Synthesis of poly(<Emphasis Type="Italic">p</Emphasis>-phenyleneethynylene)s bearing oligo-ethylene glycols and their gas permeation properties

1,4-Diiodobenzenes bearing oligo-ethylene glycols [IRC₆H₂IR, R = OCH₂CH₂OCH₃ (1a), O(CH₂CH₂O)₂CH₃ (1b), O(CH₂CH₂O)₃CH₃ (1c)] were polymerized with 1,4-diethynylbenzene in the presence of Pd/Cu catalyst to afford poly(p-phenyleneethynylene)s bearing oligo-ethylene glycols (2a–c), respectively. Polymer 2a was insoluble in any solvents, but the other polymers (2b, 2c) were soluble in CHCl₃. The weight-average molecular weights of 2b and 2c were 5.4 × 10⁴ and 9.6 × 10⁴, respectively, and they gave free-standing membranes by solution-casting method. The densities of membranes of 2b and 2c were 1.26 and 1.22 g/cm³, respectively, and their carbon dioxide permeability coefficients were 12.9 and 13.5 barrers, respectively. The CO₂/N₂ separation factor of membrane of 2b was as large as 33.7. Membrane of 3b, which contains triethylene glycols, exhibited higher CO₂ permselectivity, and the CO₂/N₂ separation factor was 50.0.     

Design proposal for hydrogen refueling infrastructure deployment in the Northeastern United States

Fuel cell vehicles (FCVs) are expected to be commercially available on the world market in 2015, therefore, introducing hydrogen-refueling stations is an urgent issue to be addressed. This paper proposes deployment plan of hydrogen infrastructure for the success of their market penetration in the Northeastern United States. The plan consists of three-timeline stages from 2013 to 2025 and divides the designated region into urban area, suburban area and area adjacent to expressway, so that easy to access to hydrogen stations can be realized. Station is chosen from four types of stations: off-site station, urban-type on-site station, suburban-type on-site station and portable station, associated with growing demand. In addition, on-site station is used as hydrogen production factory for off-site station to save total investment. This deployment plan shows that 83% of urban residents can reach station within 10 min in 2025, and that more than 90% people especially in four major cities: Boston, New York City, Philadelphia, and Washington, D.C. can get to station within 10 min by Geographic Information System (GIS) calculation.     

Effects of interface stiffness and delamination on resonant oscillations of metal laminates

In the present study, the effects of the interface stiffness and delamination of the metal laminates were investigated. In the modal analysis, the natural oscillation mode of the laminate consisting of two copper sheets with various interface conditions was analyzed by using a finite element method. The interface delamination decreases the natural frequency for the out-of-plane oscillation mode whereas it has no effect on that for the in-plane mode. The interface stiffness affects the natural frequency for both the out-of-plane and in-plane modes. Its influence was more obvious when the stiffness is lower than that of the matrix for the out-of-plane mode whereas there was an opposite trend for the in-plane mode. In the experiment, the resonant frequency of two copper sheets bonded by the adhesive was measured. As well as the simulation, the lower interface stiffness and the interface delamination decreased the resonant frequencies     

Ferroelectric and piezoelectric properties of (Bi1/2K1/2)TiO3 ceramics fabricated by hot-pressing method

Bismuth potassium titanate, (Bi_1/2K_1/2)TiO₃ (BKT), ceramics were prepared by the hot-pressing (HP) method without dopant and with dopants of Bi₂O₃, La₂O₃ and MnCO₃. The relative density of BKT ceramics hot-pressed at 1,060 and 1,080 °C (hereafter abbreviated to BKT-HP1060°C and BKT-HP1080°C) and x mass% Bi₂O₃, La₂O₃ and MnCO₃ doped BKT ceramics hot-pressed at 1,060 °C (hereafter abbreviated as BKTBix; x?=?0.1–0.6, BKTLax; x?=?0.1–0.6 and BKTMnx; x?=?0.1–0.3) were all higher than 97%. In this study, the ferroelectric properties of BKT ceramics were successfully obtained, and the remanent polarization P _r and coercive field E _c of BKT-HP1080°C were 22.2 μC/cm² and 52.5 kV/cm, respectively. A small amount of La tends to increase P _r, and the P _r of BKTLa0.1 was 19.2 μC/cm². The piezoelectricities were improved to optimize poling conditions, and the electromechanical coupling factor k ₃₃ and piezoelectric constant d ₃₃ of BKT-HP1080°C were 0.34 and 82.8 pC/N, respectively.     

