软模板法合成有序介孔材料的研究进展

有序介孔材料具有高度有序的孔道结构,较高的比表面积和较多活性位,已经广泛应用于气体吸附、催化剂和功能材料等领域。本文系统评述了软模板法制备有序介孔材料的合成路线及其组装机理,并对课题组采用软模板法组装介孔氧化钛粒子的机理进行了分析。     

Kilogram-scale synthesis of Mg-Al-CO3 LDHs nanosheets using a new two-stage reactor

A novel reactor with a two-stage reaction chamber was designed to kilogram-large-scale synthesized Mg-Al-CO₃ layered double hydroxide (Mg-Al-CO₃ LDHs) nanosheets. The effects of the reactant concentration and rotation speed of the dynamic structure on the crystal size and morphology were investigated. The results show that the size of Mg-Al-CO₃ LDH particles gained in typical condition is about 50 nm in length and 5.7 nm in thickness, and the size becomes larger as the reactant concentration or rotationl speed decreased. The possible reaction mechanism was explained by three critical factors of the reactor, N₂ gas and polyethylene glycol 2000.     

针状微胶囊Mg(OH)_2/EVA纳米复合材料的制备及性能研究

将自制针状微胶囊纳米氢氧化(镁Mg(OH)2)与乙烯-乙酸乙烯共聚(物EVA)经双螺杆挤出机熔融共混挤出造粒,然后利用注射机制成针状微胶囊Mg(OH)2/EVA纳米复合材料,对其力学性能、热稳定性和流变性能进行了研究。结果表明:纳米Mg(OH)2用量为4%时,复合材料的拉伸强度最大,加工流动性较好;在低温区时,纳米Mg(OH)2含量对复合材料的热稳定性能几乎没有影响,在高温区时,纳米Mg(OH)2的加入使其热稳定性略有提高。     

钢塑复合冲淤管的开发与应用

针对当前围堰造地与环境保护之间出现的问题,开发了一种钢塑复合冲淤管。经过工程试验证明这是一种切实可行的新技术,使用该产品做成的冲淤坝具有很好的冲淤能力。该产品的推广使用可减小围堰造地对环境的影响,加快冲淤速度,缩短围堰造地周期,节约造地成本。     

霞家河灌区续建配套与节水改造工程规划与研究

霞家河灌区是以一座中型水库为主要水源,利用灌区内小型水库、塘堰作调节,通过干渠相互沟通形成的长藤结瓜式灌溉系统,运行以来社会、经济效益巨大,但也存在工程布局不合理、水资源分配不优、工程老损失修等问题。在此提出了霞家河灌区续建配套与节水改造工程规划设计,同时对灌区工程规划设计的可行性进行了研究分析。     

GW286计算中心微机管理系统

本文详述了如何在GW286微机上利用DBASEⅢ软件对学生上机进行管理,以及如何完成上机课程表的排列、打印各种统计报表;此外,还介绍了实现DBASEⅢ与其他高级语言相互调用的方法。     

A comparison of techniques for preparing fish fillet for ICP-AES multielemental analysis and the microwave digestion of whole fish.

Four catfish fillet homogenate treatments before multielemental metal analysis by simultaneous inductively coupled plasma/atomic emission spectroscopy were compared in triplicate. These treatments were: nitric acid wet-ashing by Parr bomb digestion; nitric acid wet-ashing by microwave digestion; tetramethylammonium hydroxide/nitric acid wet digestion; and dry-ashing. The tetramethylammonium hydroxide/nitric acid method was imprecise (coefficients of variation > 20%). The dry-ashing method was fast and sensitive but had low recoveries of 50% for spiked Pb and Al and was not as precise as the Parr bomb or microwave treatments. The Parr bomb method was the most precise method but was less sensitive than the microwave method which had nearly the same precision. The microwave method was then adapted to homogenates of small whole fish < or = 3 cm in length. The whole fish homogenate required more vigorous digestion conditions, and addition of more acid after the evaporative step because of the presence of less oxidizable and acid-soluble components than fillet. The whole fish homogenate was also more heterogeneous than catfish fillet. A quality assurance protocol to demonstrate homogenate uniformity is essential. The use of a non-specialized microwave oven system allowed precise results for fillet and whole fish homogenates.     

天然裂缝性储层的特征

天然裂缝性储层给开采带来了一个矛盾难题。这类储层包括低油气采收率储层,这些储层最初可能表现出高产,但产能下降得非常快。此外,这类储层还经常出现早期见气或见水等问题。而另一方面,一些天然裂缝性储层也是全球最大、产量最高的储层。这类储层的这种矛盾特性激发业界尽力去深入了解其特征,以便更有把握地对其进行模拟分析。     

渣油中硫和硫类型分布对热转化产物中硫分布的影响

考察了热转化反应条件对胜利和孤岛渣油热转化产品中硫分布的影响。在研究原料中硫、硫醚硫、噻酚硫分布和残分布的基础上，探讨了原料硫分布与热转化产品中硫分布的关系。     

LABORATORY STUDY OF REAL-TIME OPTICAL MICROSCOPE TRACKING OF THERMAL REACTION PROGRESS OF VACUUM RESIDUA II: CHEMICAL RELEVANCE OF PHYSICAL PROCESSES IN THERMAL REACTION SYSTEMS OF VACUUM RESIDUA

It has been indicated from analyses of the vicissitude of chemical states and their comparisons with the occurring physical processes in the thermal reaction systems of vacuum residua that the first characteristic state point coincides with the induction period of coke formation, and the third characteristic state point, immediately after which a large amount of coke is yielded, manifests the critical point at which concentration of the neo-asphaltenes generated in-situ by the fast-reaction resins is high enough to approach its phase separation. The industrial implication of the second characteristic state point is not clear enough. It is accordingly pointed out, in combination with the conclusions drawn in the first part of the serial, that the real-time optical microscope tracking of the thermal reaction progress of vacuum residua based on the first and third characteristic state points is feasible on the laboratory scale for forecasting the sudden changes of the physical and/or chemical states of the thermal reaction systems of vacuum residua, and is expected to find applications in the industrial visbreaking process.