内时,可对初生和共晶Mg_2Si相进行有效变质.Sr的吸附作用可以诱发孪晶沟槽、旋转晶界等原子扩展台阶的出现,引起原子堆砌方式和晶体生长方向的改变,因而Sr可对初生Mg_2Si相起到变质作用.Sr的添加还可将Mg+Mg_2Si共晶的长大方式由合作长大模式变为以重新形核为主兼有合作长大的混合模式,使得Mg_2Si相的生长形态产生改变,因而Sr可对共晶Mg_2Si起到变质作用.     

石膏板生产线消防系统设计

以圣戈班石膏建材(常州)有限公司石膏板生产线为例,针对石膏板厂消防设计的技术特点和该厂厂区情况,对全厂的消防系统设计作了介绍.其室内外消防给水系统采用稳高压消防给水系统,两台消防水泵分别采用电动机驱动和柴油机直接传动,可供无法设置高位消防水箱及只有一路供电的类似工程消防设计参考用.     

基于物联网的智能停车场系统

针对目前国内智能停车场存在全程物理导航费用高、部分导航表达不明确和无法实现二次导航寻车等问题,设计了利用物联网将数据传输给移动设备实现全程导航的方案,并给出了硬件结构和软件组成。采集停车场停车数据于PC机,通过停车场基站号码段识别技术将数据传输给用户手机,用户利用手机接收的数据进行停车场全程导航和二次导航寻车。通过软硬件设计和调试实验结果表明,数据能够可靠传输到用户手机,用户利用手机接收的数据链接百度地图能够轻松实现停车场内定位、导航和二次导航寻车。     

资水流域短期/长期综合干旱指数的构建与应用

干旱评估作为干旱灾害监测与防御的一个重要方面,如何准确评价并预测研究区域的旱情是当前研究的热点和难点。基于资水罗家庙以上流域的水文、气象资料,分别计算具有不同时间尺度的干旱指数值,利用主成分分析方法,分别研制基于水文模型的短期/长期综合干旱指数并探讨了其在资水流域的适用性。研究结果表明:短期综合干旱指数和长期干旱指数均能很好识别并评价资水流域的历史干旱。研究成果可为长江流域及其他流域建立和健全干旱监测与预警系统提供重要参考。     

边坡工程中抗滑群桩工程特性的数值分析

针对建立抗滑群桩的设计方法问题,分析了抗滑群桩在水平推力作用下的力学行为.以重庆江东边坡的典型断面为例,应用有限元程序CORE3D分析了群桩的桩间颗粒土的土拱区域,结合桩的荷载位移曲线、土拱效应解释了土体应力传递到抗滑桩的规律,通过对影响土拱效应的参数,如桩间距、土体厚度、抗滑桩嵌入深度和桩径等的深入研究,提出了相应的群桩布置参数估算公式.研究成果在重庆江东边坡的防护工程设计中得到了应用,并取得了较好的效果.     

Non-complete relief method for measuring surface stresses in surrounding rocks

The measurement of surface stresses in surrounding rocks with the use of a relief method of annular hole-drilling was studied by numerical analysis. The stress relief process by hole-drilling was then simulated with the use of finite element method. The influences of the borehole diameter（d）, the initial stresses and the ratio of the initial principle stresses on the variations of the remained stress and the released stress in function of the relief depth（h） were discussed. The relation between the non-dimensional ratio of the released principle strains and that of the initial principle stresses, and the effect of the elastic modulus and the Poisson ratio of the rock mass on the stress relief curves were studied. The results show that the stress relief behavior formulated with the non-dimensional ratio of the released stress and the ratio of h/d is only sensitive to the ratio of the initial principle stresses and the Poisson ratio. The stresses are completely released when h equals 1.6d, and the tensile stresses take place on the bore core surface in the relief measurement process. Finally, a non-complete relief method of annular hole-drilling for measuring surface stress in surrounding rocks is proposed and the procedure is presented.     

