This research studied the mechanisms of Ca and Zn microalloying on the enhancement of ductility of extruded Mg-Gd sheet by combing electron backscattered diffraction and slip trace analysis.The ductil-ity and microstructure of extruded Mg-0,6Gd and Mg-0.6Gd-0.3Ca-0,2Zn (wt%) sheets were investigated.Basal slip was the main deformation mode under investigation.Ca and Zn microalloying increased the frequency of grain boundaries (GBs) with misorientation angles (θs) < 35°,promoted slip transfer across GBs and restricted the basal slip localization.In addition,there were a higher number of GB cracks homo-geneously distributed in the Mg-0.6Gd sheet than in the Mg-0.6Gd-0.3Ca-0.2Zn sheet,attributed to the increased cohesion of GBs.The enhancement of basal slip,the suppression of slip localization and the suppression of GB cracking were contributed to the increased ductility for Mg-0.6Gd-0.3Ca-0.2Zn sheet. 相似文献
The structure of bacterial cellulose(BC)produced by Acetobacter xylinum NUST~4(A.xylinum NUST~4)under static(SBC)and shake culture condition(ABC)was studied by means of transmission electron microscopic(TEM),X-ray diffraction(XRD)and Fourier transform-infrared spectrum(FT-IR).It was revealed that BC isⅠcrystal cellulose and the proportion of celluloseⅠ_αexceeds 80% and BC diameter is 10-80 nm. Mechanical properties and water absorption capacity were also determined.These properties cottld result from crystalline and nanometer structure of BC. 相似文献
In this paper, LaFe0.75Cr0.25O3 was synthesized by a citric acid combusting sol–gel method. The basic structural information is reflected by XRD. According to Mössbauer spectroscopy, the inhomogeneous distribution of Cr contributes to magnetic dilution, thus appearing the coexistence of singlet and sextet. Simultaneously, the rare superparamagnetic relaxation appears due to “critical superparamagnetism” caused by small magnetic clusters with intervening sizes. Oxygen vacancies of synthesized sample are also found. The DC magnetization curve reveals the magnetization reversal phenomenon, which is related to the competition between the Dzyaloshinsky–Moriya interaction (DMI) and the magnetic anisotropy belonging to single ions. At 300 K, LCFO reveals weak magnetism. No magnetic transition is observed below 400 K.