Attractive performance of a Gifford–McMahon cryocooler by co-axial layout of regenerator materials

A novel filling method of regenerator materials, which we name a co-axial layout, is experimentally investigated. The 2nd stage regenerator of a Gifford–McMahon cryocooler was packed with 50% by volume of the co-axial layout (low temperature side) that consisted of 20% Gd₂O₂S and 30% HoCu₂ spheres. The warm temperature side was packed with 50% lead spheres as a single layer. The experimental results show that the cooling power of co-axial layout is almost the same as that of a three-layer layout, 20% Gd₂O₂S, 30% HoCu₂ and 50% lead, at temperatures between the ultimate low temperature (3.0 K) and 6 K. Moreover, at the temperatures above 10 K, the co-axial layout has 1.7–2.0 times the cooling power of the three-layer layout. Thus the co-axial layout produces a major improvement in cooling power. In this paper, the performance of five types of material assortments is discussed.     

Tongue-Movement Communication and Control Concept for Hands-Free Human–Machine Interfaces

A new communication and control concept using tongue movements is introduced to generate, detect, and classify signals that can be used in novel hands-free human-machine interface applications such as communicating with a computer and controlling devices. The signals that are caused by tongue movements are the changes in the airflow pressure that occur in the ear canal. The goal is to demonstrate that the ear pressure signals that are acquired using a microphone that is inserted into the ear canal, due to specific tongue movements, are distinct and that the signals can be detected and classified very accurately. The strategy that is developed for demonstrating the concept includes energy-based signal detection and segmentation to extract ear pressure signals due to tongue movements, signal normalization to decrease the trial-to-trial variations in the signals, and pairwise cross-correlation signal averaging to obtain accurate estimates from ensembles of pressure signals. A new decision fusion classification algorithm is formulated to assign the pressure signals to their respective tongue-movement classes. The complete strategy of signal detection and segmentation, estimation, and classification is tested on four tongue movements of eight subjects. Through extensive experiments, it is demonstrated that the ear pressure signals due to the tongue movements are distinct and that the four pressure signals can be classified with an accuracy of more than 97% averaged across the eight subjects using the decision fusion classification algorithm. Thus, it is concluded that, through the unique concept that is introduced in this paper, human-computer interfaces that use tongue movements can be designed for hands-free communication and control applications.     

A novel random wireless packet multiple access method using CDMA

Random packet CDMA, a novel packet-based multiple access scheme for connectionless, uncoordinated random channel access is proposed. Random packet CDMA, or RP-CDMA, utilizes a novel packet format which consists of a short header and a data portion. Each header is spread with a unique spreading code which is identical for all users and packets, while the data portion of each packet is spread by a randomly chosen spreading sequence. The receiver operates in two stages: header detection and data detection. For header detection a conventional spread spectrum receiver is sufficient. Headers are spread with a large enough processing gain to allow detection even in severe interference. The data portion is decoded with a sophisticated receiver, such as a multiuser detector, which allows for successful decoding of overlapping active packets. It is shown that the RP-CDMA system is detector capability limited and that it can significantly outperform spread ALOHA systems whose performance is limited by the channel collision mechanism. RP-CDMA also experiences a much smaller packet retransmission rate than conventional or spread ALOHA, and provides better spectral efficiencies.     

Conceptual design of mechanisms based on computational synthesis and simulation of kinematic building blocks

Although many ingenious mechanisms have been designed, the fundamental task of conceptualizing these devices is, to a great extent, still an art. While sophisticated computational tools for dynamic analysis of mechanisms exist, hardly any computational methods exist for generalized synthesis. To develop a computational model for synthesis, a formal foundation for mechanisms design must be laid by rationalizing the process of mechanical synthesis. Rationalization in synthesis implies that complex mechanical motions can be described in terms of primitives or building blocks. In this paper, we present a matrix methodology that forms the basis for a computable approach to design synthesis. In this methodology, the continuous design space of a mechanisms domain is discretized into functional subspaces, and each subspace is represented uniquely by a conceptual building block. The matrix scheme serves as a formal means to (a) represent and reason with the building blocks at different levels of abstraction, (b) generate alternate conceptual design configurations, and (c) facilitate rapid simulation of design concepts by connecting a series of building blocks.