×Synergistic action of non-solvent induced phase separation in preparation of poly（vinyl butyral） hollow fiber membrane via thermally induced phase separation

A systematic study of air gap distance effects on the structure and properties of poly（vinyl butyral） hollow fiber membrane via thermally induced phase separation （TIPS） has been carried out. The results show that the hollow fiber membrane prepared at air gap zero has no skin layer; the pore size near the outer surface is larger than that near the inner surface; and the special pore channel-like structure near the outer surface is formed, which is quite different with the typical sponge-like structure caused by TIPS and the finger-like structure caused by non-solvent induced phase separation （NIPS）, because of the synergistic action of non-solvent induced phase separation at air gap zero. The pore size gradually decreases from outer surface layer to the intermediate layer, but increases gradually from intermediate layer to the inner surface layer. With the increase of air gap distance, the pore size near the outer surface gets smaller and a dense skin layer is formed, and the pore size gradually increases from the outer surface layer to the inner surface layer. Water permeability of the hollow fiber membrane decreases with air gap distance, the water permeability decreases sharply from 45.50× 10^-7 to 4.52× 10^-7 m^3/（m^2-s.kPa） as air gap increases from 0 to 10 mm at take-up speed of 0.236 m/s, further decreases from 4.52×10^-7 to 1.00×10 ^-8m^3/（m^2.s·kPa） as the air gap increases from 10 to 40 mm. Both the breaking strength and the elongation increase with the increase of air gap distance. The breaking strength increases from 2.25 MPa to 4.19 MPa and the elongation increases from 33.9% to 132.6% as air gap increases from 0 mm to 40 mm at take-up speed 0.236 m/s.     

Effects of coagulation bath temperature on structure and performance of poly （vinyl butyral） hollow fiber membranes via thermally induced phase separation

Poly （vinyl butyral） （PVB） hollow fiber membranes were fabricated via thermally induced phase separation （TIPS）. The effects of coagulation bath temperature （CBT） on the structure and performance of membranes were investigated in detail. The morphologies of the membranes were studied by scanning electron microscopy （SEM）, the performances of water permeability, rejection, breaking strength and elongation were measured, respectively. The results indicate that all the membranes have the asymmetric morphology and the thickness of the skin layer decreases and the pore size of the outer layer increases with the increase of CBT. The permeability of membranes prepared at air gap 1.0 cm and take-up speed 0.253 m/s increases from 1.047×10-7 to 5.909×10-7 m3/（m2·s-kPa） with the CBT increasing from 20 ℃ to 40℃, and sharply increases to 35.226×10 7 m3/（m2.s.kPa）once the CBT arrives at 50 ℃. While the carbonic ink rejections have no significant decrease, totally exceed 98%, but that of acid-maleic acid copolymer greatly decreases with the increase of CBT. Both the breaking strength and elongation decrease with the increase of CBT.     

Bioleaching of pyrrhotite by Sulfobacillus thermosulfidooxidans

The bioleaching of pyrrhotite was investigated using Sulfobacillus thermosulfidooxidans.The effects of pH,pulp concentration,inoculation amount,external addition of ferrous and ferric ions were examined.The pH is found to exert a profound effect on the leaching process for controlling the bacterial activity and precipitation of ferric ions mainly as jarosite.The results show that low pulp content increases the leaching rate of iron.The inoculation amount from 1×107 cell/mL to 1×108 cell/mL has positive effects on the leaching rate.The results also imply that addition of ferrous sulfate（1 g/L） is required for the bacteria to efficiently drive the extraction of iron,however,the leaching efficiency has no obvious enhancement when 2 g/L ferrous sulfate was added.Comparatively,addition of ferric sulfate（2 g/L） significantly inhibits the bioleaching process.At the end of bioleaching,jarosite and sulfur are observed on the surface of pyrrhotite residues by using XRD and SEM.With the passivation film formed by jarosite and sulfur,the continuous iron extraction is effectively blocked.