The chemical state of grain boundary cosegregation of Ce and P in Fe-P-Ce alloy system was studied bymeans of Auger Electron Spectroscopy(AES).The Auger peaks of Ce segregated at grain boundaries are foundwithin the range of 60~180 eV.By comparing with the Auger spectra of the Fe-Ce-P intermetallic compound,it is supposed that there is a two-dimensional interfacial phase at grain boundaries with Ce and P cosegregationwhich is similar to the structure of the Fe-Ce-P compound. 相似文献
Transition metal dichalcogenide (TMDC) monolayers are considered to be potential materials for atomically thin electronics due to their unique electronic and optical properties. However, large‐area and uniform growth of TMDC monolayers with large grain sizes is still a considerable challenge. This report presents a simple but effective approach for large‐scale and highly crystalline molybdenum disulfide monolayers using a solution‐processed precursor deposition. The low supersaturation level, triggered by the evaporation of an extremely thin precursor layer, reduces the nucleation density dramatically under a thermodynamically stable environment, yielding uniform and clean monolayer films and large crystal sizes up to 500 µm. As a result, the photoluminescence exhibits only a small full‐width‐half‐maximum of 48 meV, comparable to that of exfoliated and suspended monolayer crystals. It is confirmed that this growth procedure can be extended to the synthesis of other TMDC monolayers, and robust MoS2/WS2 heterojunction devices are easily prepared using this synthetic procedure due to the large‐sized crystals. The heterojunction device shows a fast response time (≈45 ms) and a significantly high photoresponsivity (≈40 AW?1) because of the built‐in potential and the majority‐carrier transport at the n–n junction. These findings indicate an efficient pathway for the fabrication of high‐performance 2D optoelectronic devices. 相似文献
A facile methodology for the large‐scale production of layer‐controlled MoS2 layers on an inexpensive substrate involving a simple coating of single source precursor with subsequent roll‐to‐roll‐based thermal decomposition is developed. The resulting 50 cm long MoS2 layers synthesized on Ni foils possess excellent long‐range uniformity and optimum stoichiometry. Moreover, this methodology is promising because it enables simple control of the number of MoS2 layers by simply adjusting the concentration of (NH4)2MoS4. Additionally, the capability of the MoS2 for practical applications in electronic/optoelectronic devices and catalysts for hydrogen evolution reaction is verified. The MoS2‐based field effect transistors exhibit unipolar n‐channel transistor behavior with electron mobility of 0.6 cm2 V?1 s?1 and an on‐off ratio of ≈10³. The MoS2‐based visible‐light photodetectors are fabricated in order to evaluate their photoelectrical properties, obtaining an 100% yield for active devices with significant photocurrents and extracted photoresponsivity of ≈22 mA W?1. Moreover, the MoS2 layers on Ni foils exhibit applicable catalytic activity with observed overpotential of ≈165 mV and a Tafel slope of 133 mV dec?1. Based on these results, it is envisaged that the cost‐effective methodology will trigger actual industrial applications, as well as novel research related to 2D semiconductor‐based multifaceted applications. 相似文献
Because mobile devices only have the limited resource in socially aware networking, some network nodes are unwilling to sacrifice their resource to forward messages to others for free, thus forming selfish nodes. However selfish nodes will cause dropping in the message delivery rate and affect the network performance, so this paper has proposed a diversity-based selfish node detection algorithm (DSNDA). Firstly, it mainly applies the node forwarding willingness mechanism to detect whether the node is selfish. If the node has the inadequate resource, that is, it cannot forward any messages for others; then it will be selfish. If the node’s resource is enough and the node has forwarded messages to other nodes, it indicates that the node is not selfish. Otherwise, DSNDA algorithm will use reputation mechanism to check the node further. If the node has broken faith, it indicates that the node is selfish. On the contrary the message confirmation mechanism will be employed to make the final check on the node. If a message does not be received or discarded after the node’s receiving it, which proves that it has selfish behaviour. If not, the node is normal. It can be proved by the simulation experiment and results that the DSNDA algorithm has significantly improved the delivery rate of messages, comparing with other algorithms. At the same time, reducing the network delay, thus verifying the feasibility of DSNDA.