地下环境中电子设备的腐蚀与防护

程环境中电子设备所承受的湿度、温度、腐蚀性气体、空气沉积物、微生物等环境应力因素及其腐蚀效应，概述总结了电子设备腐蚀机制及主要类型，并提出电子设备设计与使用中抑制腐蚀的措施.     

Defect classification using a new feature for pulsed eddy current sensors

The objective of this study is to identify defects such as surface cracks, subsurface defects and metal losses using feature based pulsed eddy current sensors. A new feature, termed as the rising point, related to the propagation time of electromagnetic waves in metallic targets is proposed for defect classification. Experimental studies of the validation, robustness of the new feature of rising time are reported. In addition to other features, defects can be detected and quantified robustly and lift-off can also be derived from the rising time. Conclusion and further work are derived on the basis of the findings.     

钛酸钡中的硼间隙及其对PTCR效应的影响

通过B2O3蒸汽掺杂，钛酸钡晶胞膨胀，表明硼离子可以进入钛酸钡晶格中形成硼间隙。B2O3蒸汽掺杂使含Y钛酸钡陶瓷室温电阻率下降，升阻比提高。同样的烧结条件下，钛酸钡陶瓷的PTCR效应随B2O3蒸汽掺杂源的浓度升高而升高。硼间隙和／或相关缺陷络合物可以形成电子捕获中心，从而提高PTCR效应。     

Experiment and simulation study of 3D magnetic field sensing for magnetic flux leakage defect characterisation

Magnetic flux leakage (MFL) testing is widely used to detect and characterise defects in pipelines, rail tracks and other structures. The measurement of the two field components perpendicular to the test surface and parallel to the applied field in MFL systems is well established. However, it is rarely effective when the shapes of the specimens and defects with respect to the applied field are arbitrary. In order to overcome the pitfalls of traditional MFL measurement, measurement of the three-dimensional (3D) magnetic field is proposed. The study is undertaken using extensive finite element analysis (FEA) focussing on the 3D distribution of magnetic fields for defect characterisation and employing a high sensitivity 3-axis magnetic field sensor in experimental study. Several MFL tests were undertaken on steel samples, including a section of rail track. The experimental and FEA test results show that data from not only the x- and z-axes but also y-axis can give comprehensive positional information about defects in terms of shape and orientation, being especially advantageous where the defect is aligned close to parallel to the applied field. The work concludes that 3D magnetic field sensing could be used to improve the defect characterisation capabilities of existing MFL systems, especially where defects have irregular geometries.     

撞击流—旋转填料床反应器的微观混合性能研究

采用化学偶合法 ,对撞击流—旋转填料床反应器内微观混合进行了实验研究 ,得到了转速、喷嘴间距、射流速度及浓度等因素对离集指数Xs的影响规律 ,并对其进行了定性的分析。结果表明撞击流—旋转填料床反应器中微观混合能被极大地强化 ,可成为适合快速反应新型反应设备     

