物理场强化溶液结晶应用研究进展

结晶是食品和化工分离中的一个重要单元操作。文章阐述了溶液结晶的原理，综述了超声场、微波场、静电场、磁场等物理场在溶液结晶中的应用，分析和探讨了它们对溶液结晶的影响机理，并且对今后的发展进行了展望。     

废弃木粉与短切玻璃纤维组合增强聚丙烯的力学性能

用废弃木粉与短切玻璃纤维作为增强材料，制得了组合增强的聚丙烯复合材料，研究了制备工艺及设备、材料配方及界面改性方法等对材料力学性能的影响。结果表明，用单螺杆挤出机制备组合增强材料，可减少对玻璃纤维的损伤，保持较长的玻璃纤维，有利于其增强作用的发挥；随着玻璃纤维含量的增加，体系的力学性能提高，而木粉含量对材料力学性能的影响与玻璃纤维的含量相关；采用硅烷偶联剂对木粉进行表面处理，在基体中添加接枝极性基团的改性聚丙烯，可改善体系的界面结合，提高力学性能。     

大型常压锥顶贮罐的设计

以工程实例为依据，论述国内以往较少采用的大型梁柱式支承锥顶贮罐的结构，介绍了国内外相关设计标准，给出了贮罐的典型结构－斜椽，横梁和立柱的计算公式，并用Excel电子表格编制了计算书。     

Study of different effect on foaming process of biodegradable bionolle in supercritical carbon dioxide

Microcellular foaming of biodegradable Bionolle in supercritical CO₂ has been produced. The effects of a series of variable factors, such as saturation temperature, saturation pressure, and depressurization time and step on the foam structures and density, were studied through measurement of density and SEM observation. The experimental results show that higher saturation temperatures lead to an increase in bulk densities; and different depressurization time and step result in different product cell morphology. In addition, at some saturation temperature, the orientation of the cells can be found in the product morphology. XRD experimental results show that the foaming treatment with SC CO₂ increased the crystallinity of Bionolle. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2901–2906, 2006     

Structure and properties of nitrile rubber (NBR)–clay nanocomposites by co‐coagulating NBR latex and clay aqueous suspension

Nitrile rubber (NBR)–clay nanocomposites were prepared by co‐coagulating the NBR latex and clay aqueous suspension. Transmission electron microscopy showed that the silicate layers of clay were dispersed in the NBR matrix at the nano level and had a planar orientation. X‐ray diffraction indicated that there were some nonexfoliated silicate layers in the NBR–clay nanocomposites. Stress–strain curves showed that the silicate layers generated evident reinforcement, modulus, and tensile strength of the NBR–clay nanocomposites, which were significantly improved with an increase in the amount of clay, and strain‐at‐break was higher than that of the gum NBR vulcanizate when the amount of clay was more than 5 phr. The NBR–clay nanocomposites exhibited an excellent gas barrier property; the reduction in gas permeability in the NBR–clay nanocomposites can be described by Nielsen's model. Compared with gum NBR vulcanizate, the oxygen index of the NBR–clay nanocomposites increased slightly. The feasibility of controlling rubber flammability via the nanocomposite approach needs to be evaluated further. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 3855–3858, 2003     

二氨丙基苯固化剂的合成及应用

以无水三氯化铝为催化剂,用苯和1,3-口恶嗪-2-酮进行氨丙基化反应合成了二氨丙基苯。研究了物料物质的量比、反应时间、温度对反应的影响,确定了合成二氨丙基苯的较佳反应条件。通过DSC对环氧树脂中该固化剂的加入量和固化工艺条件进行了研究,对环氧树脂固化物的力学性能等指标进行了考察。     

Bi-level programming model for reconstruction of urban branch road network

Considering the decision-making variables of the capacities of branch roads and the optimization targets of lowering the saturation of arterial roads and the reconstruction expense of branch roads, the bi-level programming model for reconstructing the branch roads was set up. The upper level model was for determining the enlarged capacities of the branch roads, and the lower level model was for calculating the flows of road sections via the user equilibrium traffic assignment method. The genetic algorithm for solving the bi-level model was designed to obtain the reconstruction capacities of the branch roads. The results show that by the bi-level model and its algorithm, the optimum scheme of urban branch roads reconstruction can be gained, which reduces the saturation of arterial roads apparently, and alleviates traffic congestion. In the data analysis the arterial saturation decreases from 1.100 to 0.996, which verifies the micro-circulation transportation’s function of urban branch road network. Foundation item: Project(2006CB705507) supported by the National Basic Research and Development Program of China; Project(20060533036) supported by the Specialized Research Foundation for the Doctoral Program of Higher Education of China     

智能材料二维问题的状态空间解

抛弃任何有关位移或应力模式的人为假设,引入状态空间理论,从压电、压磁智能材料和电磁耦合弹性介质材料二维问题的基本方程出发,建立了压电、压磁智能材料和弹性介质二维问题的状态变量方程,得到状态变量空间解,此解形式简单、便于应用.     

乱序RFID数据流上的复杂事件检测方法

针对发生时间戳乱序的RFID原子事件流,文章提出了一种新的复杂事件检测方法.该方法采用在一种特殊的Hash表结构中进行局部排序的方法来解决时间戳乱序问题.文中首先建立了时间戳乱序问题的描述模型;提出了面向时间戳乱序数据流的复杂事件检测算法;在基本算法的基础上添加了基于双时间槽的滑动窗口处理;对Hash表大小等参数对算法效率的影响、基于双时间槽的滑动窗口处理方法的效果进行了实验验证.实验结果表明:算法是有效的;Hash表大小对算法效率影响较为明显;基于双时间槽的滑动窗口处理方法可以显著提高内存使用效率.     

反旋向多漩流器阵列燃烧室流场的数值研究

采用雷诺应力模型(RSTM)对于反旋向多漩流器阵列贫油直喷(LDI)燃烧室的非反应冷态流场进行了数值模拟.研究中采用了一种3×3的漩流器阵列结构,相邻漩流器的旋向交替变化.计算结果表明,所研究的燃烧室流场结构十分复杂.由于相邻漩流器之间对于漩流的强化作用,因而各回流区维持了较长的长度.流场中存在的多个回流区及强湍流表明该燃烧室有潜力实现良好的燃烧性能.通过将雷诺应力模型的模拟结果与LDV实验数据进行比较发现,计算结果与实验值符合良好,说明雷诺应力模型较好地求解了回流区和高速度梯度问题.