Proline-derived in situ synthesis of nitrogen-doped porous carbon nanosheets with encaged Fe2O3@Fe3C nanoparticles for lithium-ion battery anodes

The homogeneous incorporation of heteroatoms into two-dimensional C nanostructures, which leads to an increased chemical reactivity and electrical conductivity as well as enhanced synergistic catalysis as a conductive matrix to disperse and encapsulate active nanocatalysts, is highly attractive and quite challenging. In this study, by using the natural and cheap hydrotropic amino acid proline—which has remarkably high solubility in water and a desirable N content of ~12.2 wt.%—as a C precursor pyrolyzed in the presence of a cubic KCl template, we developed a facile protocol for the large-scale production of N-doped C nanosheets with a hierarchically porous structure in a homogeneous dispersion. With concomitantly encapsulated and evenly spread Fe₂O₃ nanoparticles surrounded by two protective ultrathin layers of inner Fe₃C and outer onion-like C, the resulting N-doped graphitic C nanosheet hybrids (Fe₂O₃@Fe₃C-NGCNs) exhibited a very high Li-storage capacity and excellent rate capability with a reliable and prolonged cycle life. A reversible capacity as high as 857 mAh•g^–1 at a current density of 100 mA•g^–1 was observed even after 100 cycles. The capacity retention at a current density 10 times higher—1,000 mA•g^–1—reached 680 mAh•g^–1, which is 79% of that at 100 mA•g^–1, indicating that the hybrids are promising as anodes for advanced Li-ion batteries. The results highlight the importance of the heteroatomic dopant modification of the NGCNs host with tailored electronic and crystalline structures for competitive Li-storage features.

     

Preparation and microwave absorbing properties of nickel-coated carbon fiber with polyaniline via in situ polymerization

Electric conductive and microwave absorbing material PANI/Ni/CF was prepared by in situ polymerization of polyaniline on the surface of nickel-coated carbon fiber (Ni/CF). The morphologies and structures of CF, Ni/CF, PANI and PANI/Ni/CF were characterized by scanning electron microscope and X-ray diffraction. Results show that the CF was wrapped tightly around the nickel layer, and the Ni/CF was coated by PANI. Measurement of four probes resistance tester indicates that the electrical conductivity of PANI/Ni/CF was great improved compared with PANI and PANI/CF. Vibrating sample magnetometry shows that the magnetic saturation intensity of Ni/CF and PANI/Ni/CF was 13.8 and 2.3 emu/g, respectively. According to the vector network analyzer, the microwave absorbing properties of PANI/Ni/CF were better than those of PANI and PANI/CF, and its minimum loss value is ?12.4 dB at 8.8 GHz.     

Peptidyl Virus-Like Nanovesicles as Reconfigurable “Trojan Horse” for Targeted siRNA Delivery and Synergistic Inhibition of Cancer Cells

The self-assembly of peptidyl virus-like nanovesicles (pVLNs) composed of highly ordered peptide bilayer membranes that encapsulate the small interfering RNA (siRNA) is reported. The targeting and enzyme-responsive sequences on the bilayer's surface allow the pVLNs to enter cancer cells with high efficiency and control the release of genetic drugs in response to the subcellular environment. By transforming its structure in response to the highly expressed enzyme matrix metalloproteinase 7 (MMP-7) in cancer cells, it helps the siRNA escape from the lysosomes, resulting in a final silencing efficiency of 92%. Moreover, the pVLNs can serve as reconfigurable “Trojan horse” by transforming into membranes triggered by the MMP-7 and disrupting the cytoplasmic structure, thereby achieving synergistic anticancer effects and 96% cancer cell mortality with little damage to normal cells. The pVLNs benefit from their biocompatibility, targeting, and enzyme responsiveness, making them a promising platform for gene therapy and anticancer therapy.     

PLC控制在转炉上的应用案例

介绍荣信钢铁转炉过程控制系统的组成、系统功能、技术应用。     

记忆与延续——浅析苏州博物馆与宁波博物馆建筑设计

博物馆建筑,是一个城市文化的象征,如何使博物馆具有文化感,体现传统的审美文化,又具有新的设计元素,引导人类审美意识,苏州博物馆与宁波博物馆做了比较好的探索。     

基于词性的文本挖掘算法在IDS日志中的应用

提出一种以词性为参考值的文本挖掘算法,能有效挖掘与种子词有关的关联规则。基于Bootstrapping算法思想,既减少了预处理阶段对于词根还原的依赖,能处理日志中出现的中文词汇。增加了对于日志文本上下的理解,提高了关联规则的有效性,并应用与IDS日志挖掘之中,有效改善挖掘效率,为规则库提供关联规则。     

A belief-rule-based inventory control method under nonstationary and uncertain demand

This paper is devoted to investigating inventory control problems under nonstationary and uncertain demand. A belief-rule-based inventory control (BRB-IC) method is developed, which can be applied in situations where demand and demand-forecast-error (DFE) do not follow certain stochastic distribution and forecasting demand is given in single-point or interval styles. The method can assist decision-making through a belief-rule structure that can be constructed, initialized and adjusted using both manager’s knowledge and operational data. An extended optimal base stock (EOBS) policy is proved for initializing the belief-rule-base (BRB), and a BRB-IC inference approach with interval inputs is proposed. A numerical example and a case study are examined to demonstrate potential applications of the BRB-IC method. These studies show that the belief-rule-based expert system is flexible and valid for inventory control. The case study also shows that the BRB-IC method can compensate DFE by training BRB using historical demand data for generating reliable ordering policy.