Spectroscopic studies of copper, silver and gold-metallothioneins

Metallothionein is a ubiquitous protein with a wide range of proposed physiological roles, including the transport, storage and detoxification of essential and nonessential trace metals. The amino acid sequence of isoform 2a of rabbit liver metallothionein, the isoform used in our spectroscopic studies, includes 20 cysteinyl groups out of 62 amino acids. Metallothioneins in general represent an impressive chelating agent for a wide range of metals. Structural studies carried out by a number of research groups (using (1)H and (113)Cd NMR, X-ray crystallography, more recently EXAFS, as well as optical spectroscopy) have established that there are three structural motifs for metal binding to mammalian metallothioneins. These three structures are defined by metal to protein stoichiometric ratios, which we believe specifically determine the coordination geometry adopted by the metal in the metal binding site at that metal to protein molar ratio. Tetrahedral geometry is associated with the thiolate coordination of the metals in the M(7)-MT species, for M = Zn(II), Cd(II), and possibly also Hg(II), trigonal coordination is proposed in the M(11-12)-MT species, for M = Ag(I), Cu(I), and possibly also Hg(II), and digonal coordination is proposed for the metal in the M(17-18)-MT species for M = Hg(II), and Ag(I). The M(7)-MT species has been completely characterized for M = Cd(II) and Zn(II). (113)Cd NMR spectroscopic and x-ray crystallographic data show that mammalian Cd(7)-MT and Zn(7)-MT have a two domain structure, with metal-thiolate clusters of the form M(4)(S(cys))(11) (the alpha domain) and M(3)(S(cys))(9) (the beta domain). A similar two domain structure involving Cu(6)(S(cys))(11) (alpha) and Cu(6)(S(cys))(9) (beta) copper-thiolate clusters has been proposed for the Cu(12)-MT species. Copper-, silver- and gold-containing metallothioneins luminesce in the 500-600 nm region from excited triplet, metal-based states that are populated by absorption into the 260-300 nm region of the metal-thiolate charge transfer states. The luminescence spectrum provides a very sensitive probe of the metal-thiolate cluster structures that form when Ag(I), Au(I), and Cu(I) are added to metallothionein. CD spectroscopy has been used in our laboratory to probe the formation of species that exhibit well-defined three-dimensional structures. Saturation of the optical signals during titrations of MT with Cu(I) or Ag(I) clearly show formation of unique metal-thiolate structures at specific metal:protein ratios. However, we have proposed that these M=7, 12 and 18 structures form within a continuum of stoichiometries. Compounds prepared at these specific molar ratios have been examined by X-ray Absorption Spectroscopy (XAS) and bond lengths have been determined for the metal-thiolate clusters through the EXAFS technique. The stoichiometric ratio data from the optical experiments and the bond lengths from the XAS experiments are used to propose structures for the metal-thiolate binding site with reference to known inorganic metal-thiolate compounds.     

混凝浑液面沉速与混凝剂投加量的关系研究

探讨了黄河高浊度水混凝沉淀浑液面沉速与自然沉速之间的相关性,经过对实验数据进行线性回归提出了混凝过程中浑液面沉速与自然沉速、含沙量、PAM投加量之间的经验公式。运用该经验公式得出的浑液面沉速计算值与实测相对误差在0.43%～12.27%之间。     

苯酚羟基化制邻苯二酚催化剂的活性评价

对苯酚羟基化反应铁复合氧化物类催化剂进行了活性评价的实验研究 ,实验表明 ,Cat980 5的选择性好 ,但邻对位比倒置 ,Cat980 8的选择性差 ,但邻对位比正常 ,其性能与国外催化剂的性能相近     

基于高速局域网的连续搅拌反应釜(CSTR)控制系统

提出基于客户－服务器模式的连续搅拌反应釜（CSTR）控制系统。系统充分利用网络设备和技术，扩大了实时控制设备的应用范围和资源利用率，方便了学生学习和巩固基本的控制理论和技术。本系统可提供的操作（控制策略）有PID控制和鲁棒控制，同时还提供传输可执行文件和反馈执行结果的功能，以便测试实验者自行编写的算法程序。     

Influence of organophilic clay and preparation methods on EVA/montmorillonite nanocomposites

Ethylene‐vinyl acetate copolymer (EVA)/montmorillonite MMT nanocomposites have been prepared by using different methods: one is from the organophilic montmorillonite (OMT) and the other is from the pristine MMT and reactive compatibilizer hexadecyl trimethyl ammonium bromide (C16). In this study, different kneaders were used (twin‐screw extruder and twin‐roll mill) to prepare nanocomposites. The nanocomposite structures are evidenced by the X‐ray diffraction (XRD) and high‐resolution electronic microscope (HREM). The thermal properties of the nanocomposites were investigated by thermogravimetric analysis (TGA). Moreover, the tensile tests were carried out with a Universal testing machine DCS‐5000. It is shown that different methods and organophilic montmorillonite have influence on EVA/MMT nanocomposites.© 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 2416–2421, 2004