Some Regularities of Heat and Mass Transfer in the Case of Fire Within a Building

Results of a numerical investigation of heat and mass transfer at the initial stage of fire within a building in combustion of kerosene, carried out with the use of a three-dimensional mathematical field model, are presented. A comparison of the distribution of the averaged temperatures and velocities along the vertical axis of the convective column and of the mass rates of gas flows through an open opening with the experimental data has been made. Substantial three-dimensional inhomogeneities of the velocities and the temperatures in the near-ceiling layer have been revealed. It has been established that near the opening there is a critical separation zone which influences significantly the parameters of natural gas transfer.     

Predicting the performance of concrete structures exposed to chemically aggressive environment—Field validation

The behavior of two series of concrete slabs exposed to sulfate-bearing soils was investigated by a numerical model called STADIUM. In addition to the diffusion of ions and moisture, the model also accounts for the effects of dissolution/precipitation reactions on the transport mechanisms. The simulations yielded by the model were compared to the actual degradation of the slabs after 8 years of exposure. The microstructural alterations of concrete resulting from the penetration of magnesium, chloride and sulfate ions were studied by backscatter mode scanning electron microscope observations and energy-dispersive X-ray analyses. The comparison of both series of data indicates that the model can reliably predict the various features of the microstructural alterations of concrete.

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Résumé Le comportement de deux séries de dalles sur sol en béton exposées à des sols chimiquement agressifs a été étudié à l'aide d'un code de calcul numérique appelé STADIUM. Ce modèle permet de décrire le transport couplé de l'eau et des ions dans des matériaux poreux non-saturés en prenant en considération l'influence des réactions chimiques. Les résultats des simultations de la dégradation du béton après huit ans d'exposition à des ions chlore, sulfate et magnésium. Les observations ont été réalisées par microscopie électronique à balayage. Des analyses par dispersion des rayons X ont également été effectuées. Les données démontrent clairement que le modèle perment de prédire avec précision le comportement du béton soumis à différents types d'agression chimique.

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Editorial Note Laval University (Canada) is a RILEM Titular Member. Prof. J. Marchand was awarded the 2000 Robert L'Hermite Medal. He is Editor in Chief for Concrete Science and Engineering and Associate Editor for Materials and Structures. He participates in RILEM TC 186-ISA ‘Internal Sulfate attack’.     

Photoinduced recovery of gamma-irradiated fluoride glasses

Radiation-induced changes in the optical properties of fluoride glasses (FGs) were studied on samples of zirconium fluoride and aluminum fluoride based compositions gamma-irradiated to a total dose of 1.2 MGy. Upon exposure, the fundamental absorption edge smears and shifts toward longer wavelengths. The FGs studied exhibit self-recovery of the optical properties, whereby the radiation-induced absorption decreases in the course of storage without action of any external factors. Photostimulated recovery of the optical properties of the gamma-irradiated FGs was studied in the range of light wavelengths from 400 to 1200 nm at a light intensity of 1–3 mW/cm². The maximum rate of recovery for both zirconium and aluminum fluoride based glasses was observed for the photoannealing at 600 nm.     

Failure analysis of aluminum cable steel reinforced (ACSR) conductor of the transmission line crossing the Paraná River

The failure of the conductor of the 460 kV overhead transmission line located along the crossing of the Paraná River was investigated. As a result of this failure, a blackout took place in the southern states of Brazil in January of 2002, reaching approximately 67 million inhabitants. Investigation of the external aluminium layer of the ACSR conductor near the fracture showed typical static deformation marks and dynamic fretting wear tangential marks, both associated with the presence of Al₂O₃ debris. Additionally, encrusted silicon particles were observed on the external surface of the strands. The internal Al layer showed elliptical deformation marks also associated with Al₂O₃ debris. Both Al₂O₃ and Si particles are efficient abrasive material, which associated with slight relative motion of metallic surfaces (clamp/strand and strand/strand) can promote fretting wear. Two types of fracture surface of the Al strands were identified: 45° and quasi-normal surfaces, the former being the predominant type. Delamination and particle detachment were the mechanisms of superficial degradation observed on the Al strands, indicating that the rupture of the strands occurred under a gross slip fretting regime induced by sub-conductor oscillation. Inspection of the internal surface of as-cast Al–10%Si spacer clamps revealed different stages of intense circumferential wear caused by the preferential cracking and particle detachment of the eutectic constituent of the as-cast microstructure. This intense wear reduces the clamping contact pressure, which allows higher displacement amplitude and leads to the critical fretting regime. Finally, a few suggestions are discussed to minimise the occurrence of future failures.     

Special features of the periodic-pulse-train laser radiation confinement in doped gallium arsenide and zinc selenide

Experimental data on the pulsed laser radiation confinement in compensated GaAs and ZnSe with deep impurity levels are reported for the laser wavelength λ=1.55 μm and a pulse repetition frequency of up to 100 kHz. It is demonstrated that an increase in the pulse repetition rate is accompanied by a decrease in the energy confinement threshold and by an increase in the radiation attenuation coefficient. These effects are explained by the accumulation of nonequilibrium charge carriers related to a dependence of the recombination time constant on the concentration of free impurity centers.     

Coarse filters for shape matching

This article describes the coarse shape filters that support the 3D, Internet-based search engine ShapeSifter, which aims to locate parts already in production that have a shape similar to a desired new part. The search engine analyzes the target model's shape characteristics and performs a similarity match on the database's contents. Our main challenge is identifying shape metrics that produce effective characterizations of 3D models for similarity comparison. We focus on using three novel convex hull-based indices to carry out a preliminary coarse filtering of candidates prior to more detailed analysis. We also describe the crucial role played by two databases of benchmark objects. Unlike other shape-matching systems, we chose ShapeSifter's architecture (multistep query), 3D representation (triangulated mesh), and implementation (Java3D) to allow deployment online once it matures     

Adaptive Optimal Nonlinear Filtration and Certain Related Topics. II

The properties of the solutions of optimal parametric filtration equations and an adaptive variant of the problem with regard for time-drift of the unknown parameters of the system are studied. Along with the Kalman interpretation of the optimal adaptive nonlinear filter, the Bayes approach to applying the respective a posteriori densities is also studied.     

Mechanisms of Active Fuzzy Expertise

Consideration was given to the decision making procedures based on the fuzzy messages of experts whose preferences on the set of collective decisions can also be fuzzy.